Quantitative study of the effect of electromagnetic field on scale deposition on nanofiltration membranes via UTDR

Ultrasonic time-domain reflectometry (UTDR) as an in situ, non-invasive real-time technique has been successfully utilized to quantify membrane fouling and cleaning. This study describes an existing ultrasonic technique for quantitative study of the effect of magnetic fields on CaCO₃ scale deposition on the membrane surface during crossflow nanofiltration (NF). The fouling experiments were conducted with CaCO₃ solution containing Ca²⁺ of 1.8 and 3 mmol/L. The experimental electromagnetic field (EMF) was 0.02 T. A commercial NF membrane and a highly sensitive ultrasonic sensor were used in all the experiments. Results show a good relationship between the ultrasonic measurements and the development of CaCO₃ scale on the NF membrane surface. An increase in the amplitude of differential signal with operation time results from the deposition of the CaCO₃ scale layer. In addition, the movement of the differential signal in the time domain observed is associated with an increase in the thickness of the fouling layer. The UTDR technique is capable of measuring the rate of fouling layer formation under different treatment conditions, i.e. with non-magnetic field (NMF) and EMF. Scale layer of deposited CaCO₃ obtained in the experiment with NMF is denser and thicker than that with EMF. The scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses imply that the magnetic treatment suppresses the formation of calcite crystals and prefers vaterite and aragonite. Furthermore, the ultrasonic technique is sensitive to the different fouling rate between experiments carried out with 1.8 and 3 mmol/L CaCO₃ solutions. The thickness of the fouling layer measured by weight measurement is consistent with that obtained by UTDR in real time. The thinner and less dense scale layer is the main reason for the slower flux decline. Overall, independent measurements such as the flux-decline data, SEM analysis and weight measurement corroborate the ultrasonic measurements.     

3S技术在日本筑波山梅林公园规划上的应用

以日本筑波山梅林公园规划为例,总结了利用3S技术进行园林规划的方法及其起到的作用,并阐明了如何将得到的经验教训结合我国国情,推动我国相关方面的发展进程.     

直流电机换向火花的检测与调整

分析了直流电机换向火花产生的主要原因,提出了如何对电磁部分和机械部分引起的火花进行检测,通过检测得到正确判断,进行恰当地调整,使电机运行状况得到改善。     

Fast accessing Web3D contents using lightweight progressive meshes

Accessing Web3D contents is relatively slow through Internet under limited bandwidth. Preprocessing of 3D models can certainly alleviate the problem, such as 3D compression and progressive meshes (PM). But none of them considers the similarity between components of a 3D model, so that we could take advantage of this to further improve the efficiency. This paper proposes a similarity‐aware data reduction method together with PM, called lightweight progressive meshes (LPM). LPM aims to excavate similar components in a 3D model, generates PM representation of each component left after removing redundant components, and organizes all the processed data using a structure called lightweight scene graph. The proposed LPM possesses four significant advantages. First, it can minimize the file size of 3D model dramatically without almost any precision loss. Because of this, minimal data is delivered. Second, PM enables the delivery to be progressive, so called streaming. Third, when rendering at client side, due to lightweight scene graph, decompression is not necessary and instanced rendering is fully exerted. Fourth, it is extremely efficient and effective under very limited bandwidth, especially when delivering large 3D scenes. Performance on real data justifies the effectiveness of our LPM, which improves the state‐of‐the‐art in accessing Web3D contents. Copyright © 2015 John Wiley & Sons, Ltd.     

Er_2O_3改性尼龙6的制备及性能研究

用熔融纺丝法成功制备了PA6/PP-g-MAH/Er2O3纤维材料,采用DSC、FTIR研究Er2O3对尼龙6的结构性能影响,通过检测混合样品的熔融指数、拉伸强度和断裂伸长率研究Er2O3对尼龙6的力学性能影响。结果表明:当Er2O3的添加量为4 phr时,PA6/PP-g-MAH/Er2O3初生纤维强度提高了51%,断裂伸长率增加了10.6%,同时结晶温度降低,熔融温度降低,熔体流动速率提高。     

2,3-吡啶二甲酸的合成

采用喹啉为原料,以高锰酸钾为氧化剂,以水为溶剂,经过氧化、浓缩、浓盐酸酸化、抽滤、干燥,合成了2,3-吡啶二甲酸,产率43.7%。     

三维地质建模质量控制方法及应用

从地质建模的流程入手,总结了建模过程中质量控制方法,主要从基础数据准备和质量控制,构造模型质量控制,相模型的质量控制,属性模型的质量控制,模型验证五个方面加以质量控制。在多个项目中的应用表明能够显著地提高地质模型的质量。     

One-Pot Synthesis,Crystal Structure,and Thermal Decomposition Behavior of 1,1ʹ-Diamino-4,4ʹ,5,5ʹ-Tetranitro-2,2ʹ-Biimidazole

1,1?-Diamino-4,4?,5,5?-tetranitro-2,2?-biimidazole (DATNBI) was synthesized, by employing one-pot facile method, from 4,4?,5,5?-tetranitro-2,2?-biimidazole. The crystal structure was determined by X-ray diffraction for the first time. DATNBI crystallized in monoclinic system P2₁/c, with a crystal density of 1.934 g cm^?3 at 293(2) K and 2.019 g cm^?3 at 130(2) K, respectively. Its crystal parameters at 293 K are a = 4.8833(15) Å, b = 6.960(2) Å, c = 6.928(4) Å, α = γ = 90°, β = 93.418(6)°, V = 591.1(3) ?³, Z = 2, μ = 0.178 mm^?1, and F(000) = 348. The thermal stability and non-isothermal kinetics of DATNBI were studied by differential scanning calorimeter (DSC) with heating rates of 5, 10, 15, and 20 K min^?1. The apparent activation energy (E_a) at the first decomposition peak calculated by Kissinger, Ozawa, and Starink equations were 85.50, 89.67, and 86.10 kJ mol^?1, respectively. For the second peak, these were 116.49, 119.82, and 117.45 kJ mol^?1, respectively, with individual pre-exponential factors lnA = 18.40 s^?1 and lnA = 25.11 s^?1. The thermogravimetry-Fourier transform infrared spectroscopy (TG-FTIR) analysis of thermal decomposition products reveals that the main decomposition gas products are H₂O, N₂O, CO₂, and NO₂. Based on the new crystalline densities, the detonation velocity and pressure predicted by EXPLO5 are 9062 m s^?1 and 36.4 GPa, respectively.     

Two micrometer fluorescence emission and energy transfer in Yb3+/Ho3+ co-doped lead silicate glass

Enhanced 2.0 μm and visible up-conversion emissions from Ho³⁺ via Yb³⁺ sensitization in lead silicate glasses have been obtained under the excitation of 980-nm laser diode. The possible energy transfer mechanism has been analyzed based on the photoemission spectroscopy and lifetime measurement. The lifetime of Ho³⁺: ⁵I₇ laser upper level has also been measured. Based on the absorption spectra, Judd–Ofelt parameters, spontaneous emission probability, the absorption, emission cross sections, and gain coefficients have been calculated and analyzed. The results indicate that the Yb³⁺/Ho³⁺ co-doped lead silicate glass has potential application in mid-infrared wavelengths.