高含酸性气碳酸盐岩气藏流体敏感性实验研究

对川东北雷口坡组、嘉陵江组、飞仙关组、长兴组高含H，S及032的碳酸盐岩储层流体敏感性进行了实验研究，结果表明岩样速敏损害弱～强，水敏和盐敏损害中偏弱～极强，碱敏损害严重。岩石学分析揭示，川东北高含酸性气碳酸盐岩储层发育伊利石、微晶石英、白云石、方解石、硫化钙等潜在损害物质。钻井完井液侵入会破坏储层各物质间的原始动态平衡，诱发储层损害。主要损害机理为：①储层流体pH增加引起黏土矿物以及微晶石英失稳；②碱液与微晶石英、长石、白云石反应生成硅酸盐、高岭石、水镁石等新矿相；③流体矿化度改变可降低伊利石微粒间的连接力；④硫化钙水解产生OH^-，过量的OH-与Ca^2＋结合形成氢氧化钙沉淀；⑤储层含水饱和度和流体离子浓度改变，致使焦沥青脱附并在储层深部沉积；⑥硬石膏水化膨胀、分散运移。针对该气藏损害机理，可采用屏蔽暂堵技术以形成优质滤饼，有效降低储层流体敏感性损害。图5表2参10。     

醋酸甲酯在Cs_(1.5)PW/SiO_2催化剂上的水解反应

通过改变阳离子的种类与配比,制备了一系列SiO2负载的磷钨酸盐催化剂,考察了制备方法对催化剂性能的影响,采用傅里叶变换红外光谱、X射线衍射、X射线荧光光谱、环境扫描电子显微镜等方法对催化剂进行了表征,并考察了该系列催化剂对醋酸甲酯水解反应的活性。实验结果表明,Cs1.5PW/SiO2催化剂的活性最好,当Cs1.5PW负载量(质量分数)为30%时,Cs1.5PW的Keggin结构保持完好,没有硅钨酸阴离子形成,Cs1.5PW在SiO2载体上高度分散;在反应温度55℃、反应时间2h的条件下,醋酸甲酯的转化率为35.79%,约为均相磷钨酸催化剂的1.3倍。该催化剂重复使用4次后,醋酸甲酯的转化率稳定在25%;80℃下反应2h,与NKC-9磺酸树脂催化剂相比,醋酸甲酯的转化率提高了5.17%。     

Valley floor landscape change following almost 100 years of flood embankment abandonment on a wandering gravel‐bed river

Critical to restoring the nature conservation value of many river corridors is an understanding of how alluvial landscapes will respond to cessation of river management and land use practices that have previously degraded the environment. This paper analyses changes in valley floor landforms and vegetation patch dynamics, in relation to fluvial disturbance, over a period of almost 100 years following flood embankment abandonment on a wandering gravel‐bed river, namely the River Tummel, Scotland. Such rivers were once typical of many draining upland areas of northern maritime Europe. Prior to abandonment the valley floor landscape was agriculturally dominated and the river for the most part was single thread confined between flood embankments. The pattern of landform change and vegetation patch development over time following a decision in 1903 not to maintain embankments was tracked by geomorphic and land cover mapping utilizing successive sets of aerial photography for the period 1946 to 1994. A historical context for these changes was also feasible because the channel planform in 1900 and earlier channel planform changes dating back to 1753 were known due to the availability of old maps and earlier geomorphic studies. The land cover mapping was validated by comparison of results produced from the interpretation work on the 1994 aerial photographs with the field‐based UK National Vegetation Classification protocol. The findings of the study illustrate that bordering the River Tummel fluvial landforms and vegetation patch mosaics, presumably resembling those that occurred before valley floor land use intensification, evolved in less than 50 years after flood embankment abandonment with a resultant increase in habitat diversity. The change relates primarily to flood‐induced channel planform change and moderate levels of fluvial disturbance. The general significance of this change to plant species diversity on the valley floor of the River Tummel and elsewhere is discussed as is possible implications of the upstream impoundment and scenarios for climatically induced changes in flood frequency and magnitude. The overall outcome is the strong possibility that simple changes in river management and land use practices could result in re‐establishment of the nature conservation value of similar river corridors in Europe over the medium term without active restoration efforts. Copyright © 2002 John Wiley & Sons, Ltd.     

