聚合物电解质PEO全固态电致变色窗

本文用聚合物ＰＥＯ的锂盐络合物作电解质制作全固态电致变色窗，讨论了器件的特性，以及工艺条件的影响。     

Synthesis of poly(4-methylstyrene)- graft-poly(ethylene oxide)s and application as polymeric dispersant in coal-water mixture

Poly(4-methylstyrene)-graft-poly(ethylene oxide)s were prepared via polymerisation of ethylene oxide on to poly(4-methylstyrene)s functionalised with hydroxyl groups. In this way, many ‘comb-like’ polymers having different hydrophobic backbone length, hydrophilic branch length and frequency of branches were synthesised. These polymers were tested as dispersants in coal-water mixtures in order to correlate the dispersing properties of this class of polymers with the investigated parameters.     

尼龙6表面金属(Ni)化膜材料的制备及性能研究

用化学还原法制得了尼龙６表面金属（Ｎｉ）化膜材料。研究了还原条件，金属盐浓度对膜材料电性能的影响，以及膜材料的电发热性能，用光电子能谱和扫描电子显微镜对其表面及形貌进行了表征。     

聚氧乙烯 - 聚氧丙烯 - 聚苯乙烯多嵌段聚合物的力学和导电性能研究

研究了聚苯乙烯含量对聚氧乙烯－聚氧丙烯－聚苯乙烯多嵌段聚合物的力学性能及其与ＬｉＣｌＯ４络合物的离子导电性能的影响；并以电导率较高的络合物为电解质，Ｎａ１＋ｘＶ３Ｏ８复合物和Ｌｉ片分别为正、负极组装了薄型锂电池并测定其放电性能。     

对聚合物驱单井效果评价的几点认识

通过对喇嘛甸油田聚合物驱单井效果分析，给出了采油井阶段效果评价方法，即单井见效时间和含水回升时间早晚的确定方法，单井见效时间取决于油层条件，注聚前含油饱和度及累计采出地下体积倍数，单井含水回升时间主要取决于聚驱阶段剩余储量采出程度，根据单井阶段评价结果，对试验区进行跟踪调整，在单井阶段效果评价的基础上，对单井最终效果采用吨聚增油量和聚驱阶段剩余储量采收率来进行客观，有效的评价，对聚驱产量预测具有一定指导意义。     

Application of degradation kinetics to the rheology of poly(hydroxyalkanoates)

The time‐dependent rheological behavior of a series of 3‐hydroxybuytrate‐based semicrystalline copolymers is employed to determine the expected rheological curves that would be generated in the absence of any polymer degradation. Both dynamic frequency sweep and shear rate sweep experiments were analyzed. A model for the degradation kinetics, coupled with standard rheological relationships, was employed to extrapolate the measured sweeps to predicted curves at time zero, prior to degradation. The model is broadly applicable over a wide range of frequencies or shear rates, and generates a single degradation rate constant k for each polymer studied. A similar, although ad hoc, procedure was applied to the dynamic storage and loss moduli. The model provides a method for determining the rheological behavior of degrading polymers over a time interval, typically found in processing applications. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102:1794–1802, 2006     

Photoinitiated cationic polymerization using a novel phenacyl anilinium salt

A novel phenacyl anilinium salt, N-phenacyl, N,N-dimethylanilinium hexafluoroantimonate, (PDA), has been synthesized and used as photoinitiator for cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinyl carbazol (NVC). Plausible mechanism of the photoinitiation involves the decay of the excited PDA with both heterolytic and homolytic cleavages of carbon-nitrogen bond. Thus, phenacylium cations formed directly or subsequent intermolecular electron transfer, respectively, initiate the polymerization.     

共轭高分子三阶非线性光学材料

概述了ｎ－共轭高分子材料的三阶非线性光学性质，着重讨论了化学结构对其光学非线性的影响，说明了ｎ－共轭聚合物的三阶非线性极化率主要取决于共轭主链的结构，侧链取代基的变化对其非线性影响不大，文中展望了共轭高分子材料在集成光学中的应用前景。     

Study on phase behavior–impact strength relationship of unsaturated polyester/polyurethane hybrid polymer network

The phase behavior of a hybrid polymer network (HPN) composed of poly[(propylene glycol maleate)-co-(propylene glycol phthalate)] crosslinked with styrene and polyester–urethane crosslinked with methylene-bis-ortho-chloroaniline was examined. The correlation between phase separation and impact strength of the HPNs is discussed. The composition of HPNs has an effect on their properties.     

体外CFRP筋预应力混凝土箱梁长期受力性能试验研究

碳纤维(CFRP)筋具有优异的物理力学性能,可用于替代传统的预应力钢筋。制作了体外配置碳纤维筋预应力混凝土箱梁模型,对持续均布荷载作用箱梁的截面应力重分布、长期挠曲变形及裂缝发展等规律进行了1001 d的试验观测。基于素混凝土柱体的实测徐变系数,运用双线性法和曲率法分别对试验箱梁的长期挠曲变形进行预测。试验结果表明:受压钢筋应变较初值增长225%～268%,受拉钢筋的应变较初值增长36.2～38.6%,混凝土表面压应变较初值增长164%～224%。按现行设计规范计算长期荷载作用特征裂缝宽度较实测值偏小11.8%～55.5%。跨中长期挠曲变形实测值为初始变形的2.32～2.42倍,较现行设计规范取值偏大18.5%。