光催化氧化法降解有机污染物影响因素及其效率提高途径

分析了催化剂类型、污染物性质、反应条件等因素对光催化氧化法降解有机污染物的影响,从催化剂改性、高效光催化氧化反应器及光催化与其他技术联用等方面探讨了提高光催化氧化效率的途径,展望了光催化氧化法发展前景及其工业化应用时需解决的关键问题。     

超声波技术在农药残留研究中的应用

从超声波萃取和超声波降解两方面，综述了近几年国内外超声波技术在农药残留研究中的应用及研究现状。     

Thermogravimetric analysis of methyl methacrylate‐graft‐natural rubber

The thermal degradations of methyl methacrylate‐graft‐natural rubber (MG) at different heating rates (B) in nitrogen were studied by thermogravimetric analysis. The results indicate that the thermal degradation of MG in nitrogen is a one‐step reaction. The degradation temperatures increase along with the increment of heating rates. The temperature of initial degradation (T₀) is 0.448B + 362.4°C, the temperature at maximum degradation rate, that is, the peak temperature on a differential thermogravimetric curve (T_p) is 0.545B + 380.7°C, and the temperature of final degradation (T_f) is 0.476B + 409.4°C. The degradation rate at T_p is not affected by B, and its average value is 48.9%; the degradation rate at T_f is not affected by B either, and its average value is 99.3%. The reaction order (n) is 2.1 and is not affected by B. The reaction activation energy (E) and the frequency factor (A) increase along with B, and the apparent reaction activation energy (E₀) is 254.6 kJ/mol. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2952–2955, 2002     

磺酰脲类除草剂的微生物降解

微生物降解是磺酰脲类除草剂降解的重要途径之一。笔者对磺酰脲类除草剂微生物降解途径及影响微生物降解的因素进行了分析，对磺酰脲类除草剂微生物降解的研究现状做了简要综述，提出了微生物降解领域的发展趋势和有待解决的问题。     

Applications of rheological torque–time curves to the study of thermooxidative degradation of polypropylene powder

The torque–time curves of polypropylene (PP) powder treated under various thermooxidative degradation conditions were obtained through processing in the mixing chamber of a rheometer. Meanwhile, the Fourier transform infrared (FTIR) spectra of the corresponding samples were determined, and the quantitative analysis of the carbonyl indices of the FTIR spectra of the samples of the PP powder was carried out to provide evidence for the rheological characterization. PP granules, to which an antideteriorant was added before they were commercially supplied so good antidegradation could be achieved, was investigated for the sake of contrast. The analysis of the experimental results showed that the height of the torque–time curve of the PP powder and the corresponding value of the equilibrium torque could be used to characterize or evaluate the variations of the thermooxidative degradation of the PP powder. Under the same processing conditions, the heights of the torque–time curves of the PP powder and the corresponding values of the equilibrium torque decreased with the enhancement of the thermooxidative degradation treatment before mixing; on the contrary, the heights and areas of the characteristic bands of the carbonyl groups in the FTIR spectra of the PP powder and the corresponding values of the carbonyl index increased. The quantitative analysis of the FTIR spectra provided evidence for the conclusion that the heights of the torque–time curves of the PP powder and the corresponding values of the equilibrium torque could be used to characterize or evaluate the thermooxidative degradation of the PP powder. If the treatment under thermooxidative degradation conditions weakened or the degradation of the PP powder just began (i.e., in the viscosity range for processability), the evaluation method using the heights of the torque–time curves of the PP powder or the corresponding values of the equilibrium torque could provide more sensitivity than the method using the values of the carbonyl index. Consequently, the method using the heights of the torque–time curves to evaluate the thermooxidative degradation of the PP powder had its advantages. The application of the torque–time curves could be used to evaluate not only the variation of the thermooxidative degradation of the PP powder treated under aging conditions before mixing but also the variation of the degradation, including the mechanochemical degradation, of the PP powder during the period of mixing. The dependence of the variation of the degradation of the polymer on the processing time during mixing could be evaluated by the study of the variation of the torque–time curves. It can be concluded that the application of torque–time curves to the evaluation of degradation of PP powder has the advantages of being convenient, real‐time, in situ, online, and production‐oriented. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

