基于一类新的强化缓冲算子的GM(1,1)预测精度研究

根据灰色系统理论中新息优先利用原理,在对缓冲算子和已有强化缓冲算子研究的基础上,构造了一类新的强化缓冲算子,有效解决了冲击扰动数据序列在建模预测过程中常常出现的定量预测结果与定性分析结论不符的问题.实例分析结果表明,这类新的强化缓冲算子能显著提高GM(1,1)模型的预测精度.     

Controller synthesis with guaranteed closed-loop phase constraints

In this paper, we present an analysis and synthesis approach for guaranteeing that the phase of a single-input, single-output closed-loop transfer function is contained in the interval [−α,α] for a given α>0 at all frequencies. Specifically, we first derive a sufficient condition involving a frequency domain inequality for guaranteeing a given phase constraint. Next, we use the Kalman–Yakubovich–Popov theorem to derive an equivalent time domain condition. In the case where , we show that frequency and time domain sufficient conditions specialize to the positivity theorem. Furthermore, using linear matrix inequalities, we develop a controller synthesis approach for guaranteeing a phase constraint on the closed-loop transfer function. Finally, we extend this synthesis approach to address mixed gain and phase constraints on the closed-loop transfer function.     

Phase Separation Derived Core/Shell Structured Cu11V6O26/V2O5 Microspheres: First Synthesis and Excellent Lithium‐Ion Anode Performance with Outstanding Capacity Self‐Restoration

Novel amorphous vanadium oxide coated copper vanadium oxide (Cu₁₁V₆O₂₆/V₂O₅) microspheres with 3D hierarchical architecture have been successfully prepared via a microwave‐assisted solution method and subsequent annealing induced phase separation process. Pure Cu₁₁V₆O₂₆ microspheres without V₂O₅ coating are also obtained by an H₂O₂ solution dissolving treatment. When evaluated as an anode material for lithium‐ion batteries (LIBs), the as‐synthesized hybrid exhibits large reversible capacity, excellent rate capability, and outstanding capacity self‐recovery. Under the condition of high current density of 1 A g^?1, the 3D hierarchical Cu₁₁V₆O₂₆/V₂O₅ hybrid maintains a reversible capacity of ≈1110 mA h g^?1. Combined electrochemical analysis and high‐resolution transmission electron microscopy observation during cycling reveals that the amorphous V₂O₅ coating plays an important role on enhancing the electrochemical performances and capacity self‐recovery, which provides an active amorphous protective layer and abundant grain interfaces for efficient inserting and extracting of Li‐ion. As a result, this new copper vanadium oxide hybrid is proposed as a promising anode material for LIBs.     

固溶处理对TC11钛合金棒材组织和性能的影响

通过场发射扫描电镜及拉伸性能测试,研究了TC11钛合金棒材3种固溶处理时间和2种固溶方式对显微组织及力学性能的影响。结果表明:TC11钛合金在经过3 h的固溶后,组织中局部的亚稳定β晶体位相发生偏转,β转变组织中的次生α相变的粗大,经过后续时效后的β转变基体发生更为充分的分解和析出,在片层的β边界出现连续的更细小的次生α相。由于固溶时间延长,发生了过固溶,析出的次生相逐渐细小,导致裂纹扩展阻力降低,引起屈服强度的降低,分开各1 h的固溶时效性能低于连续2 h的固溶时效性能。     

Effects of microstructure on fatigue crack propagation behavior in a bi-modal TC11 titanium alloy fabricated via laser additive manufacturing

