双波长分光光度法测定自来水中Fe2+和Fe3+的含量

采用双波长分光光度法测定 Fe2 和 Fe3 的方法 ,结果表明 ,在 λ1 =4 0 0 nm,λ2 =5 4 2 nm处 ,显色时间在 6 0 min～ 80 min,p H =4～ 5时能联合测定水中 Fe2 和 Fe3 ,其结果具有较高的精密度和准确度。     

5—烃基—2,3—二甲基吡嗪的合成

2,3-二基-5,6-二氢吡嗪与醛或酮在氢氧化钠的乙醇溶液中反应制得16种5-烃基-2,3-二甲基吡嗪。产率66%～90%。其中6种为新合成的化合物。产率17%～87.9%。     

Aplysia sea hare assimilation of secondary metabolites from brown seaweed,Stypopodium zonale

JuvenileAplysia dactylomela were found feeding in abundance on the tropical brown algaStypopodium zonale, a seaweed previously shown to contain numerous unique terpene-quinone natural products. Lipid extracts of these herbivorous mollusks were shown by TLC and HPLC-NMR analyses to contain appreciable quantities of twoS. zonale metabolites as well as one new but closely related compound. Spectroscopic analyses of the new compound in concert with functional group modifications identified this new compound as 3-keto epitaondiol. A careful analysis of the seaweed extract failed to locate this ketone, and thus, it most likely represents anAplysia-biotransformed compound. This is the first clear reported observation of metabolite transfer between an alga of the phylum Phaeophyta and a sea hare.     

A 3D analysis of the joint torques developed during driver's ingress–egress motion

Providing an easy ingress–egress (I/E) movement remains a challenge for car designers. I/E has been largely studied in kinematics, but not in dynamics. This study proposes: (1) to evaluate and describe the motor torques developed in the lower limbs and lumbar joints during I/E motions and (2) to analyse the influence of the car geometry and subject anthropometry. An experiment was performed to observe 15 subjects of three anthropometrical groups getting in and out of a car mock-up simulating three different vehicle configurations. Motor torques were extracted using an inverse dynamics analysis. Both ingress and egress motions were primarily characterised by large torques. Overall, the taller a subject and the lower the seat of the vehicle were, the larger the peak torques were. Moreover, peak torques were higher for egress than ingress. These results are discussed in regard to the current knowledge on I/E ergonomics.     

基于S3C6410的远程无线环境监测系统设计

从实际应用出发并结合近年来环境监测技术的发展趋势,设计了一套以S3C6410为主要硬件平台、以嵌入式Linux为主要软件平台的远程环境监测系统。该系统采用B/S架构,具有低成本、低功耗、高稳定的特点。用户通过Internet上的任何终端(如电脑、手机等)来访问该系统,可非常方便地对监测区域进行实时的监测。该系统支持多个用户同时登陆,兼容多种浏览器,具有较高的安全性,在环保行业、制造行业、交通行业的环境监测方面具有一定的推广应用价值。     

Virtual machining considering dimensional,geometrical and tool deflection errors in three-axis CNC milling machines

Virtual manufacturing systems can provide useful means for products to be manufactured without the need of physical testing on the shop floor. As a result, the time and cost of part production can be decreased. There are different error sources in machine tools such as tool deflection, geometrical deviations of moving axis and thermal distortions of machine tool structures. Some of these errors can be decreased by controlling the machining process and environmental parameters. However other errors like tool deflection and geometrical errors which have a big portion of the total error, need more attention. This paper presents a virtual machining system in order to enforce dimensional, geometrical and tool deflection errors in three-axis milling operations. The system receives 21 dimensional and geometrical errors of a machine tool and machining codes of a specific part as input. The output of the system is the modified codes which will produce actual machined part in the virtual environment.     

熔块釉中三氧化二硼的测定

用NaOH熔融样品，向标准溶液中加入同样量的KOH基体，建立工作曲线，试样酸化后，直接用ICP－AES法测定。     

基于XC2287M的工程机械ECU设计

ECU是工程机械电控系统的核心部件,目前国内中高端ECU市场基本被国外厂商所垄断。设计了一款基于XC2287M微控制器的工程机械智能ECU,采用CODESYS软PLC作为编程平台,支持IEC 61131-3定义的5种标准PLC语言进行编程。所设计的ECU拥有丰富的I/O资源和完善的安全保护机制,能够广泛应用于各种工程机械控制系统,打破国外厂商对ECU市场的垄断。     

Effect of Pt Incorporation into Ni/ZrO2–SO 4 = /Al2O3 Catalyst for n-Butane Isomerization

Three Ni/ZrO₂–SO₄⁼/Al₂O₃ catalysts with different concentrations of platinum (0.2, 0.3 and 0.4 wt%) were prepare and tested for n-butane isomerization reaction at 338 K, in absence and in presence of hydrogen. The results shown that, at low temperature, platinum contributes to the olefin or butyl ion formation and the reaction follows a bimolecular pathway. However, when the reaction occurs in the presence of hydrogen, the formation of butyl ions is inhibited. The main feature of platinum addition is the stabilization of the catalytic activity, which is indicated by the slow deactivation constants compared to that of the unpromoted catalyst.     

2,2′-oxo-1,1′-azobenzene: microbial transformation of rye (Secale cereale L.) allelochemical in field soils byAcinetobacter calcoaceticus: III

Acinetobacter calcoaceticus, a gram-negative bacterium isolated from field soil, was found to be responsible for the biotransformation of 2(3H)-benzoxazolinone (BOA) to 2,2-oxo-1,1-azobenzene (AZOB). Experiments were conducted to evaluate the transformation of BOA to AZOB by this microbe in sterile and nonsterile soil. Transformation studies with soils inoculated withA. calcoaceticus indicated that the production of AZOB increased linearly with the concentration of BOA in sterile soil and showed a quadratic trend in nonsterile soils. This also indicated that all soil types studied for the transformation experiments might containA. calcoaceticus capable of the conversion of benzoxazolinones.