交变电场结合后处理技术对点蚀破坏电极的修复机理

针对开发的点蚀破坏电极的修复技术——交变电场(AEF)结合后处理技术，应用循环伏安、动电位极化、能谱以及光谱表征技术分别研究了AEF的反应实质与后处理的作用，并结合形貌与光谱表征技术剖析了蚀孔处的修复结果；在此基础上，探讨了该技术的修复机理．     

高性能鳞片涂料在脱硫烟囱防腐蚀中的应用

分析了湿法烟气脱硫工艺对脱硫装置及烟囱的腐蚀情况，对几种典型的衬里结构进行比较，介绍了高性能防腐蚀鳞片涂料的应用要求和工程实例。     

Effect of electrolysis superheat degree on anticorrosion performance of 5 Cu/（10NiO-NiFe2O4） cermet inert anode

5Cu/(10NiO-NiFe2O4) cermet inert anodes were prepared by cold-pressing and sintering process, and the effect of superheat degree of melting K3AlF6-Na3AlF6-AlF3 on their anticorrosion performance was studied under electrolysis conditions. The results show that, the fluctuation of cell becomes small with increasing of superheat degree, which is helpful to inhibit the formation of cathodic encrustation; the concentration of impurities from inert anode in bath goes up to certain degree, but it is far smaller than those in traditional high-temperature bath. Increasing the superheat degree of melting K3AlF6-Na3AlF6-AlF3 has unconspicuous effect on the contents of impurities in cathodic aluminum. The total mass fractions of Fe, Ni and Cu in aluminum are 15.38% and 15.09% respectively under superheat degree of 95 and 195 ℃. From micro-topography of anode used view, increasing the superheat degree can aggravate corrosion of metal Cu in inert anode, and has negative influence on electrical conductivity of electrode to some extent.     

Advanced Coatings on Furnace Wall Tubes

Nickel-based self-fluxing alloy coating extends the service life of furnace wall tubes at waste incineration plants due to its excellent corrosion resistance and heat resistance. Fusing of such coatings by induction heating offers improved efficiency and reliability of products. Compared with conventional plasma, flame, and high-velocity oxy-fuel spraying thermal-sprayed coatings, induction-fused coatings provide a far stronger metallurgical bond at the interface, while minimizing the inclusion of pores. In addition, the tubes are less costly than those with welded coatings, and the process reduces the distortion of the products, facilitating easier final assembly. A successful experimental application of 11 units in a waste incinerator revealed virtually no corrosion on the exposed surfaces, and showed an improved water heating efficiency over that of the original tubes. Such units are now being employed in four incinerators in Taiwan, and continuing tests are showing great promise.     

Evaluation of different coating systems by electrochemical methods

Corrosion protection of organic coated steel is determined by free corrosion potential measurements and impedance spectroscopy. The results are classified by means of very basic considerations and evaluation figures are developed. These electrochemical data are correlated with the extent of the corrosion for each coating system. The evaluation figures are used for ranking coating systems and this ranking is correlated with the ranking with reference to the results of standardized and exposure tests.     

W—311^#耐腐蚀SMC树脂的开发研究

本文介绍了Ｗ－３１１＾＃ＳＭＣ不饱和聚酯树脂的研制及制品耐水、耐腐蚀性能。实际应用表明，该树脂适合ＳＭＣ成型工艺要求，为优良的耐腐蚀ＳＭＣ树脂。     

Unusual W-shaped Galvanic Cell Model of ISCC of α-brass in Neutral Mattsson''''s Solution

Intergranular stress corrosion cracking(ISCC) of α-brass in neutral Mattsson's solutionwas found to be controlled by an unusual"W"-shaped galvanic cell whose cathode is thegrain boundary oxide film (G.B.0. film) andsurface film and the anode is fresh metal atthe cracked tip on both sides of the G.B.0.film. Redox reactions involved in the cellhave been proposed here. According to thismdel, initidtion of ISCC is caused by therupturing of surface film along grain boundaries,thus forming a galvanic cell. Propagation ofISCC resulted from alternate advances of G.B.0.film and dissolution on both sides of G.B.0.film caused by the effect of electrochemicalreaction. This work developed an effective approachto investigate the embrittlement process atthe tip of the crack, by increasing the lengthof the embrittlement region through constantstrain test and distinguishing the morphologyand the nature of the corrosion products byoptical microscopy and scanning electronmicroscopy (SEH).     

多水平外区抑制的轮廓检测

提取自然图像中的物体轮廓是机器视觉研究的重要问题,主要困难在于自然图像中的纹理性边缘严重干扰了物体轮廓的提取。研究表明视皮层方位选择性神经元的非经典感受野机制使得人类视觉系统在处理自然图像时不仅能够抑制纹理性边缘,而且能够增强物体的轮廓。基于此人们提出多种仿生轮廓检测算法,但算法中被称为抑制水平的参量在取值较高时会漏检部分轮廓,而在其取值较低时又会引入过多的纹理性边缘。针对这一问题,提出多水平外区抑制轮廓检测算法,通过整合各级单水平外区抑制的检测信息,有效抑制了纹理性边缘和降低了漏检轮廓的可能性。实验结果表明,相对于传统算法,新算法在轮廓检测性能上提高了10%左右,并具有更好的稳健性。     

基于像素差异的金属腐蚀区域分割仿真研究

研究基于图像的金属腐蚀区域分割问题,提高分割区域的准确性。针对传统基于金属本身与腐蚀颜色的区别,利用像素差异的变化进行腐蚀区域的分割,因当腐蚀颜色与金属的本体颜色相差不是很大,或者在边沿发生像素的混淆时,利用差异边缘像素相减的方法很难完整分割腐蚀区域的问题。为了解决上述问题,提出利用空间像素差异距离聚类的金属腐蚀区域图像分割算法。通过计算差异像素之间的差异距离概率,将差异像素特征进行严格划分,对划分后的结果进行排序计算,详细描述混淆边沿信息,对腐蚀区域进行完整分割。实验证明,改进方法能够对金属腐蚀造成的细微区域完整分割,取得了满意的效果,为金属腐蚀区检测提供了参考。     

Reaction of water vapor and oxygen with liquid uranium

The reactions of water vapor and oxygen with liquid uranium were studied by modulated molecular-beam mass spectrometric methods. Equivalent pressures of the reactant fluxes on the surface ranged from 6×10 ^–6 to 2×10^–4 torr. Temperatures up to 1570 K were investigated. The metal surface was kept clean during reaction by mechanical removal of the oxide formed with a tungsten needle. For the clean liquid uranium surface, a water reaction probability of 0.4 was deduced both from measurement of the reaction-product hydrogen signal and by the temperature dependence of the scattered reactant signal. Based solely on the latter measure, a reaction probability of 0.6 was estimated for oxygen. The reaction probabilities on the clean surface were temperatureindependent. They decreased as the coverage of the surface by islands of oxide increased and, for water, appeared to approach a value of 0.08 for a surface completely covered with an oxide estimated to be 500 Å thick. Bombardment of the surface during reaction with argon ions produced an increase in the reactivity on solid uranium but had a negligible effect on the reaction probability for the liquid.