超高分子量聚乙烯衬板在煤仓中的应用

介绍了井底煤仓溜煤斜面采用超高分子量聚乙烯衬板安装及应用情况 ,对井底煤仓棚煤原因及解决办法进行了探讨     

塔河油田特殊钻井条件下的录井技术

该文阐述了定向井、水平井和欠平衡钻井技术对传统录井方法的影响:钻时偏大、失真,岩屑细、代表性差,荧光常达12级、无意义,全烃值一般在5%以上,难以有效划分油气层;指出在特殊钻井条件下掌握设计指导思想,卡准重要层位是录井工作的关键,重点要参考组分分析数据、定量荧光分析数据和综合录井其它信息才能准确识别油气层。     

热带城市垃圾典型组分的热解特性研究

对热带城市垃圾的几种典型组分进行了热解实验，得到了它们的失重曲线，通过对失重曲线进行分析，得到了这几种典型组分的热解规律，并通过建立热解动力学模型，求出了其中两种组分的活化能E和频率因子A。     

广义物质平衡计算在凝析气藏开采动态预测中的应用

从经济的角度考虑 ,对小型凝析气藏衰竭式开采动态的预测往往不必或不值得进行数值模拟研究。常规物质平衡 (黑油 )计算方法只局限于黑油和干气藏 ,应用于凝析气藏则存在很大的误差。Walsh提出的广义物质平衡计算方法 ,可用于包括黑油、干气藏、挥发油气藏和凝析气藏在内的所有油气藏。文中将一个小型凝析气藏衰竭式开采动态的数值模拟结果与广义物质平衡计算结果进行了对比 ,结果表明 ,Walsh方法简便、应用更广泛 ,可用于规模较小、不适合进行数值模拟研究的凝析气藏的现场开发优化。     

凝析气藏物质平衡方程的改进与应用

为了提高凝析气藏油气采收率，通常采用目前最有效的循环注气保持地层压力的开采方式。在此开采方式下，直接采用气藏物质平衡方程进行地质储量计算将出现很大偏差。针对这种情况，将气藏物质平衡方程进行了改进，得到凝析气藏在注气开发方式下的物质平衡方程。     

国际水资源保护和管理的最近动态——水与可持续发展

阐述了可持续发展及其要求 ,水在可持续发展中的作用 ,国际关于水资源保护和管理的最近动态。最后提出 ,可持续发展是经济社会以及人口、资源和环境的协调统一 ,应从根本上将“先污染后治理”及“防治污染”改为“避免污染”的战略 ;从传统的整体规划向机能整体性规划发展 ;保护和建立河流系统环境 ;着手研究和解决全球环境问题。     

Modeling of the bulk free radical polymerization up to high conversion—three stage polymerization model. II. Number-average molecular weight and apparent initiator efficiency

The equations for predicting the number-average molecular weight are derived on the basis of the three stage polymerization model (TSPM) in this paper. By applying the equations, a plotting approach is proposed to determine the apparent initiator efficiency defined as f[(α_td+1)/2] and the constant of chain transfer to monomer, where f is the initiator efficiency and α_td denotes the fraction of the termination rate constants by disproportionation. Using the approach to plot the experimental data in the literature, it is found that the chain transfer to monomer can be neglected for both methylmethacrylate (MMA) and styrene (St) polymerizations, but it can exert a significant effect on ethylmethacrylate (EMA) polymerization. In addition, the apparent initiator efficiency is found to be independent of reaction temperature and initiator concentration at each stage. The values of f[(α_td+1)/2] at gel effect stage are slightly reduced as compared with that at low conversion stage for MMA and EMA polymerizations. However, it decreases significantly at gel effect stage for St polymerization. Using the equations derived and the apparent initiator efficiencies obtained from TSPM plots, the number-average molecular weights at different conversions can be predicted. Comparisons show that the agreement between predictions and experimental data is satisfactory.     

Structure and properties of injection‐molded polypropylenes with different molecular weight distribution and tacticity characteristics

Two series of polypropylenes with different molecular weight distribution and tacticity characteristics were injection molded into flexural test specimens by varying cylinder temperature and the effects of the molecular weight distribution and tacticity on the structure and properties of the moldings were studied. Measured propertied were flexural modulus, flexural strength, heat distortion temperature, Izod impact strength, and mold shrinkage and structures studied were crystallinity, the thickness of skin layer, a*‐axis‐oriented component fraction and crystalline orientation functions. The relations between the structures and properties were also studied. It was found that the molecular weight distribution and tacticity characteristics affect the properties mainly through the molecular orientation and crystallinity, respectively. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 2142–2156, 2002     

Thermally induced microstructural changes in cotton fibers: A free‐volume study

I measured positron lifetime in natural polymer–cotton fibers as a function of isochronal annealing temperature in the range 27–290°C. The variations in the positron results indicated structural changes occurring in the cotton fibers and determined the glass‐transition temperature as 80°C. Activation energies were measured separately for the crystalline and amorphous regions, indicating the versatility of the technique. These values were close to the O? H bond dissociation energy, suggesting O? H bond dissociation, the most probable process occurring under thermal treatment. As an extension of the positron results, the molecular weight of the cotton fibers was determined to be 1,200,000 based on free volume, which was within the range suggested for cotton. There seemed to be an indication that crosslinking changed the spiral structure of cotton fibers to the network type. However, this needs to be validated by other measurements. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3336–3345, 2002