In this study, the crack propagation behaviors in the equiaxed and equiaxed-columnar grain regions of a heat-treated laser additive manufacturing (LAM) TC11 alloy with a special bi-modal microstructure are investigated. The results indicate that the alloy presents a special bi-modal microstructure that comprises a fork-like primary α (α_p) phase surrounded by a secondary α colony (α_s) in the β phase matrix after the heat treatment is completed. The samples demonstrate a fast crack growth rate with larger da/dN values through the equiaxed grain sample versus across the equiaxed-columnar grain sample at low ΔK values (<13.8). The differences that are observed between the crack propagation behaviors (in the crack initiation stage) of the samples can be mostly attributed to the different size and morphology of the α_p lamellae and α_s colony within the grains in the equiaxed and columnar grain regions rather than the grain boundaries. The cracks prefer to grow along the α/β boundary with a smooth propagation route and a fast propagation rate in the equiaxed grain region, where the α_p and α clusters have a large size. However, in the columnar grain region, small and randomly distributed α_p lamellae generate a zigzag-shaped propagation path with a reduction in the da/dN value. Additionally, the change in the size of the α_p lamellae in the equiaxed grains (heat affected bands, HAB) is also observed to influence the propagation behavior of the crack during the crack initiation stage.     

TC11钛合金中α'相和α'相的组织演变和显微硬度

研究了TC11钛合金中α"相和α'相的显微组织转变和显微硬度。金相显微组织观察和X射线衍射分析的结果表明： 随着固溶温度的提高α"相逐渐向α'相的晶体结构转变,α相、α"相和α'相的显微组织演变规律为：α+α",α+α"+α',α+α',α'。显微硬度测试的结果表明：在935~995℃固溶后显微硬度随着温度的提高先增大后减少,在985℃固溶后显微硬度达到峰值。综合分析显微组织影响合金显微硬度的机理：在935~985℃固溶后α'片层的厚度和间距变化的幅度小,β转变组织长大缓慢,在β转变组织中先后析出α"和α'相,随着固溶温度的提高α'片层的含量随之提高产生了相变强度效果,使其显微硬度提高;在985~995℃固溶后α'片层的厚度和间距明显增大,β转变组织变粗大,α"相消失,α'相的含量降低,相变强化的效果减弱,使β转变组织的显微硬度降低。     

通过VXI-11协议控制LXI仪器

LXI是一种基于局域网的新型模块化仪器互联标准,VXI-11协议在LXI仪器中具有重要的作用。LXI使用VXI-11协议作为仪器发现机制,并通过其对LXI仪器进行访问。为了将LXI这一新型网络标准更广泛的推广和应用,针对LXI仪器的网络特性,对VXI-11协议和RPC协议进行了一系列研究,并详细阐述了在Windows环境下使用RPC协议来实现VXI-11客户端,从而控制LXI仪器。实验结果表明,分析正确、实现合理、功能准确,可应用于LXI标准的仪器设备开发中。     

面向Oracle 11g的语义查询集成平台

在VOEditor本体可视化编辑器的基础上,结合本体的相关知识,采用Oracle 11g和其他推理引擎的语义技术,开发一个基于语义的信息查询集成平台原型系统,介绍其体系结构、主要查询机制、实现技术及初步使用情况。结果表明,该系统能对知识库进行不同程度的推理查询,并能支持大型的语义应用。     

Forecasting conditional correlations in stock,bond and foreign exchange markets

The paper forecasts conditional correlations between three classes of international financial assets, namely stock, bond and foreign exchange. Two countries are considered, namely Australia and New Zealand. Forecasting will be conducted using three multivariate GARCH models, namely the CCC model [T. Bollerslev, Modelling the coherence in short-run nominal exchange rates: a multivariate generalized ARCH model, Rev. Econ. Stat. 72 (1990) 498–505], VARMA-GARCH model [S. Ling, M. McAleer, Asymptotic theory for a vector ARMA-GARCH model, Econometric Theory 19 (2003) 280–310], and VARMA-AGARCH model [M. McAleer, S. Hoti, F. Chan, Structure and asymptotic theory for multivariate asymmetric volatility, Econometric Rev., in press]. A rolling window technique is used to forecast 1-day ahead conditional correlations. To evaluate the impact of model specification on conditional correlations forecasts, this paper calculates and compares the correlations between conditional correlations forecasts resulted from the three models. The paper finds the evidence of volatility spillovers and asymmetric effect of negative and positive shock on the conditional variance in most pairs of series. However, it suggests that incorporating volatility spillovers and asymmetric do not contribute to better conditional correlations forecasts.