Electrochemical investigation of the iron-containing and no iron-containing AB5-type negative electrodes

The electrochemical behaviour of LaNi_3.55Mn_0.4Al_0.3Co_0.75−xFe_x (x = 0, 0.15, 0.55, 0.75) intermetallic compounds has been studied and presented [C. Khaldi, H. Mathlouthi, J. Lamloumi, A. Percheron-Guégan, Int. J. Hydrogen Energy 29 (2004) 307–311; C. Khaldi, H. Mathlouthi, J. Lamloumi, A. Percheron-Guégan, J. Alloys Compd. 360 (2003) 266–271; C. Khaldi, H. Mathlouthi, J. Lamloumi, A. Percheron-Guégan, J. Alloys Compd. 384 (2004) 249–253]. It has been deduced that the LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 compound has interesting electrochemical properties. In this paper we present the electrochemical study of LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 compound properties compared with the parent LaNi_3.55Mn_0.4Al_0.3Co_0.75 compound. Several techniques, such as, the chronopotentiometry, the constant potential discharge (CPD), the cyclic voltammetry (CV) and the linear polarization (LP) were applied to characterize these electrochemical properties. The electrochemical discharge capacity of the LaNi_3.55Mn_0.4Al_0.3Co_0.75 alloy increases to reach 294 mAh g⁻¹ after few cycles only (five cycles). However, the activation of the LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 alloy takes more than 20 cycles to be achieved and the obtained maximum discharge capacity is 194 mAh g⁻¹. The hydrogen diffusion coefficient D_H was determined by constant potential discharge and cyclic voltammetry techniques. The obtained values of the LaNi_3.55Mn_0.4Al_0.3Co_0.75 and LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 compounds are 6.29 × 10⁻¹¹ and 7.62 × 10⁻¹¹, and 2 × 10⁻⁸ and 7.5 × 10⁻⁸ cm² s⁻¹ by CPD and CV techniques, respectively. The exchange current density values, determined by a linear polarization technique, are 44 and 27 mA g⁻¹, respectively, for LaNi_3.55Mn_0.4Al_0.3Co_0.75 and LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 alloys.     

Mixed Micelles of Surface Active Ionic Liquid (SAIL)–Octylphenol Ethoxylate: A Novel Reaction Medium for Selective Oxidation of Toluene to Benzaldehyde

Ionic liquids have been found to be suitable alternatives to volatile organic solvents in chemical transformation. Through a proper choice of cations and anions, the properties of an ionic liquid can be tuned so that it resembles an amphiphile. Such specially designed molecules are known as surface-active ionic liquids (SAIL). Like conventional surfactants, SAIL also form aggregates in an aqueous medium. Studies show that the mixing of SAIL with conventional surfactants leads to synergistic micellization. However, very few reports are available on the application of such systems as reaction media. Present study focuses on the application of mixed micelles of 1-tetradecyl-3-methylimidazol-1-ium bromide, ([C₁₄mim]Br) with nonionic surfactant, Octylphenol ethoxylate with 10 moles of ethylene oxide (OPE-10). Enhanced solubilization and selective catalytic oxidation of toluene using hydrogen peroxide as an oxidant and tungstic acid as a catalyst have been studied in detail using this system.     

Design of a low temperature coefficient bandgap reference with a wide temperature range

In order to meet the requirements of different applications and markets for the accuracy and reliability of IoT chips,a low temperature coefficient bandgap reference with a wide temperature range is proposed.On the basis of the traditional Banba bandgap reference structure,the circuit utilizes high-order temperature compensation technology and piecewise temperature compensation technology to improve the curvature of the output reference voltage.The temperature coefficient of the circuit is reduced.At the same time,the operating temperature range of the circuit is extended.The circuit performances are verified in the TSMC 180 nm CMOS process.Test results show that the temperature coefficient of the circuit is as low as 7.2×10^-6/℃ in the range of-40 ℃ to 160 ℃.The power supply rejection ratio at a low frequency is -48.52 dB.The static current under the 1.8 V power supply voltage is 68.38 μA,and the core area of the chip is 0.025 mm².     