静态水热脱铝处理对HZSM-5分子筛的结构、酸性和催化性能的影响

开发了一种静态水热脱铝的方法。HZSM-5经此法处理后,正戊烷的裂解活性增加,脱氢和芳构化性能加强。可用改变处理温度的方法来控制脱铝的程度。用XRD和吡啶吸附红外技术进行了研究。HZSM-5分子筛催化剂性能的变化用非骨架铝产生的强L酸中心来解释。     

浆砌石衬砌在渠道防渗中的应用及对策

总结了浆砌石应用的历史,介绍了浆砌石的结构特性和施工工艺,从造价方面、防渗效果及施工三方面分析了浆砌石衬砌主要存在的问题,并提出了相应的解决对策,指出浆砌石衬砌在渠道防渗应用中应控制施工质量,从而更好地提高防渗效果。     

Fabrication of damascene Cu wirings using solid acidic catalyst

The copper damascene process is one of the most promising technologies for fabricating Cu wirings for electronic devices such as LSIs. In this research, the fabrication of damascene Cu wirings was conducted using solid acidic catalyst. When a Cu-plated wafer, whose oxide is a basic oxide is dipped into a mixture of oxidizing solution and acidic solution, surface atoms are ionized and etched off into the solution. However, because conventional nonelectrolytic etching does not have a reference surface, it is difficult to utilize for planarization. Therefore, a new nonelectrolytic machining method using a cation-exchange fabric instead of an acidic solution was developed. To be more precise, the planarization of a Cu-plated wafer was carried out by rubbing with the cation-exchange fabric in ozone water. Basically, this method exploits chemical reactions so that the physical properties of the workpiece surface are not deteriorated. Furthermore, this method uses no chemicals except for ozone water, which easily dissociates into water and oxygen molecules; thus, this method is a low-cost, environmentally friendly process. In this paper, as a preliminary experiment, the nonelectrolytic etching of a Cu sample using solutions of O₃ and CO₂ was carried out to inspect the dependence of the etching rate on [O₃] and [H⁺]. The results indicate that the etching rate increased as [O₃] and [H⁺] increased. When [H⁺] was high relative to [O₃], a smooth etch-pit-free surface was achieved. Next, nonelectrolytic etching using a cation-exchange fabric was carried out, and properties similar to those in the case of etching using solutions were obtained. Finally, damascene Cu wirings were fabricated using ozone water and a cation-exchange catalyst.     

预应力长线台座的施工方法及要点

叙述我国中小型建筑构件厂最常用的预应力长线台座的建造过程，以及必须注意的事项及质量控制方法。     

大碎石柔性基层沥青性能分析

用沥青大碎石柔性基层对旧路面进行补强，可以有效地提高路面的使用性能，减少反射裂缝的产生，延长道路的使用寿命。对沥青大碎石柔性基层用加德士AH-70、SBS改性沥青和MAC改性沥青分别进行试验，通过试验结果和经济性能对比分析，找到适合此结构的最佳沥青。     

Acidic and basic hydrolysis of poly(N‐vinylformamide)

Poly(N‐vinylformamide) (PNVF) was synthesized and hydrolyzed to poly(vinylamine) (PVAm) in both HCl and NaOH solutions. The hydrolysis kinetics and the equilibrium hydrolysis were examined experimentally at different temperatures, polymer concentrations, and acid‐ or base‐to‐amide molar ratios. The hydrolysis kinetics strongly depended on temperature, polymer, and HCl or NaOH concentrations, but showed little dependence on PNVF molecular weight. The acid hydrolysis of PNVF exhibited limited conversions because of the electrostatic repulsion among the cationic amine groups generated during hydrolysis and proton hydrates. In the basic hydrolysis, complete amide conversions were observed when the NaOH/amide molar ratios were greater than unity. The effects of temperature and PNVF concentration on the equilibrium amide conversion appeared to be negligible in both acidic and basic hydrolysis. The equilibrium conversions of base hydrolysis were higher than those of acidic hydrolysis under the same reaction conditions. At NaOH/amide ratios of less than unity, the equilibrium hydrolysis experiments revealed that one base molecule could induce the hydrolysis of more than one amide group. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3412–3419, 2002     

微观视域的福州乌山摩崖石刻景观分析

本文通过实地调研,结合摩崖石刻的内容形式和空间位置,选取具有代表性的"张伯阳等题名"、"道山亭"、"石天-双峰梦"和"天秀岩"为研究对象,以儿童和成人的视角分析微观视域下的摩崖石刻景观空间."张伯阳等题名"成人的欣赏方式为俯视,儿童经历俯视-平视-仰视的过程;"道山亭"成人的欣赏方式以平视为主,仰视为辅,儿童则以仰视为主,平视为辅;"石天"-"双峰梦"和"天秀岩"成人和儿童多以仰视为主.