输出电流达200mA的双极性电流源

本文介绍一种稳幅式双极性电流源,它是根据自动控制原理设计而成的,用于连续铸造熔渣的检测.     

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与常规水泥浆固井技术相比,MTC固井技术具有明显的技术、经济优势。但是,由于低密度、超低密度矿渣MTC固井液体系中含有大量的低密度减轻材料和泥浆处理剂,同时,矿渣只具备潜在的水化反映活性。因此,体系的强度与同等密度的水泥浆相比有些偏低,从而限制了其在低压易漏地层固井中的应用。新疆石油管理局钻井工艺研究院通过大量的实验研究,开发出一种适于新疆油田多种泥浆体系的矿渣MTC高效促凝剂。室内检测结果表明,该促凝剂：①可显著提高矿渣MTC在低温下的早期强度;②所配矿渣MTC的稠化时间随其加量的变化、随设计温度的变化近似呈线性变化,因此,可通过其加量的变化灵活调节矿渣MTC在低温下的稠化时间;③不影响体系的流变性及流动能力,可与分散剂配合使用,灵活调节体系的流变性,从而有效解决低密度、超低密度矿渣MTC低温早期强度偏低的问题。     

增进核电焊材用钢508 Ⅲ洁净度的工艺实践

核电焊材用钢508 Ⅲ（/%:0.09~0.12C,0.30~0.40Si,1.45~1.65Mn,≤0.008P,≤0.008S,0.45~0.60Mo,0.60~0.75Ni）的生产工艺流程为20t EAF-LF-VD-4t铸锭-锻造150 mm×150 mm坯-轧制Φ5.5mm盘条。采用精选炉料,以及高碱度渣、高FeO含量,钢水温度1550~1570℃等措施控制,电弧炉终点[P]≤0.002%,并选用低磷合金,使钢中磷含量≤0.006%;LF采用硅钙合金沉淀脱氧,SiC粉扩散脱氧、CaO-Al₂O₃-SiO₂渣系,碱度5.0~5.5,VD真空度≤67Pa,Ar流量30~50 L/min,保护浇铸等措施后,3炉钢的分析结果表明,钢中气体含量为1.3×10^-6~1.5×10^-6[H],10×10^-6~14×10^-6[O]和44×10^-6~58×10^-6[N],满足核电焊材用钢508Ⅲ洁净度的要求。     

Mn对含炭耐火材料抗渣侵蚀性的影响

以烧结板状刚玉、锆莫来石、天然鳞片状石墨为主原料 ,酚醛树脂为结合剂 ,Al、Si、B4C、Mn粉为添加剂 ,经 1 4 50℃埋炭烧成后 ,制成铝炭和铝锆炭系列试样 ,并对各试样的抗渣侵蚀性能进行了对比研究。结果表明 :在铝锆炭材料中 ,当Mn与Al、Si复合加入且Mn与C的质量比为 1∶4时 ,试样的抗侵蚀性和渗透性均较好 ;在铝炭材料中 ,当Mn与Al、Si、B4C复合加入且Mn与C的质量比为 1∶4时 ,试样的抗渗透性较好     

Operation performance of a pilot-scale gasification/melting process for liquid and slurry-type wastes

A gasification/melting facility that can operate up to 10 bar and 1,550 °C with a maximum 1 ton/day capacity was developed for liquid and slurry-type combustible wastes. The main focus of the system development was minimal use of expensive fuel for maintaining the reaction temperature by replacing it with cheap waste oil for energy input. The carbon conversion obtained was 97% while the cold gas efficiency reached 77.6% for the refined waste oil. When the feed was refined oil mixed with fly ash from a municipal waste incinerator, the carbon conversion and cold gas efficiency were 93% and 71.9%, respectively, with a slag conversion ratio of 0.93. The slag produced from fly ash exhibited environmentally acceptable heavy-metal leaching values and thus can be applicable as road material and for other purposes. The optimal O₂/feed ratio was 0.9–1.0 when only the refined waste oil was gasified, whereas the O₂/feed ratio had to be higher than 1.2 when fly ash was mixed. In addition, data showed that gasifier temperature can be estimated by on-line methane concentration measurements.     

Slag resistance mechanism of MgO–Mg2SiO4–SiC–C refractories containing porous multiphase aggregates

The slag resistance of MgO–SiC–C (MSC) refractories should be improved because of the mismatch in the thermal expansion coefficient between the aggregates and matrix, as well as the defects caused by the affinity between periclase and slag. In this study, MgO–Mg₂SiO₄–SiC–C (MMSC) refractories were prepared using porous multiphase MgO–Mg₂SiO₄ (M-M₂S) aggregates to replace dense fused magnesia aggregates. Compared to MSC, the slag penetration index of MMSC decreased by 43.5%. The structure of the porous aggregates increased the surface roughness, and the multiphase composition of the aggregates decreased the mismatch of the thermal expansion coefficient with the matrix, thus reducing debonding between the aggregates and matrix. The aggregates and matrix in the MMSC formed an interlocking structure, which bound them more tightly to improve the slag resistance. The slag viscosity at different depths from the initial slag/refractory interface was calculated using the Ribond model. The M-M₂S aggregates increased Si_xO_y^z− in the slag, which increased the slag polymerization and slag viscosity. The aggregates and matrix in the MMSC reacted with the slag to form high melting point phases, which reduced the channel of the slag. In addition, the penetration depth and velocity derived from the Washburn Equation were modified for the CaO–SiO₂–Al₂O₃–MgO–FeO slag and magnesia based refractory to accurately evaluate slag penetration.     