西南山区交通工程弃渣的工程特性评价及其分类

山区交通工程弃渣力学参数的准确测定,一直是弃渣场边坡稳定性评价面临的基础科学问题。在山区交通工程弃渣场运行特点和弃渣固体废弃物特征认知的基础上,探讨弃渣取样和试验代表性问题的物理根源,依托实际工程累计数据尝试提出简单实用的弃渣工程特性评价和分类方法。结果表明:①常规交通工程弃渣的密度、颗粒分析和强度试验,由于弃渣的粒径范围差异大、颗粒空间分布不均、弃渣来源复杂等固体废弃物特征造成取样和试验代表性难题; 用多阶段坡角测量和颗粒分析试验代替传统的弃渣边坡试验,解决了试验和取样代表性难题。②利用弃渣粗细比可将弃渣分为细粒弃渣、混合型弃渣和粗粒弃渣。③根据弃渣粗细比、天然休止角和整形坡率,将西南山区交通工程弃渣分为细粒弃渣、混合型弃渣和粗粒弃渣等3类。细粒弃渣,弃渣粗细比小于0.3,天然休止角小于31.5°,整形坡率为1.00:2.00; 混合型弃渣,弃渣粗细比为0.3～1.0,天然休止角为31.5°～39.5°,整形坡率为1.00:2.00～1.00:1.50; 粗粒弃渣,弃渣粗细比大于1.0,天然休止角大于39.5°,整形坡率为1.00:1.50。④用多阶段坡角测量、颗粒分析试验和无黏性土边坡稳定性系数计算公式代替传统的弃渣边坡试验和稳定性系数计算方法,方法简单,结果保守,可以作为弃渣边坡稳定性评价和安全控制技术的有益补充。     

基于BC聚类的差分隐私保护推荐算法

为提高差分隐私保护下推荐算法的准确性,提出了一种考虑差分隐私保护的基于Bhattacharyya系数（BC）的聚类推荐算法.以BC作为项目相似性度量的标准,根据BC相似性对项目进行K-medoids聚类,并在聚类簇中进行私有项目邻居选择.最后,根据最近邻居集信息,对用户的评分进行预测和Top-n推荐.提出的方案有效地克服了已有方法中存在的相似性度量依赖于共同评分的问题,提高了相似性度量的准确性,有效避免了因隐私保护而造成的最近邻居集质量下降的问题.理论分析和实验测试的结果表明,该方法在实现隐私保护的同时还能有效保证推荐的高质量,较好地实现了隐私保护和数据效用之间的平衡,具有良好的应用潜力.     

振荡翼改进运动模型的能量捕获性能分析

为了提高振荡水翼的水动力性能和能量捕获效率,基于传统简谐运动模型提出改进运动模型,通过引入俯仰运动系数k,推导改进后俯仰运动规律的一般形式,利用Fluent软件建立水翼的二维模型,综合分析半主动振荡模型下不同俯仰运动系数、折算频率和俯仰振幅等运动参数对水翼能量捕获性能的影响。结果表明:与传统简谐运动模型相比,改进运动模型能够使水翼升力系数在较长时间段内维持较大数值,提高水翼的升力系数和捕能效率;在相同的折算频率和俯仰振幅下,减小俯仰运动系数会增大俯仰角转动的角速度,进而增大俯仰运动所消耗的能量;不同俯仰振幅下对应不同的最优折算频率,折算频率越低水翼的捕能性能越不稳定,俯仰振幅越大,转动俯仰角所消耗的能量越多。在给定参数条件下,水翼的能量转化效率可超过40%。     

ON THE COMPOSITION UNIFORMITY AND SHAPE COEFFICIENT OF MOLTEN POOL BY LASER ALLOYING

The effect of the laser processing parameters on the composition uniformity and shapecoefficient of fusion zone with laser surface alloyed Cr plated on medium carbon low alloysteel has been studied.It was found that the composition uniformity depends on the shapecoefficient of fusion zone,and the later is a function of both power density and interactiontime.If the power density is fixed to a certain value,the shape coefficient is directly,propor-tional to the interaction time.A completely,uniform molten pool can be obtained,when theshape coefficient is between 1.6 and 3.0.     

卡盘的若干设计计算问题

以“夹持系数”取代传统的摩擦系数；对卡盘的主要零件重新进行了受力分析，推导出能满足各零件设计计算之用的计算公式；并提出了提高卡盘夹持能力的有效措施：（１）减小卡瓦和卡圈斜面之间的摩擦系数；（２）提高卡瓦和主动钻杆之间的夹持系数     

一种基于RSA安全可行的（t，n）门限签名方案*

分析了大多数RSA门限群签名方案存在的缺陷,RSA的模数是n,φ(n)是秘密参数,参加部分签名的成员无法知晓,求Lagrange相关系数存在困难,也为建立门限RSA密码体制带来困难.提出一种新的方案以克服上述困难,通过求ai无须在求Lagrange相关系数时进行求逆运算,使该方案在保证安全的前提下变得可行实用.     

相对压强对白炭黑氮吸附表面积测试稳定性的影响

研究相对压强对白炭黑氮吸附表面积测试稳定性的影响。结果表明:在相同液氮纯度、脱气温度、脱气时间、氮吸附点数量条件下,与相对压强范围为0.05~0.1时相比,相对压强范围为0.05~0.2时白炭黑的氮吸附表面积测量值偏低,且差值随氮吸附表面积的增大呈增大趋势;相对压强范围较小时,氮吸附表面积测试结果的线性相关因数较大,再现性较好,测试结果较稳定。