全文获取类型
收费全文 | 11965篇 |
免费 | 1506篇 |
国内免费 | 473篇 |
专业分类
电工技术 | 490篇 |
技术理论 | 1篇 |
综合类 | 1001篇 |
化学工业 | 1392篇 |
金属工艺 | 318篇 |
机械仪表 | 460篇 |
建筑科学 | 1651篇 |
矿业工程 | 346篇 |
能源动力 | 1475篇 |
轻工业 | 888篇 |
水利工程 | 1206篇 |
石油天然气 | 322篇 |
武器工业 | 55篇 |
无线电 | 599篇 |
一般工业技术 | 1157篇 |
冶金工业 | 1100篇 |
原子能技术 | 70篇 |
自动化技术 | 1413篇 |
出版年
2024年 | 71篇 |
2023年 | 224篇 |
2022年 | 432篇 |
2021年 | 490篇 |
2020年 | 553篇 |
2019年 | 501篇 |
2018年 | 414篇 |
2017年 | 436篇 |
2016年 | 548篇 |
2015年 | 511篇 |
2014年 | 704篇 |
2013年 | 828篇 |
2012年 | 767篇 |
2011年 | 1012篇 |
2010年 | 694篇 |
2009年 | 706篇 |
2008年 | 667篇 |
2007年 | 725篇 |
2006年 | 629篇 |
2005年 | 528篇 |
2004年 | 414篇 |
2003年 | 406篇 |
2002年 | 342篇 |
2001年 | 246篇 |
2000年 | 190篇 |
1999年 | 136篇 |
1998年 | 110篇 |
1997年 | 92篇 |
1996年 | 79篇 |
1995年 | 63篇 |
1994年 | 69篇 |
1993年 | 41篇 |
1992年 | 43篇 |
1991年 | 26篇 |
1990年 | 22篇 |
1989年 | 26篇 |
1988年 | 22篇 |
1987年 | 15篇 |
1986年 | 18篇 |
1985年 | 9篇 |
1984年 | 9篇 |
1983年 | 6篇 |
1982年 | 7篇 |
1964年 | 10篇 |
1961年 | 8篇 |
1960年 | 6篇 |
1959年 | 6篇 |
1957年 | 12篇 |
1955年 | 6篇 |
1951年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 284 毫秒
121.
Microcapsules with phenolic resin (PFR) shell and n‐hexadecane (HD) core were prepared by controlled precipitation of the polymer from droplets of oil‐in‐water emulsion, followed by a heat‐curing process. The droplets of the oil phase are composed of a polymer (PFR), a good solvent (ethyl acetate), and a poor solvent (HD) for the polymer. Removal of the good solvent from the droplets leads to the formation of microcapsules with the poor solvent encapsulated by the polymer. The microstructure, morphology, and phase‐change property as well as thermal stability of the microcapsules were systematically characterized by scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimety (DSC), and thermogravimetric analysis (TGA). The phase‐change microcapsules exhibit smooth and perfect structure, and the shell thickness is a constant fraction of the capsule radius. The initial weight loss temperature of the microcapsules was determined to be 330°C in N2 and 255°C in air, respectively, while that of the bulk HD is only about 120°C both in air and N2 atmospheres. The weight loss mechanism of the microcapsules in different atmosphere is not the same, changing from the pyrolysis temperature of the core material in N2 to the evaporation of core material caused by the fracture of shell material in air. The melting point of HD in microcapsules is slightly lower than that of bulk HD, and a supercooling was observed upon crystallization. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
122.
