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921.
922.
黄河下游河道萎缩致灾机理探讨 总被引:9,自引:4,他引:5
本文基于水力学原理,结合实体模型试验及原型实测资料分析,探讨了黄河下游河道萎缩的概念、致灾效应和致灾机理。分析表明,河道萎缩是造床过程中河道排洪输沙功能衰退的一种演变现象,其致灾效应是使洪水涨率增大,同流量下洪水水位不断抬升。致灾的现象主要表现在畸型河势增加、工程险情增多、直接造成工程损失及滩区经济损失等。试验研究揭示,主河槽宽度缩窄造成洪水水位涨幅增大,河底平均高程抬升和过水断面面积减小造成洪水水位起涨的基准面抬升是河道萎缩致灾的主要原因。河道萎缩致灾效应的大小与萎缩模式有关,其中以“集中淤槽”模式所形成的致灾效应尤为明显。 相似文献
923.
Todd M. Alam Joshua U. Otaigbe Dave Rhoades Gregory P. Holland Brian R. Cherry Paul G. Kotula 《Polymer》2005,46(26):12468-12479
Nanostructured polymer blends prepared via anionic ring opening polymerizations of cyclic monomers in the presence of a pre-made polymer melt exhibit a number of special properties over traditional polymer blends and homopolymers. Here, we report on a simple and versatile method of in situ polymerization of macrocyclic carbonates in the presence of a maleic anhydride polypropylene (mPP) matrix and a surface-active compatibilizer (i.e. PC grafted onto a mPP backbone generated in situ) to yield a micro- and nanostructured polymer blends consisting of a polycarbonate (PC) minor phase, and a polypropylene (PP) major phase. By varying the processing conditions and concentration of the macrocyclic carbonate it was possible to reduce the size of the PC dispersions to an average minor diameter of 150 nm. NMR and TEM characterizations indicate that the PC dispersions do not influence crystal content in the PP phase. Overall, the results point to a simple strategy and versatile route to new polymeric materials with enhanced benefits. 相似文献
924.
Du Young Choi Long Mei Jin Dexian Wang Kyung Ho Row 《Korean Journal of Chemical Engineering》2005,22(3):465-469
High-performance frontal analysis (HPFA) was used for a protein binding study of isoflavones (daidzein, genistin, and genistein),
enantiomers of perillyl alcohol and S-ibuprofen to human serum albumin (HSA). The analyses were performed on a Develosil and
Inertsil 100-Diol-5 column (10 cm×4.6mm). Sodium phosphate solution (pH 7.4, ionic strength 0.17) was used as the mobile phase
at a flow rate of 1 ml/min. To ensure the drug to be eluted as a trapezoidal peak with a plateau, injection volumes were each
fixed up the zonal profile with an evident plateau appears. The unbound drug concentration was determined from a plateau height
of the plateau region after that experimental data were fitted by Scatchard equation. The binding constants (K) and total
binding affinities (nK) of drugs to HSA were calculated, respectively. 相似文献
925.
Kwang-Hee Lim 《Korean Journal of Chemical Engineering》2005,22(2):228-233
An experiment for five stages of a biofilter-run was performed to investigate the effect of hydrophilic ethanol and hydrophobic
toluene on the biodegradation of hydrophobic toluene and hydrophilic ethanol, respectively, when waste-air containing toluene
and ethanol was treated by a biofilter. Removal efficiencies of toluene and ethanol began to decrease when inlet load surpassed
90 g/m3/h and 100 g/m3/h consistent with maximum elimination capacities of toluene and ethanol, respectively. At the end of the biofilter-run, removal
efficiencies for toluene and ethanol were decreased and maintained at 65% and 40%, respectively. The concentration of toluene
at 1st sampling port was raised by factor of two in the 3rd stage of the biofilter run when the inlet load of ethanol co-feed
was increased by 1.5 times, while the process conditions of toluene were maintained the same as those of the 2nd stage of
biofilter-run. According to the result of Mohseni and Allen, it may be interpreted that removal efficiency of hydrophobic
toluene was affected by the presence of hydrophilic ethanol when high load of hydrophobic toluene was applied like that of
the 1st sampling port of the biofilter. However it was not the case when a low load of hydrophobic toluene was applied like
those of the 2nd, 3rd and 4th sampling ports since hydrophobicity of toluene is much less that of α-pinene. Thus, it may be
suggested that biodegradation of hydrophobic VOC was interfered by hydrophilic VOC dissolved in the biolayer and the degree
of interference was proportional to the inlet load of hydrophobic VOC as well as that of hydrophilic VOC and was inversely
proportional to the solubility of hydrophobic VOC. However, it was inferred that the existence of hydrophobic toluene from
waste-air can hardly inversely hinder the removal of hydrophilic ethanol in the biofilter when timeevolutions of hydrophilic
ethanol concentrations of this experiment were compared with those of the previous experiment of biofilter to treat waste-air
containing ethanol only. 相似文献
926.
A simple mathematical analysis on the effect of sand in Cr(VI) reduction using zero valent iron 总被引:1,自引:0,他引:1
A simple mathematical model was proposed to analyze the enhancement of Cr(VI) reduction when sand materials are added to the
zero valent iron (ZVI). Natural decay of Cr(VI) in a control experiment was analyzed by using a zero-order decay reaction.
Adsorption kinetics of Cr(VI) to sand was modeled as a first-order reversible process, and the reduction rate by ZVI was treated
as a first-order reaction. Natural decay of Cr(VI) was also included in other experiments, i.e., the adsorption to sand, the
reduction by ZVI, and both adsorption and reduction when sand and ZVI are present together. The model parameters were estimated
by fitting the solution of each model to the corresponding experimental data. To observe the effect of sand addition to ZVI,
both adsorption and reduction rate models were considered simultaneously including the natural decay. The solution of the
combined model was fitted to the experimental data to determine the first-order adsorption and reduction rate constants when
sand as well as ZVI is present. The first-order reduction rate constant in the presence of sand was about 35 times higher
than that with ZVI only. 相似文献
927.
928.
Photoluminescence features in a commercial grade cured DGEBA-based epoxy resin have been investigated with as objective to determine which of the material compounds are responsible for cured resin emissions. The origin of the bands has been approached by considering photoluminescence of base resin and hardener taken separately, of their mixture, and in the course of curing. Most of the bands observed in the cured resin could be interpreted based on those found in the components taken separately. Fluorescence of the cured resin appears dominated by two broad bands that are characteristic of the hardener and exhibits a blue shift by up to 30 nm in the course of curing which could be used for cure monitoring purpose of the investigated system. Fluorescence of the base resin is clearly detected in the resin cured with tertiary amine as catalyser. However, it is very weak if the catalyser is not added. Two phosphorescence processes have been isolated in the cured resin, one of them being related to the base resin. Finally, a chemiluminescence spectrum has been recorded in the course of curing, which has been related to either curing-related reactions or to an oxidation process. 相似文献
929.
This article describes two interviews with Theodor Reik. Explored topics include Reik's relationship with Sigmund Freud, psychoanalytic literature, and the history of the psychoanalytic movement. The author concludes with an analysis of his impressions of Reik. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
930.
以水资源可持续发展为出发点,探讨了一种可以同时兼顾经济发展、水资源利用和社会效益的多目标水资源宏观经济模型的建立方法,通过引入带权2-模评价函数,将多目标优化问题转变成单目标优化问题。以2002年为现状水平年,对安徽省2010年的产业结构及产业规模进行优化分析。结果表明,多目标模型求得的总用水量较单目标模型明显降低,而两模型优化的产业规模与结构差别不大,体现了高用水效率行业优先发展的要求。 相似文献