高寿命弥散型透气砖的研制及应用

采用电熔Ａｌ２Ｏ３添加适量氧化铬和复合结合剂，试制出具有较好的抗周期性热冲击，抗侵蚀渗透和固结作用的高寿命弥散型透气砖。该砖透气性能理想，工作安全、可靠，实现了透气砖寿命与包龄同步。     

AZS烧结砖的研制

以电熔ＡＺＳ废砖为主要原料．配以ＡＺＳ复合结合剂和锆英砂．研制的ＡＺＳ烧结砖具有较高的荷重软化温度和耐压强度，显气孔率低．抗玻璃液侵蚀能力强．是较好的电熔ＡＺＳ砖的替代材料。通过对ＡＺＳ烧结砖的性能测试．分析了试样的物相和结构对其性能的影响，同时讨论了ＡＺＳ复合结合剂和锆英砂加入量与试样性能的关系，得出了试样的最佳配方。     

Transformation of hardening to softening behaviors induced by Sb substitution in CuO-doped KNN-based piezoceramics

Pb-free piezoceramics of K_0.5Na_0.5Nb_1-xSb_xO₃ + 1 mol% CuO are synthesized via a solid-state reaction. Furthermore, the transformation of hardening to softening behaviors induced by Sb substitution is exhibited and the corresponding microscopic mechanism is proposed. The CuO-doped K_0.5Na_0.5NbO₃ ceramic without adding Sb exhibits extremely hardening characteristics (i.e., ultrahigh Q_m of ∼2426, low tanδ of 0.32%, and pinched ferroelectric hysteresis loop) due to the formation of defect combinations (${({\text{Cu}}_{\text{Nb}}^{\text{'''}}-{\text{V}}_{\text{o}}^{••})}^{\text{'}}$ and ${({\text{V}}_{\text{o}}^{••}-{\text{Cu}}_{\text{Nb}}^{\text{'''}}-{\text{V}}_{\text{o}}^{••})}^{•}$). Whereas, the addition of Sb dramatically reduces the levels of defect combinations, leading to obviously softening properties (d₃₃ > 210 pC N⁻¹, k_p > 40%, low Q_m, and normal single P-E hysteresis loop). Our results indicate that the decrease of defect combinations with Sb addition should be responsible for the hardening-softening transformation of piezoelectricity and ferroelectricity in CuO-doped K_0.5Na_0.5Nb_1-xSb_xO₃ piezoceramics.     

尖晶石对铝尖晶石炭砖抗渣性的影响

研究了不同种类尖晶石及其加入量对铝尖晶石炭砖抗法性能的影响，分析了铝尖晶石炭砖的抗渣机理。     

Preparation of three-dimensional ordered macroporous SiCN ceramic using sacrificing template method

Three-dimensional (3D) long range well ordered macroporous SiCN ceramics were prepared by infiltrating sacrificial colloidal silica templates with the low molecular weight preceramic polymer, polysilazane. This was followed by a thermal curing step, pyrolysis at 1250 °C in a N₂ atmosphere, and finally the removal of the templates by etching with dilute HF. The produced macroporous SiCN ceramics showed high BET surface areas (pore volume) in the range 455 m²/g (0.31 cm³/g)–250 m²/g (0.16 cm³/g) with the pore sizes of 98–578 nm, which could be tailored by controlling the sizes of the sacrificial silica spheres in the range 112–650 nm. The sphere-inversed macropores were interconnected by 50 ± 30 nm windows and 3–5 nm mesopores embedded in the porous SiCN ceramic frameworks, which resulted in a trimodal pore size distribution. The surface of the achieved porous SiCN ceramic was then modified by Pt–Ru nanoparticle depositing under mild chemical conditions.     

Mn2+、Nb5+共掺BaTiO3陶瓷的制备及压电性能的研究

本文采用改进的固相反应法,制备了施主杂质Nb5 和受主杂质Mn2 共掺的BaTiO3陶瓷。按不同Nb5 、Mn2 的掺杂量,分别在1180℃、1210℃、1250℃、1280℃温度下煅烧。实验结果表明:当烧结温度为1250℃、掺杂量为0.05mol%时,制得的试样性能较好。     

包裹法国红色料在陶瓷领域应用的探索

探索包裹法国红色料在建筑陶瓷工业釉料、坯体中应用的工艺技术条件，采用正交实验方法找出包裹法国红色料在陶瓷釉料、外墙砖、地砖中的最佳发色条件：在釉料中一价的钾、钠离子特别利于该色料的发色；二价离子钡较好、钙次之、镁最差；法国红色料在普通熔块中发色不理想，在特制的熔块中发色良好。     

CaB6陶瓷研究的进展

综合介绍了CaB6陶瓷粉末、多晶体和单晶体的制备方法。评述了各种方法的基本原理和特点。合成CaB6粉末最常用的方法为碳化硼法，此方法能够以低成本制备较纯的CaB6粉末。但是得到的粉末具有硬团聚现象，使CaB6粉末的烧结有一定的难度。由于CaB6在高温下具有高的化学活性和低的塑性,CaB6多晶多采用热压烧结的方法在高温高压下制备。单晶的制备主要采用区熔法和熔剂法。区熔法适合于生产大尺寸的CaB6单晶，而铝熔剂法制备的CaB6单晶尺寸最大为5mm，对测定其某些物理性能有一定的局限。对CaB6陶瓷的应用及国内外研究现状作了简要的概括，并对其今后的发展趋势作了展望。     

低熔封接微晶玻璃无铅化的最新研究进展及其发展趋势

低熔封接微晶玻璃是一种先进的焊接材料，由于其具有低的熔化温度和封接温度，优良的机械强度和化学稳定性，而在很多领域中得到广泛的应用，实现了玻璃、陶瓷、金属、半导体间的相互封接。综述了无铅低熔封接微晶玻璃的研究现状，展望了无铅低熔封接微晶玻璃今后的研究发展方向。     

废旧轮眙回收利用现状和利用途径

针对废旧轮胎回收处理压力越来越大的难题，系统地分析了处理废旧轮胎的各种方法，对我国翻新轮胎，胶粉用于建筑市场、铺路建设，废胎直接用于热能市场等等的利与弊、现状与前景都做了较详细的论述。对废胎利用与管理上必要的立法问题对照国外先进国家的经验，提出了建设性的意见。