全文获取类型
收费全文 | 3555篇 |
免费 | 210篇 |
国内免费 | 215篇 |
专业分类
电工技术 | 47篇 |
综合类 | 182篇 |
化学工业 | 1106篇 |
金属工艺 | 421篇 |
机械仪表 | 96篇 |
建筑科学 | 82篇 |
矿业工程 | 38篇 |
能源动力 | 46篇 |
轻工业 | 866篇 |
水利工程 | 7篇 |
石油天然气 | 134篇 |
武器工业 | 12篇 |
无线电 | 130篇 |
一般工业技术 | 313篇 |
冶金工业 | 167篇 |
原子能技术 | 104篇 |
自动化技术 | 229篇 |
出版年
2024年 | 15篇 |
2023年 | 76篇 |
2022年 | 196篇 |
2021年 | 220篇 |
2020年 | 174篇 |
2019年 | 119篇 |
2018年 | 129篇 |
2017年 | 156篇 |
2016年 | 136篇 |
2015年 | 127篇 |
2014年 | 195篇 |
2013年 | 316篇 |
2012年 | 371篇 |
2011年 | 348篇 |
2010年 | 223篇 |
2009年 | 176篇 |
2008年 | 172篇 |
2007年 | 142篇 |
2006年 | 128篇 |
2005年 | 116篇 |
2004年 | 104篇 |
2003年 | 54篇 |
2002年 | 48篇 |
2001年 | 28篇 |
2000年 | 19篇 |
1999年 | 28篇 |
1998年 | 19篇 |
1997年 | 23篇 |
1996年 | 23篇 |
1995年 | 17篇 |
1994年 | 14篇 |
1993年 | 10篇 |
1992年 | 9篇 |
1991年 | 8篇 |
1990年 | 6篇 |
1989年 | 6篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1980年 | 2篇 |
1977年 | 1篇 |
1973年 | 2篇 |
排序方式: 共有3980条查询结果,搜索用时 15 毫秒
91.
High performance Sm2Fe17Nx magnetic powders were fabricated by ball-milling method and were compacted using spark plasma sintering(SPS) technique.Effects of processing conditions on the magnetic properties and decomposition dynamic of the magnets were investigated.It is found that higher sintering temperature improves the densification of the magnets, while deteriorates their magnetic properties simultaneously due to the decomposition of the Sm2Fe17Nx.Sintering at lower temperature can preserve the crystal structure of Sm2Fe17Nx compound, while the powders cannot be consolidated into a fully dense compact.An increased compressive pressure leads to better magnetic properties and higher density for the magnet at the same sintering temperature. 相似文献
92.
Hemant J. Desai Daniel O. Acheampong Robert Hudson Richard Lacey Claire Stanley Helen Turner 《Journal of Energetic Materials》2017,35(1):109-124
The synthesis of a novel heterocyclic–telechelic polymer, α,ω-oxetanyl-telechelic poly(3-nitratomethyl-3-methyl oxetane), is described. Infrared spectroscopy (IR), gel permeation chromatography (GPC), and nuclear magnetic resonance (NMR) spectroscopy have been used to confirm the successful synthesis, demonstrating the presence of the telechelic-oxetanyl moieties. Synthesis of the terminal functionalities has been achieved via displacement of nitrato groups, in a manner similar to that employed with other leaving groups such as azido, bromo, and nitro, initiated by nucleophiles. In the present case, displacement occurs on the ends of a nitrato-functionalized polymer driven by the formation of sodium nitrate, which is supported by the polar aprotic solvent N,N-dimethyl formamide. The formation of an alkoxide at the polymer chain ends is favored and allows internal back-biting to the nearest carbon bearing the nitrato group, intrinsically in an SN2(i) reaction, leading to α,ω-oxetanyl functionalization. The telechelic-oxetanyl moieties have the potential to be cross-linked by chemical (e.g., acidic) or radiative (e.g., ultraviolet) curing methods without the use of high temperatures, usually below 100°C. This type of material was designed for future use as a contraband simulant, whereby it would form the predominant constituent of elastomeric composites comprising rubbery polymer with small quantities of solids, typically crystals of contraband substances, such as explosives or narcotics. This method also provides an alternative approach to ring closure and synthesis of heterocycles. 相似文献
93.
94.
95.
Dr. Richa Sharma Tulika Srivastava Alka Raj Pandey Dr. Tripti Mishra Dr. Bhagyashri Gupta Dr. Sabbu Sathish Reddy Dr. Suriya P. Singh Dr. Tadigoppula Narender Aradhya Tripathi Dr. Balasubramanian Chandramouli Dr. Koneni V. Sashidhara Dr. Smriti Priya Dr. Niti Kumar 《ChemMedChem》2021,16(13):2146-2156
Defective protein folding and accumulation of misfolded proteins is associated with neurodegenerative, cardiovascular, secretory, and metabolic disorders. Efforts are being made to identify small-molecule modulators or structural-correctors for conformationally destabilized proteins implicated in various protein aggregation diseases. Using a metastable-reporter-based primary screen, we evaluated pharmacological chaperone activity of a diverse class of natural products. We found that a flavonoid glycoside ( C-10 , chrysoeriol-7-O-β-D-glucopyranoside) stabilizes metastable proteins, prevents its aggregation, and remodels the oligomers into protease-sensitive species. Data was corroborated with additional secondary screen with disease-specific pathogenic protein. In vitro and cell-based experiments showed that C-10 inhibits α-synuclein aggregation which is implicated in synucleinopathies-related neurodegeneration. C-10 interferes in its structural transition into β-sheeted fibrils and mitigates α-synuclein aggregation-associated cytotoxic effects. Computational modeling suggests that C-10 binds to unique sites in α-synuclein which may interfere in its aggregation amplification. These findings open an avenue for comprehensive SAR development for flavonoid glycosides as pharmacological chaperones for metastable and aggregation-prone proteins implicated in protein conformational diseases. 相似文献
96.
