Molecular motions of non-crystalline poly(aryl ether-ether-ketone) PEEK and influence of elecron beam irradiation

The dynamic mechanical relaxation of non-crystalline poly(aryl ether-ether-ketone) PEEK and the one irradiated with electron beam were studied. The three distinct γ, β, α′ relaxation maxima were observed in unirradiated PEEK from low to high temperature. It was revealed from the study on the irradiation effects that three different molecular processes are overlapped in γ relaxation peak, i.e., molecular motion of water bound to main chain (peak temperature; at ?100°C), local motion of main chain (at ?80°C), and local mode of the aligned and/or oriented moiety (at ?40°C). The β relaxation connected with the glass transition occurred at 150°C and it shifted to higher temperature by irradiation. The α′ relaxation which can be attributed to rearrangement of molecular chain due to crystallization was observed in unirradiated PEEK ～ 180°C and its magnitude decreased with the increase in irradiation dose. This effect indicates the formation of structures inhibiting crystallization such as crosslinking and/or short branching during irradiation. A new relaxation, β′, appeared in the temperature range of 40° to 100°C by irradiation and its magnitude increased with dose. This relaxation was attributed to rearrangement of molecular chain from loosened packing around chain ends, which were introduced into the non-crystalline region by chain scission under irradiation, to more rigid molecular packing, From these observations, we proposed that deterioration in mechanical properties of non-crystalline PEEK by high energy electron beam was brought about not only by chain scission but structural changes such as crosslinking and/or branching in the main chain.     

Thermodynamics of ionic-association in aqueous solutions of Ca and Mg organic salts using ion-selective electrode technique—II. benzoate, o-toloate, o-chlorobenzoate and salycylate

The stoichiometric association constants, K, the thermodynamic association constant, K_A, and the other thermodynamic parameters such as ΔS°, ΔH° and ΔG° for the association between each of the Ca and Mg ions with benzoate, o-toloate, o-chlorobenzoate and salycylate have been determined at 25°C, 35°C and 45°C in aqueous media. Ion-selective electrode technique has been used in the measurements of Ca and Mg ion activitiesThe trend of association behavior of both Ca and Mg aromatic salts could not be explained on the basis of pK_a of the mother organic acids but could be explained based on the trend of Hammet function σ of these salts themselves relative to the corresponding benzoate salt.     

Transient and isotopic studies of the oxygen transport and exchange during oxidative coupling of methane on Sr promoted La2O3

Isotopic transient techniques were applied to study oxidative coupling of methane over lanthanum oxide and strontium promoted La₂O₃ catalysts. Results of the¹⁸O₂/¹⁶O₂ isotopic exchange experiments indicate that Sr promotion increases oxygen uptake from the lattice of the catalyst. Oxygen self diffusion coefficients, which were determined for the series of lanthana catalysts, reach a maximum for the 1% Sr/La₂O₃. Steps of¹⁸O₂ in the presence of a steady flow of methane over Sr/La₂O₃ catalysts, indicate that surface and bulk oxygen appear in the reaction products before gas-phase¹⁸O². Steps of CO₂ over catalysts in which lattice oxygen has been exchanged with¹⁸O₂, show that gas/solid exchange involves over 50% of the lattice oxygen. Under reaction conditions, methane pulses with no gas-phase oxygen yield negligible amounts of products which indicates that methane interacts with lattice oxygen only in the presence of the gas-phase oxygen.     

我国高等学校法人治理结构的实施框架

高等学校法人治理结构的关键在于权力分配与权利制衡,目标在于真正落实高等学校的办学自主权。只有以现存的治理制度与组织结构为基础,引入现代企业治理结构和国外高等学校法人治理的经验,对高等学校的科层制管理结构进行改良,建立符合我国国情的高等学校法人治理结构,才是落实办学自主全权,完善自我管理的必要出路。     

考试综合管理信息系统的关键技术研究

基于.NET技术成功开发了考试综合管理信息系统,针对考试管理工作面临的问题,提出了相应的解决方案,并以此为依据介绍了该系统开发过程中的自动编排算法、安全策略等关键技术。该系统已成功运用,并解决了高校日益复杂的考务管理工作。     

基于历史缓存技术的射线跟踪加速算法研究*

通过分析影响射线跟踪效率的因素,提出一种基于历史缓存技术的射线跟踪加速算法,以提高射线跟踪的运算效率。通过建立一个缓存区存储历史信息,用来减少每条射线必须处理的建筑物面的数量和减少计算无效的交点。对提出的算法进行仿真计算,仿真结果证明了这种算法的正确性,有效降低了计算的复杂度。     

循环经济在赣州矿产资源开发与管理中的研究

如何利用赣州矿产资源优势发展本地经济,节约资源开采,充分利用现有资源,实现资源的循环利用,保持生态环境的良好发展具有重要意义。本文分析介绍了循环经济、赣州矿产资源及开发利用现状,并提出了实现矿业循环经济的具体措施。     

中国银行利率风险实证分析

随着中国融入世界的步伐加快,加入WTO中要求中国放开金融市场的开放程度,利率管制的放松也将逐步的实行,利率风险日益成为中国商业银行面临的重要风险之一。本文从理论和实践角度对中国商业银行的利率风险进行了分析和研究,剖析中国商业银行存在的诸多障碍,指出了商业银行风险管理中存在的问题,并提出中国商业银行利率风险管理建议。     

无线射频识别技术（RFID）及其在物联网中的应用

随着物联网知识的普及,以及其技术的广泛推广应用,物联网被越来越多的人所关注。本文介绍了物联网及其关键技术RFID,并结合RFID在物联网的实际应用,并对其未来的发展作出了展望。     

稳定路径的Ad hoc网络QoS路由算法

移动Ad hoc网络中节点移动或能量耗尽会使得建立的QoS路径断裂而需重构路由,造成通信中断,对实时业务造成严重影响,提出了一种基于路径稳定性的QoS路由算法.该算法采用网络探测技术,综合考虑链路和节点稳定性,选择一条最稳定的路径进行通信,并实时监测路径状态变化,有效降低通信中断的概率.仿真表明,该算法有效改善了分组传送成功率、时延抖动等网络性能.