Effects of a Nd—Fe—B magnetic filler on the crystallization of poly(phenylene sulfide)

The crystallization of poly(phenylene sulfide) (PPS) in a polymer–magnetic Nd—Fe—B powder suspension was studied. Isothermal crystallization behavior was analyzed by way of differential scanning calorimetry, and the kinetics were described via the Avrami equation. The Avrami parameters and the crystallization times were strongly affected by both the particle size and the presence of a coupling agent coated on the filler particles. The small Nd—Fe—B particles exhibited long induction and half‐times, whereas the large particles tended to have short crystallization times. Particles ranging from 38 to 150 μ appeared to have similar crystallization times and to have no significant change in the value of Avrami index with melt crystallization temperature. As a result of these analyses, the dynamic mechanical properties were determined to correlate the fundamental polymer crystallization characteristics and the physical properties of the PPS binder. The enhancement of the wetting of the filler to the binder was promoted through the coupling agent, as confirmed by dynamic mechanical testing performed on the samples. The storage modulus typically decreased because of the presence of the uncoated small particles. Conversely, the loss modulus was enhanced because of the presence of the coated small particles in the PPS binder. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1091–1102, 2002     

榆树林油田砂岩储层敏感性研究

榆树林油田储层粘土矿物含量较高，各种注入条件和施工条件都会对该储层造成相应的伤害，应采取相应的防护措施，为防止速敏的发生，储层的注水速度应控制在临界流速（1.0mL/min）以下，在油井转注时，可先注入1.09PV的含粘土稳定剂的进行处理，以提高产量或注入量，注入阴离子表面活性剂配置的活性水再注入地层水，不能增加地层水的渗透率，该项试验研究对指导榆树林油田的开发具有重要的意义。     

聚醚酰亚胺热焓松弛的分子量依赖关系

采用ＤＳＣ对不同分子量的聚醚酰亚胺的等温及动态热焓松弛行为进行了研究，并以ＫＷＷ方程对实验数据进行了非线性拟合。结果表明，分子量对热焓松弛的影响是由高分子端基引起自由体积的差异所致。不同分子量的聚醚酰亚胺分子具有不同数量的端基，淬冷时端基数目的差异将产生不同数量的过剩自由体积，从而影响松弛热焓及松弛速率、低分子量的聚醚酰亚胺松弛相对较快，且起始热焓高，松弛的表观活化能亦较小。     

Practical method for generation expansion planning based on dynamic programming

This paper presents an efficient method which provides the optimal generation mix and the optimal generation construction process. The approximation method in which the dynamic programming technique and gradient method are combined is applied to determine the optimal generation mix with hydropower generation technologies. The successive approximations dynamic programming (SADP) technique, which is very suitable for high-dimensional multistage decision process problems, is used for obtaining the optimal generation construction process. The effectiveness and feasibility of the developed technique are demonstrated on a practical power system model which has five types of generation technologies including a hydropower generation technology.     

泥浆制备中工艺改造的研究

根据室条件下粉磨试验结果，发现球磨过程中筛上料变化存在的突变范围，提出两次加料一次加水可改变泥浆颗粒分布，并找出适宜的加料种类与时间。另外给予测粒度分布提供了宝贵的试验基础数据。     

Kinetic study of the hydrolysis of isocyanic acid in the gas phase

The hydrolysis of isocyanic acid in the gaseous phase has been investigated at temperatures between 553 and 613 K by mass spectrometry and evaluated to obtain the corresponding kinetic data. The reaction order and reaction constant have been determined. Finally, the influence of water on the catalysed formation of melamine from isocyanic acid under the operating conditions employed has been investigated in order to determine whether there is a need to try the process gas.     

对洪水分级的浅见

洪水的等级划分应考虑流量、水位、防洪能力及灾害等因素,综合这些因素把洪水分成5个等级。1、2级洪水,洪水流量小,水位低,基本无灾;3级洪水,洪水流量较大或水位较高,有一定灾害;4级洪水,为大洪水或高水位,有较大灾害;5级洪水,为特大洪水或高水位,灾情严重。     

非串行生产线的建模,分析及设计

本文利用等效工作站理论和工件流平衡原理，推导出非串行离散事件生产线可以等价于串联系统，并归结为装配和拆卸两条定理，解决了系统的建模、分析与设计问题。     

Ammonia-water absorption machines for refrigeration: theoretical and real performances

In principle, absorption chillers of the ammonia-water type could work at temperatures well below the usual air-conditioning temperatures, arriving at the range 250–260 K, which can be useful for refrigeration applications. This possibility is studied for an air-cooled machine, comparing the results with the experimental data supplied by a manufacturer that recently commercialized such a refrigerator. The prediction is fair, and the study allows an insight into the internal parameters and into the possible behaviour for more severe conditions than those studied.     

连续驱动摩擦焊动态扭矩检测的新方法—VCMM法

连续驱动摩擦焊动态扭矩检测的新方法──ＶＣＭＭ法刘金合，罗键连续驱动摩擦焊扭矩是一个重要的工艺参数。摩擦焊扭矩是动态扭矩，具有时变性、速变性以及变化范围大等特点。现有的检测摩擦焊扭矩的方法均有一定的局限性’‘－’‘，本文提出了通过驱动主电机定子电压和...