Preparation of ordered mesoporous SiCN ceramics with large surface area and high thermal stability

For the first time, highly ordered two-dimensional (2-D) and three-dimensional (3-D) mesoporous SiCN ceramics with high surface area and high thermal stability were prepared by nanocasting a preceramic polymer solution into mesoporous carbon templates, CMK-3 and CMK-8, respectively. As a negative replica of CMK-3 carbon, the obtained mesoporous SiCN ceramic possessed an ordered 2-D hexagonal mesostructure, which is similar to the structure of SBA-15 silica except for the reduced dimensions. An ordered 3-D cubic mesoporous SiCN ceramic was also fabricated using CMK-8 as a template. The wall of the mesoporous SiCN replicas consisted of an amorphous SiCN ceramic phase, which possessed high thermal stability at high temperature up to 1000 °C. N₂-sorption isotherms revealed that these ordered mesoporous SiCN ceramics have high BET surface areas (up to 472 m² g⁻¹) and narrow pore-size distributions, which was preserved even after a re-treatment at 1000 °C in air. The use of carbon template played an important role in the preparation of mesoporous SiCN replicas and enhanced the thermal stability of the SiCN products. It is expected that many other types of ordered mesoporous ceramics can be prepared from nanoporous carbon by nanocasting method.     

Heat‐resistant hydrophobic–oleophobic coatings

Thermally and chemically durable hydrophobic oleophobic coatings, containing different ceramic particles such as SiO₂, SiC, Al₂O₃, which can be alternative instead of Teflon, have been developed and applied on the aluminum substrates by spin‐coating method. Polyimides, which are high‐thermal resistant heteroaromatic polymers, were synthesized, and fluor oligomers were added to these polymers to obtain hydrophobic–oleophobic properties. After coating, Al surface was subjected to Taber‐abrasion, adhesion, corrosion, and thermal tests. The effects of the particle size of ceramic powders, organic matrix, and heat on the coating material were investigated. Coating material was characterized by FTIR spectrophotometer. Surface properties and thermal resistance of the coating materials were investigated by SEM and TGA analyses. After thermal curing, contact angles of these coatings with H₂O and n‐hexadecane were measured. It was observed that coatings like ceramic particles are more resistant against scratch and abrasion than the other coatings. Also, they are harder than coatings, which do not include ceramic particles. It was seen that coatings, containing Fluorolink D10H, have high‐contact angles with water and n‐hexadecane. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2386–2392, 2006     

一种新型超磁致压电混合精密位移机构的研究

为了研究大步距高精度精密位移机构,利用超磁致伸缩材料和压电陶瓷材料在驱动原理和使用方法上的相似性,提出一种超磁致伸缩材料与压电叠堆组成的混合驱动精密位移机构,介绍了机构运动原理及控制方式,制作了试验样机.测试表明,所研制的混合精密位移机构能实现双向可控运动,单步前进最大位移可达20μm,调节驱动电压可控制单步位移量,能满足大步距、高精度的驱动要求.     

Molten salts/ceramic-foam matrix composites by melt infiltration method as energy storage material

A new type of high temperature energy storage material was obtained through the melt infiltration method, using compounding SiC ceramic foam as matrix and Na₂SO₄ as phase change material. The resulting composite material was measured by XRD, SEM, TG-DSC methods. The experimental results indicate that the composite is composed of silicon carbide, sodium sulfate and square quartz, and no chemical reactions occurs between Na₂SO₄ and SiC matrix. Na₂SO₄ has a good bonding with the SiC ceramic foam matrix. As the composite material is characterized by high thermal energy storage density and high thermal conductivity, it is suit for energy storage under high temperature. Funded by the “863” Hi-Tech Research and Development Program of China (2008AA05Z418)     

数控超声磨削陶瓷叶片型面刀位轨迹计算

介绍了陶瓷超声磨削加工现状,建立了平行直纹面数学模型.分析了用圆柱磨轮四轴数控超声磨削平行直纹面时原理误差,并提出减小误差的措施,计算出磨轮空间轨迹,并进行陶瓷叶片型面超声磨削加工工艺试验.试验结果表明,超声磨削加工陶瓷叶片型面是可行的,所完成的刀位计算可有效减小原理误差.     

