全文获取类型
收费全文 | 51553篇 |
免费 | 5437篇 |
国内免费 | 3504篇 |
专业分类
电工技术 | 2798篇 |
技术理论 | 1篇 |
综合类 | 4729篇 |
化学工业 | 8823篇 |
金属工艺 | 3762篇 |
机械仪表 | 2249篇 |
建筑科学 | 3583篇 |
矿业工程 | 2939篇 |
能源动力 | 2412篇 |
轻工业 | 4458篇 |
水利工程 | 1735篇 |
石油天然气 | 3010篇 |
武器工业 | 631篇 |
无线电 | 4727篇 |
一般工业技术 | 5520篇 |
冶金工业 | 3624篇 |
原子能技术 | 1316篇 |
自动化技术 | 4177篇 |
出版年
2024年 | 193篇 |
2023年 | 686篇 |
2022年 | 1364篇 |
2021年 | 1661篇 |
2020年 | 1853篇 |
2019年 | 1562篇 |
2018年 | 1563篇 |
2017年 | 2006篇 |
2016年 | 2159篇 |
2015年 | 2187篇 |
2014年 | 3248篇 |
2013年 | 3638篇 |
2012年 | 3961篇 |
2011年 | 4114篇 |
2010年 | 2982篇 |
2009年 | 2909篇 |
2008年 | 2657篇 |
2007年 | 3244篇 |
2006年 | 2788篇 |
2005年 | 2353篇 |
2004年 | 2059篇 |
2003年 | 1808篇 |
2002年 | 1520篇 |
2001年 | 1299篇 |
2000年 | 1112篇 |
1999年 | 943篇 |
1998年 | 777篇 |
1997年 | 667篇 |
1996年 | 618篇 |
1995年 | 526篇 |
1994年 | 418篇 |
1993年 | 303篇 |
1992年 | 302篇 |
1991年 | 209篇 |
1990年 | 196篇 |
1989年 | 135篇 |
1988年 | 98篇 |
1987年 | 61篇 |
1986年 | 60篇 |
1985年 | 55篇 |
1984年 | 52篇 |
1983年 | 25篇 |
1982年 | 26篇 |
1981年 | 16篇 |
1980年 | 20篇 |
1978年 | 7篇 |
1977年 | 4篇 |
1975年 | 10篇 |
1959年 | 10篇 |
1951年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
12.
Strain rate is not only an important measure to characterize the deformation property, but also an important parameter to analyze the dynamic mechanical properties of rock materials. In this paper, by using the SHPB test system improved with high temperature device, the dynamic compressive tests of sandstone at seven temperatures in the range of room temperature to 1000 °C and five impact velocities in the range of 11.0–15.0 m/s were conducted. Investigations were carried out on the influences of strain rate on dynamic compressive mechanical behaviors of sandstone. The results of the study indicate that the enhancement effects of strain rates on dynamic compressive strength, peak strain, energy absorption ratio of sandstone under high temperatures still exist. However, the increase ratios of dynamic compressive strength, peak strain, and energy absorption ratio of rock under high temperature compared to room temperature have no obvious strain rate effects. The temperatures at which the strain rates affect dynamic compressive strength and peak strain most, are 800, and 1000 °C, respectively. The temperatures at which the strain rates affect dynamic compressive strength and peak strain weakest, are 1000 °C, and room temperature, respectively. At 200 and 800 °C, the strain rate effect on energy absorption ratio are most significant, while at 1000 °C, it is weakest. There are no obvious strain rate effects on elastic modulus and increase ratio of elastic modulus under high temperatures. According to test results, the relationship formula of strain rate with high temperature and impact load was derived by internalizing fitting parameters. Compared with the strain rate effect at room temperature condition, essential differences have occurred in the strain rate effect of rock material under the influence of high temperature. 相似文献
13.
This work is devoted to the stress–strain state of isotropic double curved shell with defect system. The construction is weakened by two non-through thickness (internal) cracks of different length and by a circular hole located between cracks. In this study we use the line-spring model. Within the framework of this model cracks are modeled as mathematical cuts of shell’s middle surface. This leads to a two-dimensional problem. The problem is reduced to a system of eight boundary integral equations. To ensure the uniqueness of solution an additional equation is added. In the numerical solution of the problem special quadrature formulas for singular integrals of Cauchy type and the finite difference method are applied. The influence of defects on each other for double curved shell has been investigated. The given theoretical results can be used for the calculation of structural elements with holes, cracks on the strength and fracture toughness in various branches of engineering. 相似文献
14.
15.
《International Journal of Hydrogen Energy》2021,46(70):34970-34982
Alloy hardened steels offer excellent combination of mechanical properties, hardenability and corrosion resistance. 34CrMo4 is a medium carbon, low alloy steel widely used due to a good combination of high-strength, toughness and wear resistance. However, this steel experiences hydrogen embrittlement (HE), a complex phenomenon depending on the composition and microstructure. This work estimates de loss of the mechanical properties caused by hydrogen in electrochemically H-charged specimens in absence of mechanical stress but also, at low strain rate and constant load. H-charging for 2 and 6 h induce YS losses of about 40% and 71% and UTS losses of 39% and 59%, respectively. The synergistic effect of the stress and the H-charging process leads to a higher loss, 91%, and a faster brittle fracture even though hydrogen content is similar to those firstly H-charged and then tested in air. 相似文献
16.
