Two Isomers of C60F48: Computed Inter-isomeric Equilibrium

C₆₀F₄₈ has been known to exist in two isomeric forms of D₃ and S₆ symmetries. However, the quantum-chemical calculations have not agreed on their stability order though a near-isoenergetic picture is otherwise always encountered. In order to clarify the situation, the entropy effects are evaluated for synthetic temperatures of about 500K. The entropy evaluations suggest that the D₃ isomer should be more stable in the potential energy by 2.05-2.55 kcal/mol (to which term the ab initio data are closer than the semiempirical ones).     

三维地质模型在濮城油田的应用

以濮城油田东区沙二下油藏为研究对象，在储层流动单元细分、微构造、沉积微相、测井曲线二次处理、储层非均质研究、储层动态解释等研究基础上，以数据库为支撑，应用三维可视化技术，建立了研究区油藏三维可视化地质模型。其成果应用于油藏的调整井位设计，并且实现了油藏精细描述—油藏精细数值模拟一体化，效果良好。     

Palogue油田复合油藏动态响应及特征描述

以简单的复合油藏模型理论和方法为基础,以Palogue油田的实际测试井为例,介绍了复合油藏模型的试井动态识别与模型拟合,及与地质静态资料相结合的油藏综合描述过程.该描述方法将会对实际试井解释和油藏综合描述工作有所借鉴和帮助.     

动态陶瓷微滤膜净化沐浴污水实用研究

利用自制的动态陶瓷微滤膜对沐浴污水进行了处理,根据处理水质指标及膜操作参数的比较,发现在0.15MPa以下时,膜通量随压力的升高明显增加,大于0.15MPa时,压力对膜通量的影响不明显。合适的操作压力是0.1～0.15MPa,稳定通量为90～110L/m2·h。不同压力出水CODCr去除率达87%～98%、浊度从120°降到3°以下,处理后颜色为无色。并根据实验结果进行了工程化工艺初步设计和经济分析。     

Extending the color gamut and dynamic range of an sRGB image using a residual image

Image sources, such as digital camera captures and photographic negatives, typically have more information than can be reproduced on a photographic print or a video display. The information that is lost during the tone/color rendering process relates to both the extended dynamic range and color gamut of the original scene. In conventional photographic systems, most of this additional information is archived on the photographic negative and can be accessed by adjusting the way the negative is printed. However, most digital imaging systems have traditionally archived only a rendered video RGB image. As a result, it is not possible to make the same sorts of image manipulations that historically have been possible with conventional photographic systems. This suggests that there would be an advantage to storing images using an extended dynamic range/color gamut color encoding. However, because of file compatibility issues, digital imaging systems that store images using color encoding other than a standard video RGB representation (e.g., sRGB) would be significantly disadvantaged in the marketplace. In this article, we describe a solution that has been developed to maintain compatibility with existing file formats and software applications, while simultaneously retaining the extended dynamic range and color gamut information associated with the original scenes. With this approach, the input raw digital camera image or film scan is first transformed to the scene‐referred ERIMM RGB color encoding. Next, a rendered sRGB image is formed in the usual way and stored in a conventional image file (e.g., a standard JPEG file). A residual image representing the difference between the original extended dynamic range image and the final rendered image is formed and stored in the image file using proprietary metadata tags. This provides a mechanism for archiving the extended dynamic range/color gamut information, which is normally discarded during the rendering process, without sacrificing interoperability. Appropriately enabled applications can decode the residual image metadata and use it to reconstruct the ERIMM RGB image, whereas applications that are not aware of the metadata will ignore it and only have access to the sRGB image. The residual image is formed such that it will have negligible pixel values for those portions of the image that lie within the sRGB gamut, and will therefore be highly compressible. Tests on a population of 950 real customer images have demonstrated that the extended dynamic range scene information can be stored with an average file size overhead of about 8% compared to the sRGB images alone. © 2003 Wiley Periodicals, Inc. Col Res Appl, 28, 251–266, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.10160     

