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121.
有机硅乳液稳定性的研究 总被引:1,自引:1,他引:1
以阳离子型乳液聚合为例,详细讨论了聚合反应因素及环境因素对环氧改性有机硅乳液稳定性的影响。结果表明:在聚合反应温度为65℃、催化剂的用量为总加料量的0.3%~0.5%、硅烷偶联剂的用量为D4质量的3%~5%、乳化剂用量为总加料量的10%、阳/非离子型乳化剂的质量比为1.5~1.8、D4与水的质量比为0.3~0.4条件下,制得的环氧改性有机硅乳液稳定性良好;采取急冷的方式中止聚合反应,并以醋酸中和至pH值为6~7,有利于环氧改性有机硅乳液稳定性的提高。 相似文献
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结合大凌河流域初始水权分配实践,从分配范围、分配机制、分配原则、分配模型等方面,对现有研究成果进行全面梳理。在此基础上,结合大凌河流域特点,借鉴我国流域水资源配置评价指标体系,从公平性、效率性、可持续发展、政府宏观调控4个维度,设计了一套水权分配评价指标体系,进而构建了初始水权分配实践效果的耦合评价模型,并应用于大凌河流域。结果表明,在政府和大凌河流域水行政管理部门的宏观调控作用下,通过加强大凌河流域所在区域的政治民主协商,流域内各区域水权分配结果充分体现了与其社会经济发展之间的匹配性,且各区域之间的耦合协同发展效度均达到较高水平。 相似文献
125.
This paper is concerned with the state estimation problem for the complex networked systems with randomly occurring nonlinearities and randomly missing measurements. The nonlinearities are included to describe the phenomena of nonlinear disturbances which exist in the network and may occur in a probabilistic way. Considering the fact that probabilistic data missing may occur in the process of information transmission, we introduce the randomly data missing into the sensor measurements. The aim of this paper is to design a state estimator to estimate the true states of the considered complex network through the available output measurements. By using a Lyapunov functional and some stochastic analysis techniques, sufficient criteria are obtained in the form of linear matrix inequalities under which the estimation error dynamics is globally asymptotically stable in the mean square. Furthermore, the state estimator gain is also obtained. Finally, a numerical example is employed to illustrate the effectiveness of the proposed state estimation conditions. 相似文献
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本文选用废渣制成的粉煤灰纤维棉(FAF)和聚氯乙烯(PVC)树脂作为原料,成功制备了FAF/PVC复合材料,研究了FAF的表面处理及其加入量对复合材料力学性能、热性能和硬度的影响,并用SEM对复合材料的界面进行了表征。实验结果表明,相对于纯PVC树脂而言,复合材料含经KH550处理的FAF40phr时,拉伸强度提高约12%;含经软化剂处理的FAF10phr时,冲击强度提高约110%;含经偶联剂和软化剂联合处理的FAF10phr时,冲击强度提高约70%,拉伸强度提高约11%,维卡软化温度随FAF添加量的增加呈上升趋势。研究结果证明,KH550和软化剂联合使用会对复合材料起到有效的增强增韧效果,因此能提高复合材料中FAF的填充量。制成的环保型FAF/PVC复合材料不仅性能全面高于纯PVC,而且材料成本显著降低,为综合利用废渣FAF开拓了新方向。 相似文献
128.
The chemical equilibrium for the coupling of ethylbenzene dehydrogenation with nitrobenzene hydrogenation, to produce styrene and aniline simultaneously, has been calculated on the basis of the Soave–Redlich–Kwong equation of state. The dehydrogenation of ethylbenzene in the presence of nitrobenzene over the catalysts -Al2O3, ZSM-5, activated carbon and platinum supported on activated carbon has been carried out at 400 °C. The effects of Pt loading and the pretreatment of the catalysts have been investigated. It has been revealed that the conversion of ethylbenzene can be greatly improved by the reaction coupling due to the elimination of the hydrogen produced in the reaction by the hydrogenation of nitrobenzene. Platinum supported on the activated carbon has been suggested as a suitable catalyst. The best results with ethylbenzene conversion of 33.8% and styrene selectivity of 99.2% were obtained over Pt(0.02 wt%)/AC at 400 °C. Moreover, such process is also energetically favored since the necessary process heat to drive the ethylbenzene dehydrogenation can be provided by the coupling with the exothermic nitrobenzene hydrogenation reaction. 相似文献
129.
C. Finol M. Menendez A. Monz n J. Santam Arí a 《Chemical Engineering Communications》1995,135(1):175-184
Methane oxidative coupling has been carried out in a reactor with a distributed oxygen feed. The system consists of a catalytic bed of Li/MgO in a quartz reactor with one inlet for methane and one or more inlets for oxygen. To enable the comparison between the co-fed mode and the distributed feed mode, an especial experimental design was used in order to maintain the same contact time in the co-fed and in the distributed feed modes, and in order to minimize the temperature gradients caused by the exothermic oxidation process. The results clearly show that a distributed oxygen feed may give rise to significant increases in the hydrocarbon selectivity obtained at a given methane conversion, 相似文献
130.
Colloidal silica particles are prepared via a sol gel technique carried out in an inverse microemulsion of water in a toluene solution of tetraethoxysilane (TEOS), stabilized by either an anionic surfactant AOT or isopropanol. Functionalized material was obtained using a functional coupling agent (RO)3Si(CH2)3
X, X being a functional group such as methacryloyl, thiol, vinyl, amino group, or a chlorine atom. Functionalization can be carried out either directly via the direct copolycondensation of TEOS and the coupling agent, or in a two-step process involving a core-shell polycondensation of the coupling agent onto preformed silica particles. Kinetic studies of the copolycondensation are carried out using either29Si NMR analysis or liquid chromatography. They show that the consumption of TEOS is more rapid than that of the coupling agent. The materials are characterized both chemically (elemental analysis, FTIR,13C and29Si NMR CPMAS analysis), and by their particle size. The silica functionalized with a polymerizable methacryloyl group is encapsulated by a polymer layer in an inverse emulsion polymerization of acrylic acid. After inversion of the emulsion in water, the resulting material is covered with a layer of hydrophobic polymer in a conventional emulsion polymerization. 相似文献