Improvement of the deflocculating power of polyacrylates in ceramic slips by small additions of quaternary ammonium salts

In this work, we examine the effect of small additions of cationic quaternary ammonium salts (QAS) of different molecular weight on the rheology of an industrial ceramic suspension deflocculated with sodium polyacrylate and sodium metasilicate. The observed shear thinning behaviors obey the typical power law of fluid rheology. In order to characterize the rheological behavior of these slurries, three new parameters are introduced: a low shear rate consistency index and two transient viscosities, distant from the equilibrium, after increasing and decreasing the shear rates. These parameters vary with polyacrylate molecular weight and on additions of small quantities of QAS, which we found to be useful for decreasing the slurry viscosity.     

准噶尔盆地腹部超压层分布研究

准噶尔盆地腹部普遍发育深层（大于4000m）超压系统，很多钻井都钻遇超压。通过对超压段钻井、地质、测井、地震特征系统研究发现，超压段泥浆密度大幅增加，具有高声波时差、低电阻率以及地震低速的超压响应特征。利用Dix公式计算地震层速度和利用Fillippone公式计算地层压力，得到超压数据体。准噶尔盆地腹部超压在白垩系及其以下沉积地层中均有分布，超压层的深度范围不同。分1井西凹陷边缘以及昌吉凹陷西南有空层现象。超压顶面分布的层位由北往南、从东到西逐渐变浅，从三叠系顶部到白垩系底部。深部超压对油气分布和富集有着重要的控制作用，准噶尔盆地腹部超压层分布的研究将对本区油气勘探起积极的推动作用。     

Chirality-antimicrobial relationship of quaternary ammonium cationics

Optically active and racemic quaternary ammonium cationics containing a chiral alkyl group, such as N,N-dimethyl-N-(1-phenylethyl)alkylammonium bromides were prepared and showed excellent antimicrobial properties against Gram positive and negative bacteria, with some exceptions, and against fungi. The influence of optical isomerism on their antimicrobial properties showed that the antimicrobial properties between racemic and optically active cationics were obscure. The order of activity of substituted alkyl groups was tetradecyl > dodecyl ° hexadecyl.     

应用烃类直接检测技术预测天然气藏

柴达木盆地位于青藏高原北部，是中国大型含油气盆地之一，历经４０年的勘探，发现了丰富的油气资源。柴达木盆地东部地区是第四纪沉降与沉积中心，区内第二系生储气岩厚度大、分布广、第四纪新构造运动形成的同生沉积构造发育、保存完整、具有形成大中型天然气田的地质条件。此外，由于该地区含气地层时代新、埋藏浅、成岩与胶结作用差、含气层厚度大、孔渗性好，加之构造条件简单，人文干扰小、是应用烃直接检测技术寻找天然气的有     

一种新型针状合金-金刚石复合钻头胎体配方的试验研究

本文首先介绍一种用于卵砾石地层钻进的新型针状硬质合金钻头的设计原理，而后简要说明其胎体配方组成机理。在分析胎体性能要求的基础上，选择了六组配方，对其进行抗弯强度、抗剪强度，硬度性能、冲击韧性、SEM照片等试验，优选了四号配方，试制了钻头。生产试验结果表明，这种新型复合型钻头钻进萝日砾石地层的平均时效1．89m／h、平均每回次进尺为2．3m，平均钻头寿命19．81m，具有实用和推广价值。     

季胺萃取锌的动力学研究

以恒界面池法研究了氯化物介质中季胺萃锌的动力学。考查了搅拌转速、传质界面积和温度对萃取速率的影响，判定季爱萃锌为界面化学反应的动力学模式。进一步研究了季胺萃取剂浓度和水相Ｚｎ＾２＋浓度对萃取速率的影响，得到了与理论推断相吻合的速率方程。     

高压大流量地下水隧道开挖超前帷幕注浆参数研究

锦屏水电站锦屏山隧道开挖中面临高压大流量地下水、且富水地段长(约占隧道全长的40%)的难题。为安全、可靠地进行隧道施工,以注浆材料的适应性、超前帷幕注浆的参数及工艺为研究对象,对浆液做了大量配合比试验,分析其流动性、物理力学性能和凝结时间。研究结果表明:用纯水泥进行单液浆帷幕注浆,其可注性好,可大大地提高注浆加固效果;纯水泥+双液浆对局部小的渗漏水具有很好的封堵效果。对于低于2 MPa的压力水,注浆压力取2~3倍的静水压力;对于高于5 MPa的压力水,注浆压力取净水压力加2~3 MPa。对于在2~5 MPa之间的压力水,注浆压力可灵活选取,但不宜超过7 MPa,注浆应采用孔内循环灌注的方式。地下水发生在断层破碎带时,超前帷幕注浆宜采用全断面帷幕;若出水段以溶蚀裂隙、断层、管道为主宜采用有针对性的局部超前帷幕注浆。该技术成功解决了锦屏山隧道高压大流量地下水封堵的难题,对富水地层地下隧洞施工具有重要参考价值。     

Liquid-liquid equilibrium for the quaternary system of o-xylene(1)+water(2) +propionic acid(3)+1-butanol(4) at 298.15 K and atmospheric pressure

The liquid-liquid equilibrium for the quaternary system of o-xylene(1)+water(2)+propionic acid(3)+1-butanol(4) was measured at 298.15 K and atmospheric pressure. Binodal curves, tie-lines, a distribution curve, and a selectivity curve for the quaternary system have been determined in order to investigate the effect of binary solvents, oxylene and 1-butanol, on extracting propionic acid from aqueous solution. In addition, these experimental tie line data were also compared with the values predicted by the UNIFAC model. In this study, the UNIFAC model was capable of predicting the compositions of this quaternary system within an average RMSD of 1.13 mol%. This paper was prepared at the 2004 Korea/Japan/Taiwan Chemical Engineering Conference held at Busan, Korea between November 3 and 4, 2004.     

Effect of Ca~(2+) on CO_2 corrosion properties of X65 pipeline steel

The effect of Ca~(2+) on CO_2 corrosion to X65 pipeline steel was investigated in the simulated stratum water of an oil field containing different concentrations of Ca~(2+). It is found that Ca~(2+) can enhance the corrosion rate,especially in the Ca~(2+) concentration from 256 to 512 mg/L,which can be attributed to the growing grain size and loosing structure of corrosion scales with increasing Ca~(2+) concentration. X-ray diffraction(XRD) and X-ray photoelectron spectroscopy(XPS) investigations reveal that a complex carbonate (Fe, Ca)CO_3 forms at high Ca~(2+) concentration due to the gradual replacement of Fe~(2+) in FeCO_3 by Ca~(2+).     

浅埋暗挖地铁车站管棚的数值模拟及其加固效果分析

以北京地铁十号线黄庄站126 m超前大管棚一次性施作作为研究背景,在对管棚作用效果和作用机理分析的基础上,比较了现有管棚计算模型的优劣,提出了在数值计算中采用桩单元模拟管棚的思路;对车站导洞施工过程中管棚变形的动态过程以及管棚注浆和管棚直径对地表沉降的控制效果进行了分析研究.监测数据表明:北京地铁十号线黄庄站管棚施作后,四导洞开挖完成后地表沉降控制在30 mm左右,与四号线黄庄站四导洞完成后地表80 mm的沉降值相比大大减小,起到了良好的控制作用.