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81.
本文介绍了变压吸附法制备富氧空气用于合成氨造气系统的新工艺,并对50000t/a合成氨厂进行了技术经济评估。结果表明,同间歇法气化相比,该技术工艺先进且具有显著的经济效益。 相似文献
82.
Spectroscopic evidence for the interaction of hydroxyl groups and chromium ions was obtained using a catalyst prepared from chromyl chloride. A new OH peak, observed at 3705 cm–1 after pumping away CO gas, is attributed to the direct interaction of OH with the low-valent chromium. This peak shifts to 3590 cm–1 on contact with O2 at room temperature and it is assigned to a hydroxyl interacting with the oxidized chromium. New assignments are also proposed for IR bands of CO presorbed on the catalyst. The peak due to CO at 2188 cm–1 decreases as the OH intensity at 3705 cm–1 increases, suggesting that the former peak arises from adsorption on Cr(II) species to which two oxygen atoms are attached. 相似文献
83.
On Cu-ZSM-5 zeolite at room temperature, propane is physisorbed, while propene shows characteristics of chemisorption. The chemisorption mode has certain advantages for the catalytic control of automotive emissions. Alkane and alkene adsorption equilibria and kinetics are compared on Cu-ZSM-5 and on ZSM-5 free of alumina. The results are discussed in terms of the Langmuir adsorption isotherm. 相似文献
84.
Phosphorus modification of ZSM-5 leads to extra framework P5+ and probably incorporation of +3 valence state of P in the framework. The resulting system has increased Brønsted acidity. Theoretical calculations also favour the postulate that phosphorus in +3 valence state can be incorporated into the lattice. 相似文献
85.
86.
Hsi-Jen Chen Shan-Huei Yang Shun-Hsing Huang Y.P. Chyou 《Journal of the Chinese Institute of Chemical Engineers》2007
This paper addresses an integrated design of paraffin-reformer, gas separations and the electricity production with a solid oxide fuel cell (SOFC). The overall design consists of three modules. First module is a system of paraffin reformer. In this module, the paraffin feed stream is to send to a steam-reformer. In the second module, the gas separations method illustrated is the combination of a methane-permeable membrane with a pressure-swing adsorption (PSA). In the third module, the purified hydrogen is fed to the SOFC unit. To be energy efficient, this paraffin-fueled SOFC system is designed with the consideration of heat integration. The intent of this paper is to provide a possible, alternative way of cogeneration systems for refinery and petrochemical plants. 相似文献
87.
The electrochemical behavior of the bronze (Cu-8Sn in wt%) was investigated in 3% NaCl aqueous solution, in presence and in absence of a corrosion inhibitor, the 3-phenyl-1,2,4-triazole-5-thione (PTS). The inhibiting effect of the PTS was evidenced for concentrations higher than 1 mM for the cathodic process whereas its effect was clearly seen with a concentration as low as 0.1 mM for the anodic process. A significant positive shift of the corrosion potential was also observed, and its inhibiting effect increased with both its concentration and the immersion time of the sample. From voltammetry and electrochemical impedance spectroscopy experiments, the inhibiting efficiency of the PTS was found to be in the 94-99% range for 1 mM concentration. Scanning electron microscopy and X-ray energy dispersion analysis of the specimen surface show the presence of sulphur on the surface. Raman micro-spectrometry study confirms the protective effect of the PTS in aqueous solution through three types of interactions with the electrode, namely the adsorption of the inhibitor in a flat configuration, the formation of copper-thiol molecules, and when copper is released, the formation of a polymeric complex. 相似文献
88.
研究了玻璃颗粒在乙醇溶液中对Ca^2 的选择吸附,反转了玻璃颗粒在乙醇中的荷电性质,使玻璃颗粒能够在乙醇中与羟基磷灰石发生共沉积。讨论了不同离子浓度下电泳沉积的沉积量与沉积电流的变化情况,并以此对Ca^2 在电泳沉积中的作用进行了分析。实验结果证实:悬浮液中Ca^2 或吸附到玻璃颗粒上,改变其荷电性质;或留在溶液中,作为电泳沉积过程中电流的主要承载者。离子浓度对电泳沉积的效果有重要的影响,离子浓度太低或太高都易使涂层出现缺陷。分析了不同沉积条件下电泳沉积所得涂层的各种缺陷及其成因。 相似文献
89.
Polyaspartate is an excellent Pb2+‐binding agent in comparison with some polyaspartamide derivatives with different side chains, in that it possesses a higher Pb2+ uptake and a lower Pb2+ equilibrium concentration. Equilibrium sorption data for Pb2+ on polyaspartate can be well fitted with the Freundlich and Langmuir models. Experimental results show that a crosslinked polyaspartate hydrogel is superior to poly(acrylic acid)‐based resins and polystyrene‐based chelating resins. IR spectra and X‐ray photoelectron spectra reveal that the polyaspartate hydrogel binds Pb2+ by both an ion‐exchange mechanism and a chelating mechanism. The polyaspartate hydrogel is also an effective agent for the removal of Pb2+ from glycyrrhizin. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 2215–2220, 2005 相似文献
90.