不同养护方式对水泥-锂渣浆体水化程度影响

为了分析水泥-锂渣浆体的水化程度, 采用高温煅烧法测试各龄期的化学结合水, 结果发现:水泥-锂渣浆体的化学结合水量随龄期的延长而增加, 水化3 d和7 d时能达到水化90 d时的60%和80%。高温养护、碱激发、高温和碱激发均能提高锂渣复合水泥基材料早期的化学结合水量, 最高可达3~4倍, 提高的幅度依次为碱激发和高温养护＞碱激发＞高温养护＞标准养护。高温和复合环境养护也能提高水泥的水化程度, 1~28 d内, 锂渣掺量在40%以内时, 水泥水化程度相对指数(ψ值)均大于1;掺量为60%时, ψ值均小于1。综上, 高温养护、碱激发、高温和碱激发均能提高锂渣和水泥的水化程度, 高温和碱激发复合作用时较为显著。     

A Solder Alloy Filled Z-Axis Conductive Epoxy Adhesive

Epoxy adhesives filled with four different volume fractions of eutectic tin-bismuth solder alloy were prepared and the effect of filler content on the electrical and mechanical properties of these anisotropic electrically conductive adhesives was investigated. The results show that the adhesive containing the lowest amount of the filler alloy had the best combination of conductivity, insulation resistance and shear strength. The DSC-measurements suggested that the filler melts before the cure of the resin begins which allows the filler to wet and bond well to the conductors. This was verified by SEM/EPMA examinations. A temperature cycling test and high humidity, high temperature treatment were conducted on the best composite adhesive. The temperature variation had no effect on conductivity of the joints while humid and hot environment decreased the conductivity.     

醋酸装置催化剂循环使用周期短的原因及对策

根据乙醛氧化反应催化剂的循环使用机理对湘维醋酸装置催化剂循环使用周期短的原因进行了分析，找出了反应温度偏高、氧醛比偏大、醋酸锰循环使用流程不合理、用工业水溶解醋酸锰等四项原因，并提出了改进措施，实施后使湘维醋酸装置催化剂循环使用周期达到了国内先进水平。     

Kinetic study of the curing behavior of bismaleimide modified with diallylbisphenol A

The curing kinetics of bismaleimide modified with diallylbisphenol A were investigated for different ratios of 1,1′‐(methylene di‐4,1‐phenylene) bismaleimide and diallylbisphenol A with differential scanning calorimetry. Multiheating‐rate and isothermal methods were used to study the kinetics of the curing process. The results indicated that the activation energy changed with the extent of conversion. The activation energy obtained by the multiheating‐rate method was higher than that obtained by the isothermal method. Two kinetic models (autocatalytic and nth‐order) were successfully used to model the curing process. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2229–2240, 2003     

Texaco煤气化装置长周期运行影响因素分析

介绍了Texaco煤气化工艺流程,从原料煤种、水煤浆浓度、操作工艺、关键设备等几个方面讨论了影响装置长周期运行的因素,提出了延长气化装置运行周期的措施。     

UV涂料在户外的应用

本文简述了辐射固化技术的发展历史，回顾了我国辐射固化涂料的发展状况，介绍了户外用UV涂料的特点、制备及国外最新进展。     

Increasing urea-N efficiency for transplanted lowland rice by pneumatic injection: Yield and economics at the farm level

To increase the fertilizer-N efficiency in lowland rice (Oryza sativa L.) cultivation, new management practices are needed. Main cause of the present low efficiency is the low N recovery by plants, as a considerable part of the N applied is lost; deep placement techniques improve the recovery. A pneumatic injector, with which urea prills can be point-placed at a depth of 5–10 cm in paddy soils, was tested in 38 on-farm trials in 1989/90, mostly during the wet season. The experiments, located in Africa and Asia, focussed on differences in grain yield between conventional methods of broadcasting urea and injection by the pneumatic injector, at recommended N-rates. The study shows that the pneumatic injector is effective as a tool to improve the N fertilizer efficiency. The average yield increases per region, resulting from the use of the injector, ranged from about 250 to 1300 kg grain ha^–1. The value of the yield increase would allow most farmers to recover the costs of the injector within one season, even if labour was hired to carry out the injections. The average labour requirement of the injector was 40 hours ha^–1. In Indonesia, injection of prilled urea gave yields similar to those obtained with urea briquettes.     

改性蓖麻油制备UV光固化涂料的研究

研究了改性蓖麻油制备UV光固化涂料。由蓖麻油、环氧丙烯酸树脂UVR6100、光引发剂UVI6990制得的涂料具有优良的光泽、良好的柔韧性、良好的附着力与硬度，且当改性蓖麻油含量为40％时，漆膜性能最为优良。     

榫边扣合管状密闭输送带的制作及其质量优化

对用于制药、精细化工、建材业等输送松散及粉、粒物料不污染环境的榫边扣合管状密闭输送带的结构特点、技术要求、制造工艺和优化制品质量的技术措施及效果进行了实验探讨。     

Curing process of powdered phenol–formaldehyde resol resins and the role of water in the curing systems

The curing behavior of two kinds of commercial powdered resol phenolic resins was studied by differential scanning calorimetry. Liquid‐state ¹³C‐NMR spectroscopy was used to aid in understanding the curing behavior by detecting the structure of powdered resins. The reaction mechanism was interpreted with the dependency of activation energy on the degree of conversion. The results indicate that there are differences in the curing mechanism between core and face phenolic resins. The curing process of core resin was faster than that of face resin at the same reaction temperature. The water added in the curing system played an important role of plasticizer or diluent according to different curing stages and water content. In the initial curing stage, water mainly diluted the system and retarded the curing reactions. However, at the higher degrees of conversion, water played the role of plasticizer to decrease the effect of diffusion on the curing reactions to make the curing reactions more complete. The excess water added in the curing system played the role of diluent at almost all stages during the curing process. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1371–1378, 2003