Adsorption and decomposition of NO on carbon and carbon-supported catalysts

The interactions of NO with carbon and carbon-supported catalysts have been investigated by means Fourier transform infrared spectroscopy. Nitric oxide direct decomposition over carbon-supported catalysts (Cu, Pt) was studied in a temperature ranging from 473 to 623 K. NO conversion increased with increasing reaction temperature in the whole temperature range. The carbon-supported Pt catalyst has a very high activity for the decomposition of NO in the absence of oxygen. As a result of NO chemisorption isocyanate (-NCO) species on the surface of carbon containing Cu were observed. When the reaction temperature was increased, the -NCO band at 2229 cm⁻¹ became more intense.     

挤压六通管及其连接结构的安全性研究

六通管是石油化工设备及压力管道中的重要元件,传统的制作及连接方法是在集流管上开孔,然后将支管插入并焊接而成或采用锻制的方法制成。采用挤压的方法制作六通管,将其与支管对接焊接。并通过试验及数值模拟对该结构的安全性进行了研究,实践证明,这种挤压六通管的强度性能优于普通的焊接六通管,可以广泛应用于工业生产。     

螺栓球网架杆件在非节点横向荷载作用下承载力的有限元分析

运用ANSYS有限元程序 ,研究了在轴向力与非节点横向力共同作用下网架螺栓球节点杆件的受力性能 ,得出其应力分布状况及弹性极限承载力 ,并提出了螺栓球网架杆件在非节点横向力作用下承载力的计算公式。     

SO_4~(2-)(S_2O_8~(2-))/Fe_2O_3-SiO_2固体超强酸对乙酸/丁醇酯化反应的催化性能研究

研究了SO2 -4/Fe2 O3 SiO2 固体超强酸对乙酸 /丁醇酯化反应的催化作用 ,得到合适的工艺条件 :复合氧化物中n(Fe)∶n(Si) =1∶2 ,浸渍的H2 SO4浓度 1mol/L ,5 5 0℃预焙烧活化 3h ,催化剂用量 0 .8g ,酯化反应时间 4h ,乙酸的转化率达 96 .3%。在此条件下制得S2 O2 -8/Fe2 O3 SiO2 固体超强酸催化剂 ,并考察了其催化活性 ,实验结果显示该固体超强酸具有更高的催化活性 ,乙酸转化率高达 98.6 %。     

三维地震资料连片的一致性处理技术

三维地震资料连片处理是一套复杂而精细的数字处理工作。根据各区块三维地震资料的频率、相位、时差、信噪比等的特殊性和差异性，采用叠前能量一致性、相位一致性和振幅一致性处理方法，对能量、振幅、相位等有效地进行一致性补偿和校正，使各区块资料在保持原有品质的前提下，既提高了信噪比和分辨率，又保证了资料整体拼接的一致性。应用该方法处理胜利桩海地区23块共1500km^2三维资料，取得了良好的效果。     

聚酯新型催化剂乙二醇锑的工业应用

介绍了国产新型催化剂惭二醇锑在洛阳石油化工总厂聚酯装置上的使用情况，结果表明：乙二醇锑催化剂活性高、易溶解；以乙二醇锑催化剂合成的聚酯产品质量稳定，纺丝时的加工性能明显得到改善。     

Divide and Congruence Applied to η-Bisimulation

We present congruence formats for η- and rooted η-bisimulation equivalence. These formats are derived using a method for decomposing modal formulas in process algebra. To decide whether a process algebra term satisfies a modal formula, one can check whether its subterms satisfy formulas that are obtained by decomposing the original formula. The decomposition uses the structural operational semantics that underlies the process algebra.     

孤东油田的海油陆采进展

孤东油田极浅海区域新发现几个边际油藏。其中垦东401块水深-2m,距陆地2.7km,为稀油、疏松砂岩油藏,试油获14～25t/d工业油流。在三维地震、测井约束地震反演、数值模拟和油藏经营管理评价基础上编制了产能建设方案,通过修筑海公路、人工岛、丛式井组、大位移水平井、采用数据采集与控制的远程测控和紧急关断技术,能够无人职守、遥测遥控,整体实现了海油陆采。有效动用地质储量233×104t,钻井12口,建成年产油4×104t能力,累产油8.6×104t。目前在垦东12人工岛上钻打了26口井,推广了海油陆采经验。     

割缝防砂筛管抗挤强度有限元计算模型

针对割缝防砂筛管周围或缝内部堵塞，造成井眼压力增加，可能会导致筛管被挤毁的问题，采用有限元方法，通过大型有限元程序，建立了其抗挤强度的有限元计算模型。根据弹塑性理论，对割缝防砂筛管进行分析，得出其抗挤强度。结果与国外的实验数据进行对比，数值模拟结果比实验值略大，但两者相差较小，证明了该模型的正确性。为其他尺寸割缝筛管的抗挤强度设计提供了一种数值计算方法。     

Vorticity field structure associated with the 3D Tollmien-Schlichting waves

Details of the vorticity field structure associated with the 3D Tollmien-Schlichting waves have been examined based upon the recent numerical studies of the subject. First, a single obliquet-s wave has been found to have the velocity component parallel to the wave front playing an overall dominant role, in particular, to create the longitudinal vorticity. The so-called Benney-Lin longitudinal vortices are then demonstrated to be, in fact, a minor consequence compared with the localized longitudinal vorticity field and its periodic pumping. Finally, the formation of the longitudinal vorticity field in the fundamental- and subharmonic-mode interactions is explained. The research reported in this paper has been supported in part by Bundesministerium für Forschung und Technologie and by Deutsche Forschungsgemeinschaft. The major part of the paper has been presented at the Third Asian Congress of Fluid Mechanics, 1–5 September 1986, in Tokyo, as a General Lecture by the senior author, FRH.