Non-steady-state model for kinetics of free radical polymerization, 4. Direct thermal initiation

This paper deals with the non-steady-state kinetics of direct thermal initiated polymerization. The initiation is assumed to be a bimolecular reaction of the monomer. The relationship between the radical concentration and the monomer conversion is rigorously derived. In further treatment a few very close approximations are introduced based on the fact that the number of monomer molecules reacting in the initiation step is much less than that consumed in the propagation step for a process producing high polymer, and the value of the rate constant for propagation or chain transfer is much lower than that for chain termination. Expressions for various molecular parameters, such as molecular weight distribution, number-average and weight-average degrees of polymerization, and dispersity, are given. Several numerical examples are provided.     

Geometric features of the flame propagation process for an SI engine having dual‐ignition system

Flame front surface area and enflamed volume (the volume enclosed with flame front) is theoretically analysed for a spark‐ignition engine, having cylindrical disc‐shaped combustion chamber with two spark plugs located axisymmetrically on cylinder head, between cylinder axis and cylinder wall. Spherical flame front assumption is used. A computer code is developed based on purely geometric consideration of the flame development process in combustion chamber, and is used to investigate the effects of variations of spark plugs' locations on geometric features of the flame front. A comparison has also been made with a spark‐ignition engine having one spark plug at the same location. Copyright © 2002 John Wiley & Sons, Ltd.     

步进式加热炉炉温优化设定模型及软件开发

针对线材厂步进式加热炉实际工况，提出了基于经验规则的炉温优化设定模型和在线自学习获取知识的思想，并以炉温优化设定模型为核心，开发出加热炉计算机控制系统的优化运行软件。     

面流消能近底紊动流速特性的研究(面流消能试验研究之一)

本文主要论述了面流消能五种典型流态近底紊动流速特性,总结出了近底时均流速和紊动强度沿程变化规律,提出了近底紊动流速可能出现的最大瞬时值及相应位置的计算公式。面流消能工程的下游防冲设计中考虑的主要水力参数之一是,消能段近底流速紊动可能出现的最大瞬时值及其相应的部位,但目前国内外研究成果较少。笔者通过水工模型试验重点研究了面流消能各典型流态近底流速及其紊动纵向分量沿程的变化规律,并提出了计算公式,为优化面流设计提供科学依据。     

Kinetic analysis for effect of initial substrate concentration on growth and secondary metabolite production in cultures of Nicotiana tabacum

Suspension cultures of tobacco cells were studied using airlift and rotary-drum bioreactors. The effect of initial concentrations of a major substrate, sucrose, on the growth and production of a secondary metabolite, phenolic compounds, was investigated. The dry weights and total concentrations of the phenolic compounds increased with the initial sucrose concentration in both bioreactors. Both bioreactors were found to have the same tendency for the effect of initial sucrose concentration. The structured model, presented previously was modified by considering that sucrose was hydrolyzed to glucose and fructose by an enzymatic reaction. The previous and the new models were applied to the above two sets of experimental data obtained with two bioreactors, independently. The hydrolysis of sucrose was elucidated to contribute slightly to the overall kinetics of growth and secondary metabolite production in these cultures. Furthermore, the levels of shear damage in each bioreactor were quantitatively compared based on the death rate constant, k_i, which is one of the model constants.     

Design of a robust controller for a supersonic aircraft using H∞ approach

In this paper an H_∞ optimal, robust flight control system design for a supersonic aircraft has been described. Separate controllers are designed for longitudinal and lateral motions. A general two-degrees-of-freedom controller is proposed, where feedback control is designed for robust performance augmentation, while a series compensator is used to ensure that requisite handling qualities. Three alternative methods to achieve performance robustness have been discussed. The results obtained are very encouraging. It is hoped that this will equip the flight control engineers with an alternative to the conventional methods.     

创新数学模型优化过程控制

重点介绍了武钢热冷连轧计算机轧制工艺数学模型，武钢数模的开发创新使用情况及其取得的经济效益和社会效益。     

Unrestricted Hartree-Fock approximation of the extended emery model

We use an unrestricted self-consistent Hartree-Fock approach to calculate the nature of doping states in the three-band Hubbard model. It turns out that for physically relevant parameter values one hole is localized within a small spin-polarized region where five Cu spins are aligned in the same direction. The spin polarization and binding energy between these spinpolaronic states are investigated as a function of different parameters including a Holstein-type electron-phonon coupling on the Cu sites. At higher doping concentration we observe the occurrence of afmon states where the holes are localized in a ring-shaped area. Inside this ring the antiferromagnetic order parameter has inverse sign with respect to the residual antifer-romagnetically ordered plane.     

集群系统与公用网互连的仿真模型和模拟算法

在讨论ＭＰＴ１３２７信令的集群移动通信系统与国内Ｎｏ．７信令的ＰＳＴＮ网间互连，帝现两种信令配合中，研究了集群系统的仿真模型和模拟算法，同时模拟出整个集群系统的工作情况，运行结果证实了所提方案的可行性与准确性。