灞河流域气候因子对水沙变化的影响 总被引:1,自引:0,他引:1
利用灞河流域蓝田气象站和马渡王水文站1960—2012年的气象、水文实测资料,分析灞河流域气候及水沙变化规律,同时运用相关性分析、灰色关联分析、多元线性回归模型等多种方法探讨了该流域水沙变化与气候变化的关系。结果表明:灞河流域降雨量、蒸发量、径流量和输沙量皆呈显著下降趋势,而气温呈上升趋势;降雨量与水沙都有重要的相关关系,1960—1990年影响径流量的气候因子敏感度由大至小依次为降雨量、气温、蒸发量,而1991—2012年则为降雨量、蒸发量、气温,当气温和蒸发量不变时,降雨量每增加1 mm,两阶段的年径流量分别增加0.14亿m3和0.08亿m3;1960—2012年影响输沙量的气候因子敏感度由大至小依次为降雨量、气温、蒸发量,当气温和蒸发量不变时,降雨量每增加1 mm,年输沙量增加0.668万t。 相似文献
123.
Thermal stability of composite phase change material microcapsules incorporated with silver nano-particles 总被引:3,自引:0,他引:3
This paper reports a study on the thermal stability of phase change material microcapsules that are incorporated with silver nano-particles (Ag-NPs). The novel microcapsules were fabricated by the technique of in situ polymerization, with aminoplast as the wall and phase change material bromo-hexadecane (PCM BrC16) as the core. Thermal gravimetry (TG) analysis was applied to measure the thermal stability of these microcapsules and surface morphology of the microcapsules was observed by means of scanning electron microscopy (SEM) after an application of curing treatment at 130 °C. Comparing with conventional phase change material microcapsules (PCMMs), nano-composite phase change material microcapsules (NCPCMMs) have higher thermal stability. This can be attributed to nano-composite structure of the microcapsules, in which metal Ag-NPs distributed on the surface to increase wall toughness and strength. The possible reinforcement mechanisms of the nano-composite structure are explored. 相似文献
124.
125.
随着我国建筑总量和建筑能耗的快速增长,传统的供热方式已难以满足建筑供热的需求,而利用太阳能为建筑物供热,则可获得良好的节能和环保效益。就太阳能供热系统优化设计的相关问题进行了分析和研究,以期能为太阳能供热技术的推广和应用提供一定的理论依据。 相似文献
126.
《The Journal of Strategic Information Systems》2014,23(1):45-61
Information systems (IS) are strategic in so far as they are used to realize strategic intent. Yet, while much has been said about aligning IS functionality with the strategic intent and how to organizationally implement strategically aligned systems, less is known of how to successfully implement strategic change associated with system use – a truly critical challenge within strategic IS implementation. Drawing on a strategy-as-practice perspective we address this gap by developing a multi-dimensional view of IS strategy, conceptualizing three key challenges in the IS strategy process, to explain how and why a paper mill, despite successfully implementing a strategic production management system, failed to produce intended strategic change. We call this outcome strategy blindness: organizational incapability to realize the strategic intent of implemented, available system capabilities. Using a longitudinal case study we investigate how cognitive rigidity of key actors and fixed, interrelated practices shaped the implementation of the new production system. We also identify core components and dynamics that constitute a richer multi-dimensional view of the IS strategy implementation (alignment) process. In particular, we identify three salient factors that contribute to strategy blindness – mistranslation of intent, flexibility of the IT artifact and cognitive entrenchment – and discuss how they affect strategic implementation processes. We conclude by discussing implications of our findings for IS strategy theory and practice, especially the contribution of strategy-as-practice to this stream of research. 相似文献
127.
以聚乙二醇(PEG10000)和氨丙基封端的聚二甲基硅氧烷(APDMS)为软段,以甲苯-2,4-二异氰酸酯(TDI)为硬段,以碳纳米管(CNTs)作为功能性材料,一锅法制备了导热增强的聚氨酯基柔性定形相变材料(PU/APDMS/CNTs)。用FTIR、XRD、DSC和TGA等对材料的结构特征和热性能进行了表征。当APDMS含量为10 wt%时,PU/APDMS/CNTs的相变焓值为88.3 J/g,该相变材料在200℃内不发生热分解,具有良好的热稳定性和定形效果,加入5 wt% CNTs的柔性定形相变材料,能够实现光热转换和热能存储,其光热转换和热能存储效率为62.8%,与未加入CNTs的相变材料相比,导热性能明显增强,其升降温速率提高了2.75倍。 相似文献
128.
