变化环境下韩江生态流量演变特征分析

选取位于粤东、闽西南地区的韩江流域为研究对象,基于CA-Markov模型对2050年流域土地利用空间格局进行预测,构建SWAT分布式水文模型,以未来土地利用情景和气候变化情景为变量进行水文模拟,分析不同情景下韩江生态流量的时空演变特征。结果表明,未来城镇化扩张将使梅江支流中上游成为韩江流域内生态流量对土地利用变化最为敏感的区域;土地利用和气候变化将导致韩江流域枯水期流量整体减小,枯水期流量对环境变化更加敏感;韩江流域生态流量变化特征将呈现从西南到东北由升到降的趋势,梅江支流中上游地区的生态流量将得到改善;梅江和汀江两大支流上游区域生态流量对气候变化更为敏感;韩江流域径流总量下降,但丰枯流量分化加剧,长期来看枯季生态流量保障风险可能进一步增大。     

阿姆河流域耕地变化及水土匹配特征分析

基于中亚阿姆河流域4个分区1990—2015年间土地利用变化和水资源等数据,运用耕地变化速率、洛伦兹曲线和基尼系数法以及水土资源匹配系数对阿姆河流域耕地变化和水土匹配状况进行了综合分析。结果表明:1990—2015年阿姆河流域耕地以146.74 km²/a的速度在扩张,且各时期、各分区扩张的速度不同;在不考虑咸海来水不断减少、生态持续恶化的前提下,绿洲区匹配状况属比较公平和相对合理状况;阿姆河流域水土资源空间分布存在明显的错位现象;全流域生态用水被农业用水严重挤占,阿姆河流域灌溉面积、灌溉用水量成为影响咸海水量及面积变化的重要因素,是一种不可持续的用水方式。     

基于时序特征的黄河三角洲土地覆盖动态及驱动力分析

综合不同土地利用类型的Landsat影像时序特征和面向对象分割方法,分析1985-2018年现代黄河三角洲土地覆盖时空特征,探讨土地覆盖变化的驱动机制。结果表明:1985-2018年间研究区天然湿地面积大幅减少,共减少9.9847×104 hm²,其中沼泽和草甸湿地面积减少尤为明显,而人工湿地面积则逐年增加,年平均增加率达54.66%,主要是盐田养殖场和水稻种植面积的增大;社会经济因素对研究区土地覆盖的影响程度高于水文因素;输沙量是影响研究区土地覆盖变化的主要水文因素,实测径流量的减少进一步导致天然湿地向旱地类型转化;人口和GDP变化对人工湿地面积增加的正相关作用比较显著,而天然湿地面积的减少则与该两个指标的负相关关系比较明显。     

Land‐use dynamic discovery based on heterogeneous mobility sources

Nowadays, cities are the most relevant type of human settlement and their population has been endlessly growing for decades. At the same time, we are witnessing an explosion of digital data that capture many different aspects and details of city life. This allows detecting human mobility patterns in urban areas with more detail than ever before. In this context, based on the fusion of mobility data from different and heterogeneous sources, such as public transport, transport‐network connectivity and Online Social Networks, this study puts forward a novel approach to uncover the actual land use of a city. Unlike previous solutions, our work avoids a time‐invariant approach and it considers the temporal factor based on the assumption that urban areas are not used by citizens all the time in the same manner. We have tested our solution in two different cities showing high accuracy rates.     

中国耕地细碎化的理论解析与研究框架

基于演绎推理法和文献研究法,探索耕地细碎化的概念、过程、机制和效应,并构建耕地细碎化研究框架,为耕地细碎化研究提供理论指导。结果表明:①耕地细碎化是耕地在自然-人为双重因素驱动下,耕地地块在形态上不断分割、变小,耕地产权在主体上不断细分、多元的过程,并分别表现为相互关联又有所区别的耕地景观细碎化和耕地权属细碎化; ②耕地细碎化研究应遵循“诊断-机制-效应-治理”的理论框架,耕地细碎化诊断需从形态和权属两方面构建评价指标体系,形成机制可从自然切割力、利用切割力、设施切割力和管理切割力4个方面揭示不同因素的作用机制,效应需揭示不同尺度下耕地细碎化形态和产权的趋势性转折对经济、社会和生态的影响,治理研究应按照“问题识别治理潜力治理路径保障措施”的逻辑顺序构建。     

Stable NiO–CeO2 nanoparticles with improved carbon resistance for methane dry reforming

