全文获取类型
收费全文 | 190571篇 |
免费 | 24128篇 |
国内免费 | 23933篇 |
专业分类
电工技术 | 18534篇 |
技术理论 | 8篇 |
综合类 | 13295篇 |
化学工业 | 39560篇 |
金属工艺 | 7589篇 |
机械仪表 | 11949篇 |
建筑科学 | 8538篇 |
矿业工程 | 2133篇 |
能源动力 | 5931篇 |
轻工业 | 14492篇 |
水利工程 | 2437篇 |
石油天然气 | 4139篇 |
武器工业 | 1926篇 |
无线电 | 30621篇 |
一般工业技术 | 20618篇 |
冶金工业 | 4100篇 |
原子能技术 | 3250篇 |
自动化技术 | 49512篇 |
出版年
2024年 | 1057篇 |
2023年 | 3543篇 |
2022年 | 6349篇 |
2021年 | 7305篇 |
2020年 | 6958篇 |
2019年 | 6320篇 |
2018年 | 5897篇 |
2017年 | 7923篇 |
2016年 | 8623篇 |
2015年 | 9768篇 |
2014年 | 9400篇 |
2013年 | 12606篇 |
2012年 | 14332篇 |
2011年 | 16151篇 |
2010年 | 11579篇 |
2009年 | 11392篇 |
2008年 | 12661篇 |
2007年 | 14055篇 |
2006年 | 13415篇 |
2005年 | 11481篇 |
2004年 | 9729篇 |
2003年 | 7617篇 |
2002年 | 5817篇 |
2001年 | 4403篇 |
2000年 | 3675篇 |
1999年 | 3067篇 |
1998年 | 2546篇 |
1997年 | 2044篇 |
1996年 | 1619篇 |
1995年 | 1342篇 |
1994年 | 1190篇 |
1993年 | 888篇 |
1992年 | 716篇 |
1991年 | 579篇 |
1990年 | 497篇 |
1989年 | 356篇 |
1988年 | 281篇 |
1987年 | 175篇 |
1986年 | 167篇 |
1985年 | 225篇 |
1984年 | 194篇 |
1983年 | 138篇 |
1982年 | 193篇 |
1981年 | 94篇 |
1980年 | 95篇 |
1979年 | 23篇 |
1978年 | 15篇 |
1977年 | 23篇 |
1976年 | 14篇 |
1959年 | 18篇 |
排序方式: 共有10000条查询结果,搜索用时 9 毫秒
991.
Rubber‐toughened polypropylene (PP)/org‐Montmorillonite (org‐MMT) nanocomposite with polyethylene octene (POE) copolymer were compounded in a twin‐screw extruder at 230°C and injection‐molded. The POE used had 25 wt % 1‐octene content and the weight fraction of POE in the blend was varied in the range of 0–20 wt %. X‐ray diffraction analysis (XRD) revealed that an intercalation org‐MMT silicate layer structure was formed in rubber‐toughened polypropylene nanocomposites (RTPPNC). Izod impact measurements indicated that the addition of POE led to a significant improvement in the impact strength of the RTPPNC, from 6.2 kJ/m2 in untoughened PP nanocomposites to 17.8 kJ/m2 in RTPPNC containing 20 wt % POE. This shows that the POE elastomer was very effective in converting brittle PP nanocomposites into tough nanocomposites. However, the Young's modulus, tensile strength, flexural modulus, and flexural strength of the blends decreased with respect to the PP nanocomposites, as the weight fraction of POE was increased to 20 wt %. Scanning electron microscopy (SEM) was used for the investigation of the phase morphology and rubber particles size. SEM study revealed a two‐phase morphology where POE, as droplets was dispersed finely and uniformly in the PP matrix. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3441–3450, 2006 相似文献
992.
993.
用5-硝基糠叉二醋酸酯与环己酮在60%H3PO4溶液中缩合制得标题物。反应混合物在100℃下搅拌反应5h得61%的2,6-双(5-硝基-2-糠叉)环己酮。分别经IR、1HNMR、MS、UV、TLC和元素分析进行了表征和鉴定。 相似文献
994.
The high melting point of poly(1,4‐cyclohexanedicarboxylic anhydride) [poly(CHDA)] is a disadvantage, in that it is intractable in the melting process of a drug delivery system. This report relates to diols introduced into the polyanhydride main chain to decrease its melting point. Various poly(ester anhydride)s containing ethylene glycol, 1,3‐propanediol, 1,4‐butanediol, or 1,6‐hexandiol [poly(CHDA–XDO)] were synthesized by the esterification reaction and melt polycondensation. FTIR, DSC, WAXD, and intrinsic viscosity of polymers were recorded and hydrolytic degradation, as well as in vitro drug delivery, was conducted. The results show that the samples are stable in an anhydrous environment at room temperature and degrade in water following a surface erosion mechanism. The degradation period of poly(CHDA–XDO) ranged from 130 to 320 h as a result of the different diols and amounts of XDO introduced. The in vitro drug delivery gave 130–350 h of stable delivery along with the typical surface erosion mechanism. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2509–2514, 2002 相似文献
995.
