双包络TI-环面蜗杆传动的二次包络分析

在一次包络分析的基础上,着重进行了二次包络齿面接触分析,推导出了蜗杆和蜗轮齿面方程。齿面接触分析表明：齿面呈双线接触,润滑条件好,承载能力大,在重型机械传动装置中具有实用价值。     

大豆中异黄酮类化学成分的研究

用w(C2H5OH)=70%的工业乙醇从脱脂大豆饼中提取大豆异黄酮,并依次用乙酸乙酯、正丁醇萃取,乙酸乙酯萃取部分经硅胶柱和SephadexLH-20柱层析,用V(CHCl3)∶V(CH3OH)=(12～4)∶1梯度洗脱。分离得到4种化合物,通过理化常数和光谱分析鉴定其化学结构,分别为大豆甙元(daidzein)、染料木素(genistein)、大豆甙(daidzin)、染料木甙(genistin)。     

用人工神经网络方法预测鼓泡塔气含率

A new correlation for the prediction of gas hod up in bubble columns was proposed based on an extensive experimental database set up from the literature published over last 30 years .The updated estimation method relying on artificial neural network,dimensional analysis and phenomenological approaches was used and the model prediction agreed with the experimental data with average relative error less than 10%.     

Partial Oxidation of Methane to Syngas over Calcined Ni–Mg/Al Layered Double Hydroxides

The catalytic partial oxidation of CH₄ to syngas was carried out over an Ni–Mg/Al mixed-oxide catalyst prepared from layered double hydroxide-type precursors. The catalysts were characterized by XRD, TPR, UV-DRS, XRF, BET and CHNS analysis. The effects of the catalyst composition and the calcination temperature on the catalytic performance and the extent of catalyst deactivation were investigated. Ni–Mg/Al oxide catalysts converted CH₄ into syngas efficiently with high selectivity. The catalyst performance was strongly related to the Ni particle size and the calcination temperature. The catalysts that were calcined at higher temperature exhibited a better catalytic performance. In conclusion, the NiAl₂O₄ spinel phase had a positive effect on the stability of the catalyst.     

多元复杂精馏过程模拟和优化

采用非平衡级METSH方程组，对丙烯精馏过程进行了模拟计算和优化，提出了一种全新的、实用的塔板组成的圆整归一方法，摸索出了一套行之有效的计算程式，大大提高了模型方程组迭代计算的收敛性，求解更加稳定。本文还以精馏塔利润为目标，建立了优化目标函数，进行了优化计算，计算结果对丙烯塔生产具有一定意义。     

DEDS-10双子表面活性剂的性能研究

合成了一种新型的DEDS-10双子表面活性剂,用红外光谱对所合成化合物的结构进行了初步表征。DEDS-10的临界胶束浓度cm c为0.47 mmol/L,γcm c为34.5 mN/m,A lC l3、CaC l2和NaC l可以使γcm c降低3.6~1.1 mN/m,其cm c值大约为纯水溶液cm c值的1/5~1/3;加入乙醇,可增加其表面活性,在乙醇的浓度为0.22 mol/L时,其表面张力为30 mN/m左右。与阳离子表面活性剂DTAB和非离子表面活性剂曲拉通X-100复配,可以大幅度地降低cm c和γcm c值,与阴离子表面活性剂TLS复配时,cm c降低,cγm c略有增加。     

纳米层状双金属氢氧化物的制备及结构表征

采用恒定pH 12±0.2,按n(Mg2+)∶n(Al3+)∶n(OH-)∶n(CO2-3)=6∶2∶16∶1配制溶液,采用一步反应液相法,制备纳米层状双金属氢氧化物(LDH)粉体.为了获得无团聚、分散均匀的纳米粉体,探讨了溶剂置换干燥、真空干燥、常压干燥对纳米LDH粉体形成团聚的影响;用X射线衍射仪、透射电镜、红外光谱仪和元素分析仪对样品的物相、形貌、粒径和组成进行了表征.结果表明,溶剂置换干燥能够有效防止纳米粉体形成硬团聚,样品分散性好,呈针状形态,长50 nm,宽5 nm.     

Current problems in the modelling of chemical reactors

Modelling of chemical reactors is reviewed with an emphasis on process development and scale-up. A distinction is made between modelling of chemical kinetics, of rate processes in volume elements and of whole reactors. Examples are mainly taken from papers presented at the Sixth International Symposium on Chemical Reaction Engineering. Special attention is given to the modelling of single phase reactors, fixed beds, trickle beds, fluid beds, and gas bubble reactors.     

Monodisperse‐porous poly(styrene‐co‐divinylbenzene) beads providing high column efficiency in reversed phase HPLC

A multistage polymerization protocol, the so‐called “modified seeded polymerization,” was developed for the production of monodisperse‐porous poly(styrene‐co‐divinylbenzene) providing high column efficiency as a packing material in reversed phase high performance liquid chromatography (RPLC). In the first stage of the multistage production, uniform polystyrene seed particles, produced by dispersion polymerization, were swollen by an organic agent (i.e., the diluent) and then by a monomer mixture containing styrene and divinylbenzene. The final porous particles were obtained in the monodisperse form by the polymerization of monomer mixture in the seed particles. By the use of a small size seed latex with low molecular weight and by the selection of the appropriate diluent, relatively small monodisperse‐porous particles with suitable pore structure could be achieved. In the reversed phase separation of alkylbenzenes, under isocratic conditions, theoretical plate numbers up to 40,000 plates/m were achieved by using 5.2 μm porous particles, obtained by a toluene‐dibutyl phthalate mixture as the diluent. No significant decrease in the resolution power was observed by the fourfold increase in the mobile phase flow rate. The column efficiency and the resolution observed with 5.2 μm monodisperse‐porous particles were significantly higher with respect to the currently available polymer based packing materials used in the reversed phase HPLC. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1430–1438, 2005     

凉水塔技术研究与探讨

通过对我厂引进的大型进口设备———Marley—600型冷却塔进行技术改造情况的介绍,具体分析了进口材料与国产材料的本质区别,并具体介绍了我厂的使用情况。此次技术改造在大化肥行业是首次进行,并取得了成功。论证了进口设备走国产化道路的必然性及可行性,从而为我国的其他大型Marley—600型冷却塔设备走国产化道路作了较好的铺垫。