单釜合成四羰基钴盐和苯丙酮酸盐

在１００Ｌ的反应釜中，加入醇－水石灰乳、硫代硫酸钠、氯化钴和通入ＣＯ气体制备四羰基钴盐，接着在同一反应器中催化氯苄的双羰基化反应，合成苯丙酮酸盐。省去制备催化剂的高压反应釜及其复杂的贮运设备     

酯化釜塔顶温度控制系统改造

介绍了串级控制在仪化研究院半连续聚酯试验装置酯化釜塔顶温度控制上的应用,解决了酯化釜塔顶温度调节滞后问题,提高了调节过程的品质     

某砖混结构加层改造的设计

通过对某砖混结构加层改造的设计实践,介绍了加层改造的方法,分析了在加层改造过程中需解决的问题。主要包括地基及基础的处理,墙体抗压、抗震验算,节点连接处理,如何保证新结构与原结构连接的整体性,楼梯间处理,构造柱的连接等,并提出了结构加层对施工技术的要求。给出一些具体的构造大样,供工程设计参考。     

充填浮选柱捕集区气含率的试验研究

通过冷模试验方法考察了充填浮选柱捕集区的气含率，经试验数据回归分析，气含率εｇ＝０．０９６Ｊｇ０．９１（Ｈｃ／Ｄ）－０．１８。并结合漂移通量的理论，确定充填浮选柱的捕集区为近似均匀鼓泡流。     

电化学界面处离子分布、静电势和ξ势的研究

Density functional theory is applied to predicting the structures and electrostatic potentials of planar electrochemical surfaces within the framework of the restricted primitive model where small ions are represented by charged hard spheres of equal diameter and the solvent is assumed to be a continuous dielectric medium. The hard-sphere contribution to the excess Helmholtz energy functional is evaluated using the modified fundamentalmeasure theory and the electrostatic contribution is obtained from the quadratic functional Taylor expansion using the second-order direct correlation function from the mean-spherical approximation. Numerical results for the ionic density profiles and the mean electrostatic potentials near a planar surface of various charge densities are in excellent agreement with molecular simulations. In contrast to the modified Gouy-Chapman theory, the present density functional theory correctly predicts the second layer formation and charge inversion of charged surfaces as observed in simulations and in experiments. The theory has also been tested with the zeta potentials of positively charged polystyrene particles in aqueous solutions of KBr. Good agreement is achieved between the calculated and experimental results.     

基于FPGA的高速数据存储系统优化设计

针对遥测系统数据记录装置中数据传输速率与存储速率不匹配的问题,提出Flash的并行存储方案,采用交替双平面的编程方式可以使得存储器的存储速率达到单片Flash最高存储速率的2倍,即60 MB/s;对控制单元FPGA内部双端口RAM的逻辑设计进行改进,解决了数据存储异常的现象。在数据回收方面,提出了多备份的设计思想和备用读数接口的设计方案,已在工程应用中得到成功实践,验证了该数据记录装置的可靠性。     

常压脱高硫浅议

就用常压塔脱高硫从流程设置、设备选择、工艺条件控制以及硫回收几方面进行讨论,并着重阐述了脱硫塔、再生槽的设计要求以及吸收、再生、熔硫的工艺条件。     

热态下鼓泡浆液反应器的气含率研究

本文在热态条件下，研究了鼓泡浆液反应器的气含率、反应器直径为0.098m，物系组成为氮气－液体石腊－石英砂。考察了气速、压力、温度、静床高及固体引入等因素对气含率的影响。对于53μm粒子的三相浆态体系，气含率与表观气速关系式为εG=0.053uG^1.2。     

Nanocomposites based on polyethylene and Mg-Al layered double hydroxide. I. Synthesis and characterization

Low density polyethylene (LDPE)/Mg-Al layered double hydroxide (LDH) nanocomposites have been synthesized with different compositions by melt-mixing technique using maleic anhydride grafted polyethylene as compatibilizer. LDH has been modified by sodium dodecylbenzene sulfonate using reconstruction method and characterized by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. The nanocomposites are characterized by different techniques such as, transmission electron microscopy (TEM), XRD and rheology. The TEM analysis shows a complex nature of particle dispersion in the polymer matrix with wide distribution of particles sizes and shapes. The rheological analysis showed significant changes in linear viscoelastic responses of the composites, even at very low concentration (2 phr) of LDH materials, in comparison to the pure polymer in low frequency regime in dynamic frequency sweep experiments. These changes are related to the LDHs-polymer chains interactions resulting in network-like structure.     

针铁矿法沉铁过程亚铁离子浓度预测

针对针铁矿法沉铁过程出口亚铁离子浓度离线化验获得,存在很大滞后性,难以实现沉铁过程实时控制的问题,研究反应器出口亚铁离子浓度在线预测方法.本文在分析沉铁过程化学反应机理的基础上,考虑铜离子对反应过程的影响,结合连续搅拌反应器（Continuous stirred tank reactor,CSTR）特性,建立了针铁矿法沉铁过程的机理模型,并提出了基于信息交换的双粒子群搜索算法（Double particle swarm optimization,DPSO）优化选择机理模型的参数,构建基于最小二乘支持向量机（Least squares support vector machine,LS-SVM）的机理模型输出误差的补偿模型,采用并联补集成方式建立了亚铁离子浓度的集成预测模型.工业现场数据验证了所建模型能有效地反映亚铁离子浓度的变化趋势,为针铁矿法沉铁过程的优化控制奠定了基础.