Murray S. Blum Ray F. Severson Richard F. Arrendale Douglas W. Whitman Pierre Escoubas Olushola Adeyeye Clive G. Jones 《Journal of chemical ecology》1990,16(1):223-244
Adults of a generalist herbivore, the lubber grasshopper,Romalea guttata, can be converted to functional specialists by feeding them exclusively on catnip,Nepeta cataria. No obvious adverse effects on adult development resulted from this enforced monophagy. Notwithstanding the fact thatR. guttata has had no coevolutionary relationship with this Eurasian mint, it readily sequesters compounds that are identical to or derived from the terpenoid lactones that are characteristic ofN. cataria. R. guttata appears to both biomagnify minor allelochemicals and to sequester metabolites of theNepeta terpenes in its paired defensive glands. The levels of autogenously produced phenolics are not affected by feeding onN. cataria and the defensive secretions of catnip-fed grasshoppers are more repellent to ants than those of wild-fed acridids. Metabolites of theN. cataria monoterpenes are sequestered in the defensive glands when catnip is added to the natural diet ofR. guttata. The ability of a generalist,R. guttata, to facilely bioaccumulate a potpourri of foreign allelochemicals when feeding in a specialist mode is analyzed in terms of its biochemical, physiological, and functional significance. Sequestration is examined as a response to the enteric effronteries represented by the phytochemicals that can be characteristic of the overload in a monophagous diet. 相似文献
996.
Ramie yarns were treated with various concentrations of NaOH at room temperature and subsequently crosslinked with 1,2,3,4‐butanetetracarboxylic acid (BTCA). The microstructure and tensile properties of the treated yarns were characterized. X‐ray diffraction (XRD) and FTIR were used to study the crystalline structure of the resultant ramie yarns. The results showed that the maximum change in the structure of the alkali‐modified ramie took place at 16% NaOH, which would completely transform cellulose I to cellulose II. At the same time, the crystallinity index and fiber orientation decreased to the minimum value while the absorption properties were enhanced. The average degree of polymerization (DP ) of the treated ramie yarns slightly decreased after NaOH treatment. Tensile properties including tenacity, breaking elongation, and modulus of the treated yarns were also investigated. Scanning electron microscopy (SEM) was used to investigate the breakage of the treated yarns. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1857–1864, 2004 相似文献
997.
D. S. Rosa I. Chiovatto Neto M. R. Calil A. G. Pedroso C. P. Fonseca S. Neves 《应用聚合物科学杂志》2004,91(6):3909-3914
The thermal and mechanical properties of low‐density polyethylene (LDPE), poly(ε‐caprolactone) (PCL), and their blends were evaluated. Differential scanning calorimetry showed that increasing the PCL content of the blend did not change the LDPE melting temperature, but reduced the crystallinity by up to 16.8%. This behavior was related to interactions between the PCL chains and the crystalline phase of LDPE. Tensile strength and elongation at break values for the blends were lower than those for the pure polymers, which suggested an incompatibility between the polymers. The values for Young's modulus under tensile increased when PCL was added to LDPE. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91:3909–3914, 2004 相似文献
998.
Yiming Zeng Zhigang Wang Lijun Wan Yanqiao Shi Guanwen Chen Chunli Bai 《应用聚合物科学杂志》2003,88(5):1328-1335
By the use of atomic force microscopy (AFM), formation mechanism of nodular structure in cellulose acetate membranes was systematically investigated. Elementary factors affecting the nodule formation were delineated on the basis of both kinetic and thermodynamic considerations. It was shown that (1) the exact nature of nodular structure is thermodynamic equilibrium glassy state; nodular structure will vanish in the rubbery state; (2) the thermodynamic factor affecting nodule formation is the membrane formation temperature; with the membrane formation temperature decreasing, more chain segments are able to form nodular structures; (3) nodule formation is dependent on the segment rearrangement; variation of the solvent environment is the major kinetic factor affecting the segment rearrangement and nodule formation. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 1328–1335, 2003 相似文献
999.
为探究川中丘陵区干湿动态动力学机制,提供旱涝预测的理论依据。根据川中丘陵区8个气象站点1958~2013年逐日气象资料,采用Penman—Monteith 模型计算潜在蒸散量,构建出湿润指数。在此基础上,基于去趋势波动分析方法(DFA),对逐月、分季节、极端干湿湿润指数进行长程相关性分析,并探讨了影响湿润指数长程相关性的气象因子。结果表明:除南充、遂宁外,其余地区逐月湿润指数变化长程相关,并非完全随机;分季节与极端干湿湿润指数均具有长程相关性;对于不同季节而言,长程相关性以夏季最强,秋、冬两季次之,春季最弱,对于极端气候而言,极端湿润长程相关性强于极端干旱;通过对湿润指数与气象因子长程相关性一致性分析,降水标度指数与湿润指数标度指数呈显著正相关。 相似文献
1000.
考察了Pd/Al2O3、In/Al2O3和Co/Al2O3对甲烷选择性还原NO的催化活性。结果表明,采用浸渍法制备的Pd/Al2O3、In/Al2O3和Co/Al2O3三种催化剂,在有氧气氛下,用CH4作还原剂催化还原NO时,Pd/Al2O3催化剂的活性最佳,热稳定性好,在550 ℃,用CH4选择还原NO,Pd/Al2O3催化剂表现出较强的催化能力,NO的转化率达到100%。在高空速实验中,该催化剂亦表现出较高的活性,其活性顺序为Pd/Al2O3>In/Al2O3>Co/Al2O3。实验研究了助催化剂、氧含量以及空速对Pd/Al2O3催化剂活性的影响。 相似文献