Hollow Pd/MOF Nanosphere with Double Shells as Multifunctional Catalyst for Hydrogenation Reaction

A new type of hollow nanostructure featured double metal‐organic frameworks shells with metal nanoparticles (MNPs) is designed and fabricated by the methods of ship in a bottle and bottle around the ship. The nanostructure material, hereinafter denoted as Void@HKUST‐1/Pd@ZIF‐8, is confirmed by the analyses of photograph, transmission electron microscopy, scanning electron microscopy, powder X‐ray diffraction, inductively coupled plasma, and N₂ sorption. It possesses various multifunctionally structural characteristics such as hollow cavity which can improve mass transfer, the adjacent of the inner HKUST‐1 shell to the void which enables the matrix of the shell to host and well disperse MNPs, and an outer ZIF‐8 shell which acts as protective layer against the leaching of MNPs and a sieve to guarantee molecular‐size selectivity. This makes the material eligible candidates for the heterogeneous catalyst. As a proof of concept, the liquid‐phase hydrogenation of olefins with different molecular sizes as a model reaction is employed. It demonstrates the efficient catalytic activity and size‐selectivity of Void@HKUST‐1/Pd@ZIF‐8.     

The rim zone of cement-based materials – Barrier or fast lane for chemical degradation?

Sophisticated evaluation models for the long-term stability of cement-based systems demand a precise knowledge of the mechanisms of deterioration reactions, particularly respecting a permanent exposure to aqueous environments. Commonly, insights into these mechanisms are deduced from long-term investigations. However, these chemical reactions start immediately after exposure to aggressive environments causing rapid changes of composition and structure. Consequently, properties of its rim zone change, which affects transport processes in aqueous solutions. In laboratory experiments, the influence of these surface processes on the stability of cement-based materials exposed to different chloride solutions was studied as a function of time and temperature. Analysis of compositional and structural changes beneath the surface reveal the role of crystalline covering layers for chemical resistance. Such layers are often described as protective barriers. However, these processes in the rim zone can accelerate chemical degradation and subsequently reduce the resilience of the cement-based materials to aggressive aqueous environments.     

三维实体数据文件的建立

建立几何体数据文件是计算机图形显示的首要任务,本文介绍了简单几何体和不规则体的数据建立过程,并在微机上用Ｃ语言实现了这些算法．     

工业软测量模型结构与输入变量选择的研究

针对过程工业中难以直接测量的变量建立其软测量模型,对于实现关键指标的在线监测和实时控制具有十分重要的意义.变量的选择直接关系到神经网络软测量模型的预测性能,针对现有输入变量和网络结构选择方法在工业应用中的不足,提出了一种基于敏感度分析的方法来确定网络输入变量集和前馈神经网络隐含层节点个数,并建立了高密度聚乙烯(HDPE...     

Comparison of the RF MEMS switches with dielectric layers on the bridge’s lower surface and on the transmission line

Previously, we proposed that the dielectric layer of RF MEMS switch can be fabricated either on the transmission line, as traditional switches, or on the lower surface of the bridge. This paper presents a detailed comparison of the RF MEMS switches with different positions of dielectric layer. Through theoretically analyzing the physical model of fringing capacitance, it is revealed that different positions of dielectric layer can result in different switch capacitances. Therefore, the change of d...     

双闭环直流调速系统的工程设计与仿真

介绍直流调速系统的工程设计方法,利用MATLAB软件,对直流调速系统进行数学建模和系统仿真的研究。     

基于小波能双重自恢复的音频数字水印算法

本文设计了一种在音频信息中加入双重图像作为数字水印,这些水印经过多种攻击能相互自恢复的算法。此算法实现了将双重图像作为数字水印嵌入到WAV音频载体中的过程,在实现过程中通过对载体进行3层小波分解,将数字水印的信息嵌入到第三层小波解的低频区,即CA3中,并对双重数字水印分别设置密钥,建立起两者间稳定的映射关系,能较好地以完成自恢复的功能。     

Embedding HMMs-based models in a Euclidean space: the topological hidden Markov models

Current extensions of hidden Markov models such as structural, hierarchical, coupled, and others have the power to classify complex and highly organized patterns. However, one of their major limitations is the inability to cope with topology: When applied to a visible observation (VO) sequence, the traditional HMM-based techniques have difficulty predicting the n-dimensional shape formed by the symbols of the VO sequence. To fulfill this need, we propose a novel paradigm named “topological hidden Markov models” (THMMs) that classifies VO sequences by embedding the nodes of an HMM state transition graph in a Euclidean space. This is achieved by modeling the noise embedded in the shape generated by the VO sequence. We cover the first and second level topological HMMs. We describe five basic problems that are assigned to a second level topological hidden Markov model: (1) sequence probability evaluation, (2) statistical decoding, (3) structural decoding, (4) topological decoding, and (5) learning. To show the significance of this research, we have applied the concept of THMMs to: (i) predict the ASCII class assigned to a handwritten numeral, and (ii) map protein primary structures to their 3D folds. The results show that the second level THMMs outperform the SHMMs and the multi-class SVM classifiers significantly.     

PS对剪贴图层创建图层样式的方法

该文介绍了设计Logo时对剪贴图层创建图层样式的方法。     

集散控制系统网络结构的研究

为了提高集散控制系统通信的可靠性、稳定性、抗干扰性和可扩展性,降低集散控制系统通信的故障率,提出了一种基于工业以太网的网络通信方式,并验证了该通信网络的可行性。该网络是一种采用分布式、冗余式、立体式的多层次网络结构。此结构使网络的负荷均匀分配,降低了网络的故障率,并使集散控制系统的网络向开放化、信息化的方向发展。