Wei Zhang Zhao-Jun Mo ZhiHong Hao Jun Shen Jia-Wei Luo Rui-Jiang Chang Lan Li 《International Journal of Applied Ceramic Technology》2019,16(4):1606-1611
The magnetic properties and magnetocaloric effect for EuTi1-xFexO3 (x = 0.05, 0.1) compounds are investigated. When a part of Ti4+ions were substituted by Fe ions, the AFM ordering can be significantly changed to be FM. The EuTi1-xFexO3 (x = 0.05, 0.1) compounds exhibit a PM to FM transition with decreasing temperature and the Curie temperature is 6 K. Under the field changes of 1 T, and RC are valued to be 10.1 J/kg K and 50.2 J/kg for EuTi0.95Fe0.05O3; 9.6 J/kg K and 47.7 J/kg for EuTi0.9Fe0.1O3, without magnetic and thermal hysteresis. RC is almost twice as much as EuTiO3 (27 J/kg) as substitution of Fe3+ ions for Ti4+ions, which may be attributed to the magnetic transition (AFM to FM). Therefore, the giant and large RC suggest the EuTi1-xFexO3 compounds are good materials for magnetic refrigerant. 相似文献
129.
Jan Willem?van?GroenigenEmail author Pieter Jan?Georgius Chris?van?Kessel Eduard W.J.?Hummelink Gerard L.?Velthof Kor B.?Zwart 《Nutrient Cycling in Agroecosystems》2005,72(1):13-25
Studies on emissions of nitrous oxide (N2O) from agricultural soils mostly focus on fluxes between the soil and the atmosphere or are limited to the atmosphere in
the topsoil. However, in soils with shallow water tables, significant N2O formation may occur closer to the groundwater. The aims of this study were (i) to determine the importance of subsoil N2O formation in a sandy soil; and (ii) to obtain a quantitative insight in the contribution of subsoil N2O to the overall losses of N2O to the environment. We applied 15N labeled fertilizer at a rate of 5.22 kg 15N ha−1; 50% as Ca(NO3)2 and 50% as NH4Cl, on a mesic typic Haplaquod seeded with potatoes (Solanum tuberosum L.), and traced soil N2O concentrations and fluxes over a one-year period. Throughout the year, total N2O and the amount of 15N recovered in soil N2O were highest in the subsoil, with a maximum concentration at 48 cm depth in mid-February of 19900 μl m−3 and 24 μg 15N m−3, respectively. The maximum concentration coincided with the highest water-filled pore space of 71%. The cumulative flux of
N2O was 446 g N2O-N ha−1, the recovery of 15N in this flux was 0.06%. During the summer, maximum fluxes followed high soil N2O concentrations. During winter, no such relation was found. We concluded that the formation of N2O was the highest in the subsoil, largely controlled by water-filled pore space rather than NO3− concentration or temperature. Although high subsoil N2O concentrations did not lead to high surface fluxes of N2O in the winter, artificial draining may lead to high indirect N2O emissions through supersaturated drainage water. 相似文献
130.
MoS2因其独特的二维“三明治”层状结构在电学、能源和催化等行业备受关注。由于S、Mo原子配位模式的不同,MoS2主要以1T和2H相两种形式存在。通常,1T-MoS2拥有更大的层间距和更多的催化活性位点,在许多领域都表现出了比2H-MoS2更优异的性能。通过控制2H-MoS2 中S平面的横向位移和Mo 的3d轨道电子填充状态,可以定向调控2H-MoS2生成1T-MoS2。鉴于此,综述了2H-MoS2定向调控制备1T-MoS2的研究进展,并对影响调控过程的主要因素及相应的调控方法和机理进行了详细的阐述,同时总结了1T-MoS2在析氢、电池、光和热催化领域的应用,可为1T-MoS2的定向合成与应用打下一定的基础。另外,也对 1T-MoS2在未来的实际应用前景进行了展望。 相似文献