An inverse solution methodology for estimating the diffusion coefficient of gases in Athabasca bitumen from pressure-decay data

An inverse solution methodology is developed for the estimation of diffusion coefficient of gases in highly viscous, oil-sands bitumens from isothermal, pressure-decay measurements. The approach involves modeling the rate of change in pressure using the diffusion equation for the liquid phase coupled with a mass balance equation for the gas phase. The inverse solution framework is utilized to arrive at two graphical techniques for estimating the diffusion coefficient. Both techniques involve the determination of the slope of a straight line resulting from plotting the experimental data in accordance with the developed model. An advantage of the proposed techniques is that the diffusion coefficient is estimated directly, i.e. without making it an adjustable parameter. The novelty of the proposed method is in its simplicity as well as its ability to isolate portions of the pressure-decay data affected by experimental fluctuations. The effect of the initial pressure on the predicted diffusion coefficient and pressure-decay profile was also investigated. The diffusion coefficients of CO₂, CH₄, C₂H₆ and N₂ in Athabasca bitumen at 50–90 °C and about 8 MPa were estimated and compared with literature values.     

正压冲固基础海洋平台冰激振动动力响应

正压冲固基础海洋平台是一种新型平台桩基结构形式。采用三维有限元的数值分析方法,建立了正压冲固平台的三维有限元模型。基于冰激强迫振动理论提出动冰载荷的计算方法,根据海冰破碎长度和冰速确定冰载周期,冰强度限制的水平冰力作为冰力峰值,得到的动冰载荷用于正压冲固平台的动力响应分析,并依照规范计算了6倍桩径处刚性固定时的动力响应。三维有限元方法计算得到的动力响应大于6倍桩径刚性固定时的计算结果,结构安全性评估偏于安全。     

结构-波浪-海床耦合系统中大圆筒结构的波压力响应

以沉入式大圆筒结构为对象，通过设计随机波浪水槽实验，测取了在单筒和连续筒两种结构型式、两种沉入深度和两种波谱输入下结构表面的动波压力分布。波面高度以及波压力历程均在领域进行分析。通过计算结构表面沿高程和沿环向的波压力谱及波压力传递函数，将单筒实测结果与基于线性绕射理论的解析解进行了比较，同时也详细对比了两种结构型式下的实测结果。文中汇报了在研究中获得的新发现及进行的相应分析，特别是在结构——波浪——海床动力相互作用下对波压力响应机理以及针对连续筒的研究，可为工程应用提供有价值的参考。     

Dynamic stiffness vibration analysis using a high‐order beam model

This work presents the derivation of the exact dynamic stiffness matrix for a high‐order beam element. The terms are found directly from the solutions of the differential equations that describe the deformations of the cross‐section according to the high‐order theory, which include cubic variation of the axial displacements over the cross‐section of the beam. The model has six degrees of freedom at the two ends, one transverse displacement and two rotations, and the end forces are a shear force and two end moments. Using the dynamic stiffness matrix exact vibration frequencies for beams with various combinations of boundary conditions are tabulated and compared with results from the Bernoulli–Euler and Timoshenko beam models. Copyright © 2003 John Wiley & Sons, Ltd.     

Measuring and modeling the rheological data of diglycidylether of bisphenol‐A during polymerization for finite element analyses

Finite element analyses (FEA) of thermosets are often performed on the basis of rheological data for fully cured resin. For the FEA of thermosets during curing, a material model is established and a technique is demonstrated, which allows the rheological data of the linear viscoelastic material to be derived. As the moduli are sensitive to conversion, all measured properties are related to temperature and conversion. Therefore the basis for the rheological data has to be a suitable reaction kinetic. Based on the kinetics shear and compression properties are measured independently and modeled mathematically with the focus to gain a formulation, which is suitable for FEA. The considered time constants are in the range between one second and one month as these times are relevant for the investigated relaxation times. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1868–1872, 2003