Effect of SiO2 addition on the dielectric properties and microstructure of BaTiO3-based ceramics in reducing sintering

The effect of SiO2 doping on the sintering behavior,microstructure,and dielectric properties of BaTiO3-based ceramics has been investigated.Silica was added to the BaTiO3-based powder prepared by the solid state method with 0.075mo1%,0.15mo1%,and 0.3mo1%,respectively.The SiO2-doped BaTiO3-based ceramic with high density and uniform grain size were obtained,which were sintered in reducing atmosphere.A scanning electron microscope,X-ray diffraction,and LCR meter were used to determine the microstructure as well as the dielectric properties.SiO2 can form a liquid phase belonging to the ternary system of BaO-TiO2-SiO2,leading to the formation of BaTiO3 ceramics with high density at a lower sintering temperature.The SiO2-doped BaTiO3-based ce-ramics can be sintered to a theoretical density higher than 95% at 1220℃ with a soaking time of 2 h.The dielectric constants of the sample with 0.15mo1% SiO2 addition sintered at 1220℃ is about 9000.Doping with a small amount of silica can improve the sinter-ing and dielectric properties of BaTiO3-based ceramics.     

淬硬钢硬态切削表面粗糙度研究

使用Ti—C基金属陶瓷刀具对45淬硬钢进行了切削试验,研究了切削用量对表面粗糙度的影响．试验分析表明,进给量对表面粗糙度影响最为显著,切削速度对表面粗糙度有一定影响,切削深度对表面粗糙度的影响很小．运用回归分析法,建立了硬态切削表面粗糙度预测模型,通过试验验证了预测模型的准确性．     

砖墙-钢筋砼剪力墙组合结构的抗震性能分析

砖墙-钢筋混凝土剪力墙组合结构是从砌体结构的基础上发展起来的一种新结构体系,该种结构在砼墙配置合理的情况下具有良好的抗震性能,在设防烈度为8度地区建造这种结构的房屋是可行的.     

粘贴碳纤维布砖砌体墙在低周反复荷载作用下的有限元分析

目的 研究碳纤维布加固砖砌体墙的抗震受力性能及不同的碳纤维布粘贴方式对砖砌体墙抗剪承载能力的影响,提出纵横粘贴碳纤维布和四面围束粘贴碳纤维布的方法.方法 对比交叉粘贴碳纤维布和横向粘贴碳纤维布,采用有限元分析软件ANSYS,模拟各种不同的碳纤维布粘贴方式,并对墙体和碳纤维布分别进行应力分析,对各种碳纤维布粘贴方式的抗剪承载力进行计算和比较.结果 交叉粘贴碳纤维布的墙体抗剪承载力较未加固墙体提高了5.6%,横向及纵横向粘贴碳纤维布加固墙体的抗剪承载力分别提高了11.4%～20.4%.四面围束粘贴碳纤维布加固墙体的抗剪承载力提高了20.3%.结论 在砖砌体墙表面粘贴的碳纤维布能够提高墙体的抗剪承载力,增加墙体的整体性,改善墙体抗震受力性能;纵向粘贴碳纤维布能够有效控制横向碳纤维布的剥离.     

生命周期评价在建筑陶瓷节能评估中的应用

以建筑陶瓷生产中的原材料开采、建筑陶瓷生产过程、运输过程中的直接环境影响和产品使用、电力生产、燃料生产的间接环境影响为研究对象,运用生命周期的评价方法,对建筑陶瓷生命周期的环境影响进行了定量研究,并为陶瓷生产行业的节能减排提供了对策及建议。