Leaching kinetics of Cs and Co radionuclides fixed in cement and cement-based materials

Leach characteristics of ¹³⁷Cs and ⁶⁰Co radionuclides from both ordinary Portland cement and cement mixed with two different ratios of silica fume and ilmenite have been studied using International Atomic Energy's (IAEA) standard leach method. A mathematical model has been simulated to predict the release rate of each nuclide from cubic geometry waste matrix and the predicted values are discussed in relation to experimentally observed leach rates to confirm the validity of the proposed mechanism in the model. The effect of temperature on the radionuclides leaching rates was also studied and the effective diffusion coefficients were obtained at different temperatures. The net fractional release of the two radionuclides from different waste forms showed a decreasing pattern as ¹³⁷Cs>⁶⁰Co, indicating the largest diffusion coefficient for cesium in all waste matrices.     

商品混凝土降低成本的技术途径

商品混凝土目前价格偏高 ,用户不情愿接受 ,影响了它的推广应用。针对这一问题 ,本文提出了用“活化填料”、“活化水泥”配制高性能商品混凝土的技术路线并分析了其技术经济效益     

Air entrainment in fresh concrete with PFA

The results of a study into the influence of PFA on air entrainment in fresh concrete are discussed It is shown that the required dosage of AEA to produce an air content of 5.5 ± 0.5% in a PFA modified concrete mix is two-six times that required in the corresponding neat OPC concrete mix. The dosage of a vinsol based air entraining agent (AEA) required appears to be directly related to the PFA content of the mix. Similar direct relationships were obtained with a range of different PFAs. The dosage of an AEA based on the salt of a fatty acid appears to be sensitive to both PFA and OPC contents. For the type of PFA used, the variability of measured air content or the amount of air retained after continued agitation both indicated that vinsol based AEAs show the highest variability whilst fatty acid based AEAs show low variability. The between batch variability of air content was significantly improved by the addition of PFA regardless of the AEA used.     

混凝土小砌块与普通砖混住宅楼造价分析

指出混凝土小型空心砌块是一种节能型的新型墙体材料。本文从经济角度对该种材料和粘土砖材料进行了实例分析、比较,得出了这种新型材料值得推广使用的结论。     

微粉对矾土基超低水泥浇注料性能的影响

以高铝矾土熟料为主原料 ,加入 2 %的铝酸钙水泥及总量为 6 %的Al2 O3 微粉和SiO2 微粉 ,配制了矾土基超低水泥浇注料 ,研究了微粉对浇注料的烧结性能、力学性能及热震稳定性的影响。结果表明 :(1 )SiO2 微粉对浇注料的促烧结作用优于Al2 O3 微粉。这是因为与Al2 O3 微粉相比 ,由气相沉积生成的SiO2微粉的粒度小 ,比表面积大 ,活性较高。 (2 )随着SiO2微粉加入量的增加 ,在 1 1 0 0℃和 1 4 0 0℃处理后的常温强度以及在 1 30 0℃和 1 4 0 0℃下的高温抗折强度和抗热震性明显提高。这是由于引入的SiO2 微粉在高温下与Al2 O3 反应生成的针状莫来石穿插进入刚玉骨架 ,起着明显的强化和韧化作用     

新型锚固水泥的研制

利用优质铁铝酸盐水泥熟料配制的锚固水泥具有早强、微膨胀、抗裂性能好、耐腐蚀性强等优点。水泥的初凝时间<5min,终凝时间<10min,0.5h的抗压强度超过12MPa,1h抗压强度超过22MPa,中后期强度增长稳定,各项性能满足锚固工艺的要求。     

玻璃钢筋混凝土的有限元计算与试验

钢筋混凝土广泛应用于土木工程领域，但其结构耐久性因钢筋本身的锈蚀成为现今急待解决的问题。人们一直在寻找对钢筋混凝土进行改良的途径，用玻璃钢筋代替普通钢筋是解决这一问题的一个有效的方法，为此进行了试验和ANSYS有限元分析，结果证明此法具有可行性。     

非木本木质素磺酸镁对水泥净浆和砂浆性能的影响

用红外光谱法等测定了非木本木质素磺酸镁的结构特征参数,研究了其对水泥净浆和砂浆性能的影响,并与木本木质素磺酸钙进行了对比。非木本木质素磺酸镁结构中的甲基、酚羟基、芳香环比木质素磺酸钙少;特性黏度为 0. 61mL/g,仅是木质素磺酸钙的 61%;磺化度为 0 78mmol/g,比木质素磺酸钙低约 40%。木质素磺酸镁溶液的最低表面张力为 49 82mN/m,起泡性能与木质素磺酸钙相近。非木本木质素磺酸镁对水泥净浆和砂浆减水分散作用为木本木质素磺酸钙的 86 6% ~91 1%。但掺质量分数 0 5%的木质素磺酸镁的砂浆, 28d的抗压强度比掺木质素磺酸钙的高 70 5%。     

Chemical Reaction Engineering and Research and development of gas solid systems

A general procedure is proposed for innovative research and development of gas-solid reactor systems, with a brief explanation of the significance of each step in the procedureBased upon the contacting mode between gas and solid phases, as well as the ways of supplying thermal energy to the reacting regions, various types of gas-solid reactor systems are classified by using tables of so called “matrix” form, for thermal cracking and gasification of heavy oils, gasification of coal, gasification of solid waste, calcination of limestone, clinkering of cement and reduction of iron ore.The importance of fundamental concepts is emphasized for successful research and development by presenting several examples; namely, calcination of limestone, thermal cracking of heavy oils and gasification of solid waste materials.In connection with the direction in which fundamental research should be oriented, four primary ways of thinking are proposed, which can be applied to obtain innovative ideas for further research and development in this field.One example of the author's practical experience was selected to show the role of the fundamental research in the course of large scale development. Finally the author outlines the role of chemical reaction engineering to innovate the novel gas-solid reactor systems which may be inevitable for simultaneous solution of the three big E's; namely, Energy, Environment and Economy.