Carbon molecular sieve films produced by dc sputtering

This paper reports adsorption measurements that show molecular sieve effects in amorphous hydrogenated carbon (a-C : H) films deposited by d.c. magnetron discharge decomposition of acetylene. Adsorption of organic gases on the films is studied by using a quartz crystal microbalance technique. The sieve effect in this material depends on both deposition and annealing conditions. Films having significant molecular sieve effects are found to be typically microporous and to have a very small characteristic micropore dimension. It is suggested that the d.c. sputtered a-C : H film may be useful as a molecular sieve material in selective adsorption and gas permeation studies.     

Transition phenomena of polymers in mixed solvents in the vicinity of theta conditions: Effect of preferential adsorption

Viscosimetric measurements were obtained with the ternary systems polystyrene/dioxane/methanol, polystyrene/benzene/methanol and poly(methyl methacrylate)/dioxane/cyclohexane, changing the solvent mixture composition at constant temperature. The polystyrene and poly(methyl methacrylate) systems exhibit a transition phenomenon with solvent-mixture composition in which the polymer is just above the theta condition. In the case where two theta conditions occur ((θ-intra, θ-inter) the transition point is closely related to the intramolecular theta conditions. Moreover the intramolecular theta conditions vary with the molecular weight in the region of molecular weights where the preferential adsorption also varies. This variation induces a variation of the transition point with molecular weight which obeys a formula analogous to that giving the variation of the preferential adsorption with molecular weight.     

PTA尾气吸附系统的优化

针对吸附系统内除湿剂硅胶频繁破碎现象进行优化。在找出硅胶破碎原因的基础上,通过吸附塔直径放大18.3%,引出部分尾气,使床层流速降低。在吸附塔进口管处,安装雾沫分离器;在硅胶前沿填充部分耐水硅胶以减少液态水的冲击。再生蒸汽加热管上加调节阀防止硅胶过分干燥。使A塔硅胶使用了540d,B塔硅胶使用了630d。     

Effect of fretting amplitudes on fretting wear behavior of steel wires in coal mines

Given that fretting wear causes failure in steel wires, we carried out tangential fretting wear tests of steel wires on a self-made fretting wear test rig under contact loads of 9 and 29 N and fretting amplitudes ranging from 5 to 180 μm. We observed morphologies of fretted steel wire surfaces on an S-3000N scanning electron microscope in order to analyze fretting wear mecha-nisms. The results show that the fretting regime of steel wires transforms from partial slip regime into mixed fretting regime and gross slip regime with an increase in fretting amplitudes under a given contact load. In partial slip regime, the friction coefficient has a relatively low value. Four stages can be defined in mixed fretting and gross slip regimes. The fretting wear of steel wires in-creases obviously with increases in fretting amplitudes. Fretting scars present a typical morphology of annularity, showing slight damage in partial slip regime. However, wear clearly increases in mixed fretting regime where wear mechanism is a combination of plastic deformation, abrasive wear and oxidative wear. In gross slip regime, more severe degradation is present than in the other regimes. The main fretting wear mechanisms of steel wires are abrasive wear, surface fatigue and friction oxidation.     

新型纤维素基螯合纤维的制备与吸附性能

为了发展水处理的途径,制备了β-环糊精改性的新型纤维素基螯合纤维.运用原子吸收光谱和紫外光谱考察了其对模拟水样中重金属离子(Cu2+)和有机染料(中性红)的吸附性能.实验结果表明,螯合纤维对Cu2+吸附率达6.24 mg/g,符合Langmuir吸附模型;对中性红也具有较强的包结能力.该鏊合纤维水处理能力强,制备简单,操作简便,有潜在的应用价值.     

潜器Stewart平台动力学仿真

建立了Stewart平台的动力学模型,对潜器的动力学特征进行分析,对其运动进行动力学仿真研究.以Stewart平台的任意支腿为研究对象,考虑各支腿的重力和惯性力,利用牛顿-欧拉方法建立了支腿及动平台的力和力矩平衡方程,推导出了Stewart平台的动力学方程及支腿所受的支反力.以潜艇模拟器并联机构为例,运用动力学模型进行了实际计算并绘制了支腿驱动力的变化曲线,将驱动力与支腿运动速度相乘得到支腿功率输出的变化曲线,为液压油缸的功率设计提供了依据,也为潜器的精确动力学解耦奠定了基础.     

螺纹桩在软弱地层中的应用

分析了螺纹桩的受力机理,探讨了螺纹桩单桩承载力的确定方法,指出螺纹桩单桩承载力高、节约材料显著、能充分利用地基土的特性,在软弱地层中的应用优势显著,并通过实际工程实例给予具体说明.     

动态挖掘进程内在机制研究

针对动态挖掘进程内在运行机理,通过对动态挖掘进程中不同挖掘任务的优化分析以及动态挖掘进程和生物免疫过程之间的对比分析,提出了动态挖掘进程的eDMP机制;定义健壮型协调器,融合进化计算和免疫算法,设计了eDMP机制的实现方案;在理论分析和方案设计的基础上,给出了eDMP机制的一般流程。实验结果表明,eDMP机制及其实现方案在解决动态挖掘问题上有效、适用。