Effect of Linz-Donawitz slag addition on the hot stage slag mineralogy and fuming conditions: Output slag modification during the industrial Zn fuming operation

Up to 39.35 wt% of CaO-rich Linz-Donawitz (LD) slag was gradually added to copper slag during an industrial Zn fuming process to investigate the influence of CaO content on the Zn fuming efficiency and slag high-temperature mineralogy. Multiple slag samples were taken from a standard fuming process and an LD slag modified fuming process. Microstructure analysis revealed that the fuming bath was primarily composed of the liquid phase and a small number of spinel particles prior to LD slag addition. In contrast, an additional wustite phase was observed after the LD slag addition. According to the FactSage simulation, the bath temperature in the standard fuming process was between 1139 and 1180 °C and the oxygen level was around 1 × 10⁻¹³ - 5 × 10⁻¹⁴ atm. Upon the addition of LD slag, the temperature decreased to 1085–1140 °C, while the pO₂ increased to 1 × 10⁻¹² - 5 × 10⁻¹³ atm. An increase in LD slag content facilitated the decomposition of fayalite and spinel phases, the generation of metallic Fe under pO₂ of 1 × 10⁻¹³ atm, the formation of wustite under pO₂ of 1 × 10⁻¹² atm, and the precipitation of melilite. The optimal fuming conditions for Zn recovery and slag modification without Fe formation were pO₂ of 1 × 10⁻¹² atm, the temperature of 1168–1210 °C and an LD slag content of 28.6 wt%. Under these conditions, the CaO content in the liquid phase can reach approximately 20 wt% and ensure that the fumed slag is a suitable raw material for cementitious materials production.     

立磨矿渣水泥生产线的建设

立磨技术已在水泥、矿渣粉磨领域得到成功的应用。国内只有部分水泥厂使用立磨粉磨原料和煤,用于水泥粉磨较少,特别是国产立磨尚无成功粉磨较高磨蚀性的水泥、矿渣的实例。目前高质量矿渣水泥的优越性逐渐被人们所认识,采用屯磨分别粉磨矿渣和熟料生产矿渣水泥能更有效地利用矿渣,生产过程高效、节能。为此介绍近几年来此类生产线建设的主要方案、建设经验,以期使行业对目前采用立磨分别粉磨矿渣、熟料生产优质矿渣水泥生产线建设的基本情况有进一步的了解。     

Corrosion of phosphate added high-chrome refractory materials in an entrained-flow gasifier

Durability of the refractory liner located in an entrained-flow gasifier is one of the main factors affecting the efficiency and cost of gasification process. This study investigates the corrosion mechanism of phosphate added high-chrome refractories in a commercial entrained-flow gasifier and the effect of phosphate additives on the improvement of service life combining thermodynamic simulation calculations. The microstructures, chemical compositions, and mineral phases of the corroded samples were analyzed by scanning electron microscopy (SEM and EDS) and X-ray powder diffraction (XRD). The results demonstrated that chemical corrosion mainly occurred at the slag-matrix interface and the junction of aggregates and matrix regions. Complex spinel solid solutions were formed at the slag-refractory interface. Phosphate additives decomposed into gaseous products (such as O₂, P₂O₃) and diffused into the interior of refractories at or close to the slag-refractory interface, not only causing an oxidizing environment but also increasing the phosphate contents in the interior of refractories. Phosphate additives in the infiltration layer occupied the gaps between crystal grains of (Cr, Al)₂O₃ solid solutions, reduced the infiltration of silicate phases, and absorbed Ca and Na in the slag, which subsequently increased the viscosity of the slag.     

Integrated experimental and thermodynamic modeling study of phase equilibria in the ‘CuO0.5’-MgO-SiO2 system in equilibrium with liquid Cu metal for characterizing refractory-slag interactions

An integrated experimental and thermodynamic modeling study of the phase equilibria in the ‘CuO_0.5’-MgO-SiO₂ system in equilibrium with liquid Cu metal has been undertaken to better understand the reactions between MgO-based refractories and liquid slag in copper converting and refining processes. New experimental phase equilibria data at 1250–1680 °C were obtained for this system using a high-temperature equilibration of synthetic mixtures with predetermined compositions in silica ampoules or magnesia crucibles, a rapid quenching technique, and electron probe X-ray microanalysis of the equilibrated phase compositions. The system has been shown to contain primary phase fields of cristobalite (SiO₂), tridymite (SiO₂), pyroxene/protoenstatite (MgSiO₃), olivine/forsterite (Mg₂SiO₄), periclase (MgO), and cuprite (Cu₂O). Three regions of 2-liquid immiscibility were found—two in the high-silica range of compositions above the cristobalite primary phase field (close to ‘CuO_0.5’-SiO₂ and MgO–SiO₂ binaries) and one in the low-SiO₂, high-‘CuO_0.5’ compositional region above the periclase and olivine phase fields. The results obtained in this study indicate that silica in high-copper refining slags likely led to olivine and pyroxene phase formation, increased solubility of MgO in liquid slag, and decline in the performance of MgO-based refractories. New experimental data were used in the development of a thermodynamic database describing this pseudo-ternary system.