Zhitao Wu Kaiyu Zhang Yuanjian Hong Chengshuang Zhou Jinyang Zheng Lin Zhang 《International Journal of Hydrogen Energy》2021,46(23):12348-12360
The fatigue crack growth rate of warm-rolled AISI 316 austenitic stainless steel was investigated by controlling rolling strain and temperature in argon and hydrogen gas atmospheres. The fatigue crack growth rates of warm-rolled 316 specimens tested in hydrogen decreased with increasing rolling temperature, especially 400 °C. By controlling the deformation temperature and strain, the influences of microstructure (including dislocation structure, deformation twins and α′ martensite) and its evolution on hydrogen-induced degradation of mechanical properties were separately discussed. Deformation twins deceased and dislocations became more uniform with the increase in rolling temperature, inhibiting the formation of dynamic α′ martensite during the crack propagation. In the cold-rolled 316 specimens, deformation twins accelerated hydrogen-induced crack growth due to the α′ martensitic transformation at the crack tip. In the warm-rolled specimens, the formation of α′ martensite around the crack tip was completely inhibited, which greatly reduced the fatigue crack growth rate in hydrogen atmosphere. 相似文献
97.
The idea behind this work was to acquire one dimensional lasing in the Rhodamine 6G dye doped collagen fibers with the control of random lasing phenomenon properties by changing the dye molecular arrangement. We show that a simple manipulation of the dye concentration in biopolymeric fibril matrix bulk and an additional use of α-cyclodextrin (α-CD) molecules determine formation of specific dye aggregates and as a consequence the shift of the random lasing emission wavelength in the desired direction. The analysis of the light transport mean free path in function of the dye and (α-CD) concentration was done with the use of coherent back scattering technique. 相似文献
98.
Y-α-sialon ceramics with different compositions were hot-press sintered. Varying the m or n value in theα-Sialon general formula, both the α-sialon grain morphology and phase assemblages present diversification, therefore, affecting the toughness and hardness. Meanwhile, varying the compositional parameters also influenced the composition and structure of the intergranular glass phase, as well as its oxidation behavior at 1100-1200 ℃. The oxidation of the intergranular phase Mt in the Y-α-sialon ceramics was significantly enhanced with further rising the oxidation temperature to 1300 ℃. 相似文献
99.
Supercritical fluid extraction (SFE) was studied as an alternative technology in the pharmaceutical industry for the separation of α-tocopherol from gel and skin of Aloe vera and almond leaves. The influence of operating conditions was investigated on the recovery of supercritical carbon dioxide (SC-CO2) extraction of α-tocopherol from three-year old Aloe vera (Aloe barbadensis Miller) leaf gel. The obtained results were compared with the conventional Soxhlet extraction. Response surface methodology (RSM) was applied to optimize effective variables on the extracted recovery of α-tocopherol. The maximum α-tocopherol recovery of 53.41% from Aloe vera gel was obtained with employing RSM predicted optimal operating conditions of 32 MPa, 45.91 °C, 0.84 ml SC-CO2/min and 140 min for extraction. The α-tocopherol extraction yield for gel and skin of Aloe vera and almond leaves at these optimal operating conditions were obtained 1.53, 16.29 and 2.61 mg/100 g dry sample, respectively. 相似文献
100.
Rotational fretting which exist in many engineering applications has incurred enormous economic loss. Thus, accessible methods are urgently needed to alleviate or eliminate damage by rotational fretting. Surface engineering is an effective approach that is successfully adopted to enhance the ability of components to resist the fretting damage. In this paper, using a high-velocity oxygen fuel sprayed(HVOF) technique WC-17 Co coating is deposited on an LZ50 steel surface to study its properties through Vickers hardness testing, scanning electric microscope(SEM), energy dispersive X-ray spectroscopy(EDX), and X-ray diffractrometry(XRD). Rotational fretting wear tests are conducted under normal load varied from 10 N to 50 N, and angular displacement amplitudes vary from 0.125° to 1°. Wear scars are examined using SEM, EDX, optical microscopy(OM), and surface topography. The experimental results reveal that the WC-17 Co coating adjusted the boundary between the partial slip regime(PSR) and the slip regime(SR) to the direction of smaller amplitude displacement. As a result, the coefficients of friction are consistently lower than the substrate's coefficients of friction both in the PSR and SR. The damage to the coating in the PSR is very slight. In the SR, the coating exhibits higher debris removal efficiency and load-carrying capacity. The bulge is not found for the coating due to the coating's higher hardness to restrain plastic flow. This research could provide experimental bases for promoting industrial application of WC-17 Co coating in prevention of rotational fretting wear. 相似文献