High surface area mixed oxide 8.7% NiO-CeO₂ nanoparticles (122 m²/g; 6–7 nm) were prepared using a reversed microemulsion method, and were tested for dry methane reforming (DRM). The catalytic activity of these nanoparticles remains stable under the severe conditions of DRM (700 °C), and they show better carbon resistance than conventional NiO-CeO₂ catalysts prepared without control of the size. The activity and selectivity of nanoparticles and reference catalyst are similar, but nanoparticles reduce the accumulation of carbon by 63% during the DRM tests, which is a key feature for this reaction. XPS and H₂-TPR suggest that the improved carbon resistance of the nanoparticles is due to the better interaction and cooperation between NiO and CeO₂ mixed phases. In nanoparticles, the participation of cerium cations in the redox processes taking place during DRM stabilizes cationic species of nickel. On the contrary, the catalyst prepared without control of the size suffers segregation of Ni during DRM reaction, and segregated Ni explains the higher catalytic formation of carbon.     

马氏体不锈钢不同剩余磁场条件下短时干摩擦的摩擦损伤行为研究

本文研究了马氏体不锈钢磨削加工产生的剩余磁场对其短时干摩擦过程中摩擦系数的影响.结果表明:剩余磁场对摩擦行为的影响与外加载荷有关,当外加载荷较低时,摩擦系数随剩余磁场强度的升高无明显变化;随外加载荷的升高,剩余磁场强度对摩擦系数的影响作用增大;当外加载荷较高时,摩擦系数随剩余磁场强度的升高而增大;在短时摩擦过程中,随着剩余磁场强度的升高,摩擦界面吸附磨损颗粒的能力增强,加速了摩擦界面的磨粒磨损,使摩擦系数升高.     

液压-齿轮-齿条圆弧分型抽芯压铸模设计

给出了龙头体液压-齿轮-齿条圆弧分型抽芯压铸模实用结构，论述了模具的浇铸系统、结构特点和工作原理。该模具采用扇形龄轮-齿条机构实现龙头体铸件的侧向圆弧分型抽芯，同时通过相应的两套斜销滑块机构分别实现龙头体铸件另外两个方向的侧向分型抽芯。     

激光熔覆TiC增强FeAl金属间化合物基复合材料涂层磨损性研究

利用激光熔覆技术在1Cr18Ni9Ti奥氏体不锈钢表面制得了以TiC为增强相、以FeAl 金属间化合物为基体的耐磨复合材料涂层，研究了激光熔覆。FiC／FeAl复合材料涂层在干滑动磨损条件下的耐磨性能及磨损机制。结果表明：随着载荷和滑动速率的增加，TiC／FeAl金属间化合物基复合材料涂层的磨损速率增加，其磨损机制随着载荷的增加逐渐由磨料磨损向粘着磨损转变；激光熔覆层中TiC体积分数的增加，一方面提高了涂层的磨料磨损抗力，另一方面降低了熔覆层表面与对磨材料之间的粘着倾向，提高了TiC／FeAl涂层的滑动磨损性能。激光熔覆TiC/FeAl金属间化合物基复合材料涂层具有优异的耐磨性能并随TiC体积分数的增加而提高。     

A novel technique for the preparation of secondary fatty amides

A technique for the synthesis of monosubstituted fatty amides at low temperature and ambient pressure was developed. This method involved the condensation of an amine with a triacylglycerol. The primary amine (ethyl,n-butyl,n-hexyl andn-octyl were tested) acted as reagent and solvent for the fatty substrates. No additional organic solvent or catalyst was added. Tallow, vegetable oils and fish oil all served well as substrates, as did pure tripalmitin. The rate of amidation was dependent upon temperature and the ratio of fat to amine. In a series of experiments conducted with tallow andn-butylamine at a fat:amine molar ratio of 1:16, amidation could be carried out at 20°C, producingn-butyltallowamide in 83% yield in 24 hr. When the fat:amine molar ratio was reduced to 1:8, and the temperature raised to 45°C, the amide yield was 87.6% in 24 hr. When the reaction was carried out at the boiling point ofn-butylamine (78°C) and at a fat:amine ratio of 1:8, the amide yield was 93.2% in 4 hr. The reaction progressed more rapidly with higher molecular weight amines. The identity and purity of the amides was assessed by thin-layer chromatography and confirmed by elemental analyses and infrared and C¹³ nuclear magnetic resonance spectroscopy.