考虑多因素作用下的RC梁抗力时空退化模型

为研究钢筋混凝土结构锈蚀后的力学性能和抗力退化规律,基于RC梁加速锈蚀试验结果,首先综合考虑均匀锈蚀和点蚀同时发生的影响,对钢筋截面面积的时变模型进行分析,其次探讨裂缝宽度与氯离子扩散系数及RC梁抗力的关系,随后考虑受拉主筋锈蚀不均衡的影响,对结构抗力计算模型进行讨论,最后基于材料性能和结构尺寸的空间变异性,建立RC梁抗力时空退化模型,并对桥梁服役100 a后的抗力进行预测.研究发现:当考虑各参数的空间变异性时,不考虑裂缝影响得到的抗力值比考虑裂缝影响得到的抗力值高了9.91%;考虑各参数空间变异性时的抗力值比不考虑时下降了14.68%;适当的选取波动系数和单元尺寸对考虑结构各参数的空间变异性十分重要;潮汐区和浪溅区环境下结构的剩余抗力分别为初始抗力的43.23%和36.45%,较海岸线大气区环境下的抗力值分别下降了6.73%和21.35%,因此在结构服役期间,应尽量做好防腐措施,减少氯离子侵蚀对结构耐久性的破坏.     

Anticipating Degradation in State Estimation Accuracy via Online Nonlinear Observability Analysis

A methodology is proposed to enable real-time evaluation of the observability of local motions, and generate a local observability cost map to enable informed local motion planning in order to avoid potential degradation or degeneracy in state estimator performance. The proposed approach leverages efficient numerical techniques in nonlinear observability analysis and motion primitive-based planning technique to realize the local observability prediction with real-time performance. The degradation of the state estimation performance can be readily predicted with the local observability evaluation result. The proposed approach is specialized to a representative optimization-based monocular visual-inertial state estimation formulation and evaluated through simulation and experiments. The experimental results demonstrated the ability of the proposed methodology to correctly anticipate the potential state estimation degradation.     

地聚物砂浆高温后抗拉和粘结性能及退化机理

为考察地聚物砂浆在有耐高温要求的混凝土结构加固领域的应用可行性,开展了常温下和高温后地聚物砂浆的抗拉强度试验以及地聚物砂浆与普通水泥砂浆及普通混凝土基体的粘结性能试验,并与普通水泥砂浆的抗拉及粘结性能进行试验比较;通过热重分析-差示扫描量热分析(TG-DSC),探究了地聚物砂浆的高温强度退化机理.试验结果表明:地聚物砂浆与水泥砂浆及混凝土之间的常温粘结强度分别达2.15 MPa及1.7 MPa,经300℃高温后残余粘结强度仍有1.5 MPa左右,远高于普通水泥砂浆的粘结强度;超过300℃以后地聚物砂浆的强度急剧退化,这主要是因地聚物砂浆高温脱水、微观结构遭受破坏引起.基于上述试验结果,可将地聚物砂浆用于300℃以下高温环境的混凝土结构修补加固.     

Simulation of Fatigue Stiffness Degradation in Prestressed Concrete Beams under Cyclic Loading

In order to investigate and research the fatigue cracking of prestressed concrete fatigue properties and loading and stiffness degeneration process,cyclic loading tests were carried out on six prestressed concrete beams and the stiffness degradation under fatigue was investigated. A simulation model of stiffness degradation is proposed based on the stiffness analysis of the fatigue-damaged section. The elastic modulus of damaged concrete and the effective residual area of steel were introduced as well as an adjusted three-stage concrete fatigue damage evolution model. The strip method was used to analyze concrete damage due to changing stress along the depth of the beam section. The simulation and test results were compared and a method of predicting fatigue deflection was presented based on the simulation model. The predicted results were compared with that of the neural network method. It is in good agreement for the simulation results with the test results. It is only less than 5% error for the simulation model which can reveal the two-stage degradation of prestressed concrete beams under cyclic loading. It is more precise for the simulation prediction method under proper conditions.     

二乙基羟胺-臭氧体系降解邻苯二甲酸二甲酯的机理学研究

本研究采用二乙基羟胺（DEHA）促进臭氧（O3）降解水中邻苯二甲酸二甲酯（DMP）,并建立了强化O3氧化能力的O3/DEHA体系。主要探索了在O3/DEHA体系中pH、DEHA投量、臭氧通量和DMP投量对该体系的影响及体系的氧化机理,并通过气相色谱/质谱（GC/MS）对DMP的降解产物进行了分析。结果表明：DEHA能够有效促进臭氧的分解且在酸性条件下（pH=3）明显提高DMP的降解率,DEHA投量为25μΜ时促进效果最佳;DMP降解速率随臭氧通量的增加而增加,随DMP浓度的增加而减小,通过动力学计算,该反应符合拟一级动力学反应;投加叔丁醇（TBA）能够明显抑制DMP的降解,验证了在酸性条件下,·OH对DMP的降解起主要作用;通过产物分析可推导出O3/DEHA体系中DMP 的降解途径主要从苯环上碳链的断裂开始,中间生成酸类和脂类化合物,最终矿化为水和二氧化碳。