高速钢W6Mo5Cr4V2的脱磷试验

在３０ｋｇ感应炉上用ＣａＯ－Ｎａ２ＣＯ３－ＣａＦ２－ＦｅｘＯ（ＭｏＯ３）渣、ＭｏＣｌ６粉剂和Ａｌ－Ｃａ合金作脱磷剂对高速钢Ｗ６Ｍｏ５Ｃｒ４Ｖ２进行脱磷试验。结果表明，ＣａＯ－Ｎａ２ＣＯ３－ＣａＦ２－ＦｅｘＯ渣的脱磷效果最好，一般脱磷率可达２６％￣５６％。     

Probing the early stages of polymerization of ethylene on a model chromium/silica catalyst by Fourier transform infrared spectroscopy

The nature of the interaction of monomer, and the early stages of growth of oligomers of ethylene on a rather more uniform surface of Cr/SiO₂ catalyst than hitherto studied has been investigated by differenceFTIR spectroscopy using C₂D₄ and C₂H₄ as reactants both with and without subsequent treatment of the catalyst with CO andTHF. The active catalyst was prepared by reaction of vapour phase CrO₂Cl₂ with the vicinal hydroxyls of the silica surface. Three distinct kinds of methylene groups were detected. Arguments are given for assigning the peaks at 2935 and 2860 cm^–1 to CH₂ groups directly bound to the active site and those at 2920 and 2850 to CH₂s in the growing chain well removed from the Cr. The peaks at 2160 and 2165 cm^–1 are attributed to CD₂ groups hydrogen bonded to surface hydroxyls.     

Transport of chromium(VI) through a Cyanex 921‐supported liquid membrane from HCl solutions

The transport of chromium(VI) through a flat‐sheet supported liquid membrane containing Cyanex 921 as a carrier has been investigated. The permeation of the metal is investigated as a function of various experimental variables: hydrodynamic conditions, concentration of chromium(VI) and HCl in the feed phase, carrier concentration and diluent in the membrane and strippant concentration in the stripping phase. The mass transfer coefficient and the thickness of the aqueous boundary layer were calculated from the experimental data. Furthermore, the selectivity of Cyanex 921‐based flat‐sheet supported liquid membrane towards different metal ions and the behaviour of the system against other carriers are presented. Copyright © 2003 Society of Chemical Industry     

U(Ⅳ)-U(Ⅵ)同位素交换反应动力学研究 Ⅰ.Fe~(2+)对U(Ⅳ)-U(Ⅵ)同位素交换反应的催化作用

一、前言由于U(IV)-U(VI)同位素交换体系具有相当大的同位素效应和很好的稳定性,并且容易实现两相回流,这对于分离U同位素的工业应用都是十分有利的。但是,U(IV)-U(VI)同位素交换反应速度非常慢,常温下H~+浓度为1.0—4.0 mol/l时,速度常数为1.0×10~(-4)l~2/mol·s。因此要用U(IV)-U(VI)交换体系浓缩铀同位素,必须研究U(IV)-U(VI)交换反应动力学,找到加快交换反应的方法。     

Cr12MoV钢冷挤压成形模强化工艺的研究

针对Crl2MoV钢冷挤压成形模热处理存在的质量问题，对加热温度和方式进行了大量的试验研究，在此基础上，提出了改进的快速加热工艺。结果表明，经该工艺处理后，模具使用寿命得到显提高。     

Simulation of the Forming Behaviour of a Boron Modified P91 Ferritic Steel

The forming behaviour at high temperature of a modified 9%Cr‐1%Mo (P91) ferritic steel containing B and Ti for elevated temperature service was investigated. The microstructure of the as‐received material is mainly martensite at room temperature, but special etching revealed prior austenite grains of about 25 μm in size. Torsion tests were conducted at temperatures in the range 850 to 1250 °C to simulate the hot rolling process under comparable conditions of temperature, strain rate and strain. The deformation data obtained from these tests were correlated with the Garofalo equation with a stress exponent of 4.6 and an activation energy of 315 kJ/mol. This equation was used to predict the formability behaviour for the rolling process and also to determine the maximum forming efficiency and stability of the steel. A temperature of 1200 °C is recommended to conduct the forming process.     

Cr12型模具钢锻造内部裂纹产生的原因及预防

基于Cr12型钢种的特点，归纳了Cr12钢锻造时内部裂纹的类型，分析了内部裂纹产生的原因并提出了相应的预防措施。     

控制W9Cr3Mo4V低倍碳化物剥落的工艺改进

针对W9Cr3M04V轧制成品材低倍碳化物剥落的形成原因分析，得出一次碳化物颗粒粗大、在1／4D至中心区域聚集是导致低倍热酸浸试验碳化物剥落的主因；由此进行冶炼过程中注速（锭形）、浇注温度选择对比工艺试验，得出在原有冶炼＋轧制的工艺基础上选用2．2t锭、降低浇注温度（1489℃）能有效改善一次碳化物颗粒大小和聚集程度，进而有效降低低倍碳化物剥落倾向。     

提高Cr12MoV钢冷作模具寿命的措施

从原材料改锻、预备热处理、淬火及回火、深冷处理、表面强化处理等方面分析介绍了提高Cr12MoV钢冷作模具寿命的一些方法和措施 ,并通过实例表明 ,采用这些方法和措施可较大幅度地提高模具寿命     

IR study of the interaction of hydroxyl groups of silica gel with Cr species of Phillips' type catalysts

Spectroscopic evidence for the interaction of hydroxyl groups and chromium ions was obtained using a catalyst prepared from chromyl chloride. A new OH peak, observed at 3705 cm^–1 after pumping away CO gas, is attributed to the direct interaction of OH with the low-valent chromium. This peak shifts to 3590 cm^–1 on contact with O₂ at room temperature and it is assigned to a hydroxyl interacting with the oxidized chromium. New assignments are also proposed for IR bands of CO presorbed on the catalyst. The peak due to CO at 2188 cm^–1 decreases as the OH intensity at 3705 cm^–1 increases, suggesting that the former peak arises from adsorption on Cr(II) species to which two oxygen atoms are attached.