17.
In the present work, a rheological study of liquid soaps prepared from different mixture of surfactants as a function of surfactant type and concentration was performed. The curves of shear stress vs. shear rate and viscosity vs. shear rate were recorded at constant temperature, 294 ± 0.1 K. The surface activity properties were also studied. The results of the study showed that values of surface tension, γ, were in the range 31–40 mN m−1 and the critical micelle concentration (CMC), was of the order 10−4 mol L−1. The calculated maximum surface excess, Γmax, varied from 2.40 to 3.66 μmol m−2, while minimum area per molecule, Amin, varied from 41.1 (for amphoterics) to 81.4 Å2 (for nonionic surfactants). The standard free energy of micellization, −29.8 and −29.3 kJ mol−1 for anionic and amphoteric surfactants, respectively, were while values for nonionic surfactants varied between −31.8 and − 30.3 kJ mol−1. The free energy of adsorption, was the lowest for amphoteric surfactants (−37.9 kJ mol−1), followed by anionics (−40.4 kJ mol−1) and nonionics (−43.34 to −46.84 kJ mol−1), indicating that micellization process is spontaneous in the examined medium. The synthetized liquid soaps show pseudoplastic behavior and they achieved pipe flow. The results of this research indicate that flow behavior was affected significantly by the ionic charge of the surfactant and the ionic strength of the formulation, suggesting that the flow behavior could be changed by manipulating the choice of the surfactant and salinity. The pH value of all liquid soaps examined were weakly acidic, in the range of 5.0–6.4. 相似文献
18.
The mechanical integrity of battery separators is critical for battery safety and durability. A comprehensive study of strain‐rate‐dependent tensile and puncture properties of a polypropylene lithium‐ion battery separator is presented here with a new model. Due to anisotropy of the polymeric membrane, tensile testing was conducted for different directions. Results showed that tensile strength and elastic modulus were increased 1000% and 500%, respectively, for different directions. It was also demonstrated that tensile strength changed 10 to 25% with strain rate (1.67 × 10?4 to 1.67 × 10?1 s?1) for different directions. An equation was obtained for the first time for flow stress versus strain rate at varied tensile directions with respect to machine direction. Moreover, puncture testing was performed and it was shown that puncture strength was increased 140% with increasing strain rate from 0.25 to 250 mm min?1. Two failure modes were also observed in puncture samples. Finally, Eyring's model was used to calculate activation enthalpy of the porous polypropylene separator. © 2020 Society of Chemical Industry 相似文献
19.
Three N-heteroleptic Pt(II) complexes, [Pt(C^C)(O^O)] [O^O = acetylacetonate, C^C = 1-phenyl-1,2,4-triazol-5-ylidene (1), C^C = 4-phenyl-1,2,4-triazol-5-ylidene (2), C^C = 2-phenylpyrazine (3)] have been investigated with density functional theory (DFT) and time-dependent density functional theory (TDDFT). The radiative decay rate constants of complexes 1–3 have been discussed with the oscillator strength (fn), the strength of spin–orbit coupling (SOC) interaction between the lowest energy triplet excited state (T1) and singlet excited states (Sn), and the energy gaps between E(T1) and E(Sn). To illustrate the nonradiative decay processes, the transition states between triplet metal-centered (3MC) and T1 states have been optimized and were verified with the calculations of vibrational frequencies and intrinsic reaction coordinate (IRC). In addition, the minimum energy crossing points (MECPs) between 3MC and ground states (S0) were optimized. At last, the potential energy curves relevant to the nonradiative decay pathways are simulated. The results show that complex 3 has the biggest photoluminescence quantum yield because the complex 3 has the biggest radiative decay rate constant and the smallest nonradiative decay rate constant in complexes 1–3. 相似文献
20.
In this study, 30 subjects were exposed to different combinations of air temperature (Ta: 24, 27, and 30°C) and CO2 level (8000, 10 000, and 12 000 ppm) in a high-humidity (RH: 85%) underground climate chamber. Subjective assessments, physiological responses, and cognitive performance were investigated. The results showed that as compared with exposure to Ta = 24°C, exposure to 30°C at all CO2 levels caused subjects to feel uncomfortably warm and experience stronger odor intensity, while increased mental effort and greater intensity of acute health symptoms were reported. However, no significant effects of Ta on task performance or physiological responses were found. This indicated that subjects had to exert more effort to maintain their performance in an uncomfortably warm environment. Increasing CO2 from 8000 to 12 000 ppm at all Ta caused subjects to report higher rates of headache, fatigue, agitation, and feeling depressed, although the results were statistically significant only at 24 and 27°C. The text typing performance and systolic blood pressure (SBP) decreased significantly at this exposure, whereas diastolic blood pressure (DBP) and thermal discomfort increased significantly. These effects suggest higher arousal/stress. No significant interaction effect of Ta and CO2 concentration on human responses was identified. 相似文献