高强度钢的Zn—Ti合金新镀层

本文研究了一种Ｚｎ－Ｔｉ合金新镀层，经盐水浸泡、中性盐雾和大气暴露试验结果试验，其耐蚀明显超过镀Ｚｎ层，并与镀Ｃｄ层相近，用缺口持久拉伸试验检验氢脆性，拉伸持续时间超过２００ｈ，达到原航空部部颁标准（ＨＢ５０６７－８５），该镀层适用于高强度钢防护。     

Electrosynthesis and impedance studies on zinc selenide

Electrochemical impedance measurements have been used to characterize zinc selenide films prepared by electrochemical co-deposition at a platinum rotating disk electrode. Estimations of capacitance and polarization resistance of variously prepared electrodeposits have been carried out to determine charge carrier density and corrosion rates.     

The influence of NaCl and CO2 on the atmospheric corrosion of magnesium alloy AZ91

The influence of NaCl and CO₂ on the atmospheric corrosion of magnesium alloy AZ91 is studied in the laboratory. Samples were exposed under carefully controlled air and flow conditions; the relative humidity was 95%, the temperature was 22.0°C and the concentration of CO₂ was < 1 ppm or 350 ppm. Different amounts of sodium chloride (0–70 μg/cm²) were added before exposure. The corrosion products were analyzed by gravimetry, ion chromatography, X‐ray diffraction and scanning electron microscopy. Mass gain and metal loss results are reported. The combination of high humidity and NaCl is very corrosive towards AZ91. However, the NaCl‐induced corrosion is inhibited by ambient concentrations of CO₂. Exposure in the absence of CO₂ gives rise to heavy pitting, with brucite, Mg(OH)₂, being the dominant corrosion product. In the presence of CO₂ a layer of hydrated magnesium hydroxy carbonate, Mg₅(CO₃)₄(OH)₂ · 5 H₂O forms. A tentative corrosion mechanism is presented that explains the behavior in the two environments.     

熔融 NaCl-(Na,K)_2SO_4引起的 Fe-Cr 合金的热腐蚀

本文采用电化学方法研究了 Fe-Cr 合金在800℃、熔融 NaCl-(Na,K)_2SO_4中的腐蚀行为,并对腐蚀产物进行了观察和分析。结果表明,提高合金 Cr 含量可以改善合金耐蚀性能。氧化-硫化是Fe5Cr、Fe10Cr 合金腐蚀破坏的主要方式;氧化膜的熔融反应是 Fe20Cr、Fe25Cr 合金加速腐蚀的主要原因。同时,氧化膜的机械破裂也加速了合金的腐蚀。     

A3钢的工业大气腐蚀

在辽宁省工业城市进行 A3钢大气暴露试验。两年后测出不同地点腐蚀率。依据所记录的各试验点的气象数据和污染数据,讨论了 A3钢的大气腐蚀规律。     

离子注入对铁及其低合金、铝及其合金耐腐蚀性能的影响

离子注入对金属腐蚀行为的研究已达30年．研究结果表明离子注入对改变金属表面成分和表面性能是极为有效的技术．本文概述了离子注入对铁及其低合金、铝及其合金的腐蚀电化学行为的影响．涉及的注入离子达十余种。     

Preparation of core–shell structured alumina–polyaniline particles and their application for corrosion protection

Polyaniline (PANI) was synthesized by chemical oxidative polymerization of aniline (ANI) in the presence of alumina (Al₂O₃) particles. The polymerization of ANI occurred preferentially on the surfaces of the particles, resulting core–shell structured alumina–polyaniline (Al₂O₃‐PANI) particles. Morphology examination showed that with decreasing of the weight ratio of Al₂O₃/ANI in the reactants, the thickness of the PANI layer increased and changed from an even surface morphology to a particulate morphology. UV–vis and Fourier transformed infrared (FTIR) spectra indicated that there is no chemical interaction between the PANI layer and the Al₂O₃ surfaces. The PANI layer adhered well to the particles and can be used as anticorrosive fillers for polymer coatings. Enhanced corrosion protection performance was achieved for the emeraldine base (EB) form of PANI deposited Al₂O₃ particles (Al₂O₃‐EB) filled epoxy coating on carbon steel in 3.0 wt % aqueous NaCl solution. The particles demonstrate both excellent corrosion protection performance and lower cost, which will be of great importance in practical applications. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 4372–4377, 2006     

燃料性质对加热炉腐蚀结焦的影响及其防治

从加热炉燃料变化情况入手 ,分析了加热炉目前存在的炉管结垢 ,预热器烟气露点腐蚀以及炉体腐蚀等问题。从机理上进行了探讨 ,从而提出了原油脱金属、燃料气脱硫、燃料油优化、化学除垢以及预热器改造等防护措施。     

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四川目前生产的天然气中含硫天然气占７１％，而含硫天然气对高强度钻杆会产生硫化物应力腐蚀玻裂，因此，在含硫气井进行钻杆测试时，应重视钻杆的安全问题。文章探讨了高强度钻杆硫化物应力腐蚀玻裂的机理和影响钻杆脆断时间的各种因素，并提出在一定的条件下，高强度钻杆在含硫气并中进行测试是安全的。采用向钻杆内加缓蚀剂或内涂层钻杆，防硫油管测试，钻杆测试更加安全。建议继续开展高强度钻杆硫化物应力腐蚀玻裂时间的试验研究，以确定合理的钻杆测试安全时间。     

Dental amalgam – the effect of the technology of alloy powder preparation on the corrosion behaviour and the release of mercury

Dental amalgams are based on a broad spectrum of materials differing in their chemical composition, metallurgical treatment, and in the way the initial alloys powders are prepared. In addition to their chemical composition, amalgams based on various powders differ in both their microstructure and the amount of mercury needed for preparation. All these facts may affect electrochemical processes occurring during their interaction with oral fluids, and also mercury release. While verifying the effect of the technology used for the preparation of the high‐copper ternary alloy powder on the properties of resulting amalgams, this study aimed at the mechanism of their interaction with a model saliva solution as well as mercury release was included. Measurements were done in a model saliva solution using standard electrochemical methods and exposition measurements. The interaction of individual types of amalgams with artificial saliva did not reveal any significant differences. The free corrosion potential of all these amalgams in an aerated solution settled in the range of values in which tin oxidation, resulting in a layer of insoluble corrosion producsts, turned out to be the dominant anodic process. The rate of mercury release was the lowest for amalgams based on a gas‐atomized alloy. The highest rate of mercury release, and also its dependence on time, was exhibited by lathe‐cut powder based amalgam. In addition to different volume fraction of the Ag‐Hg phase and the level of its tin alloying, this different behaviour may be explained by differences in the rate at which a layer of tin corrosion products acting as a barrier to mercury release is formed.