×Synergistic action of non-solvent induced phase separation in preparation of poly（vinyl butyral） hollow fiber membrane via thermally induced phase separation

A systematic study of air gap distance effects on the structure and properties of poly（vinyl butyral） hollow fiber membrane via thermally induced phase separation （TIPS） has been carried out. The results show that the hollow fiber membrane prepared at air gap zero has no skin layer; the pore size near the outer surface is larger than that near the inner surface; and the special pore channel-like structure near the outer surface is formed, which is quite different with the typical sponge-like structure caused by TIPS and the finger-like structure caused by non-solvent induced phase separation （NIPS）, because of the synergistic action of non-solvent induced phase separation at air gap zero. The pore size gradually decreases from outer surface layer to the intermediate layer, but increases gradually from intermediate layer to the inner surface layer. With the increase of air gap distance, the pore size near the outer surface gets smaller and a dense skin layer is formed, and the pore size gradually increases from the outer surface layer to the inner surface layer. Water permeability of the hollow fiber membrane decreases with air gap distance, the water permeability decreases sharply from 45.50× 10^-7 to 4.52× 10^-7 m^3/（m^2-s.kPa） as air gap increases from 0 to 10 mm at take-up speed of 0.236 m/s, further decreases from 4.52×10^-7 to 1.00×10 ^-8m^3/（m^2.s·kPa） as the air gap increases from 10 to 40 mm. Both the breaking strength and the elongation increase with the increase of air gap distance. The breaking strength increases from 2.25 MPa to 4.19 MPa and the elongation increases from 33.9% to 132.6% as air gap increases from 0 mm to 40 mm at take-up speed 0.236 m/s.     

某抽水蓄能电站一起交流串直流故障分析

某抽水蓄能电站发生一起交流串直流故障,通过分析交流串直流的特点,结合现场控制回路原理图,对故障点进行查找,并排除了故障;根据故障时的信号及现象,通过对交流串直流原理进行分析,做出交流串入直流正极和负极的等效原理图。根据等效原理图,分析交流串直流后绝缘监察装置交替报“正母接地”或“负母接地”的原因;通过对交流串直流后的交流电流通路进行分析,得出跳闸中间继电器动作功率是保护装置无故障跳闸的原因。     

以工作页为载体的完整行动模式教学研究与实践——以“数控机床装调与维修”课程为例

结合"数控机床装调与维修"课程,以"FANUC PMC工作方式控制"项目为例,开发了基于完整行动序列"资讯—计划—决策—实施—检查—评价"的工作页,并以此为载体,进行了理实一体化教学研究与实践,以培养学生职业能力,提高学生职业素养。     

电磁方法在地震监测预测中的新思路探讨

针对地面电磁观测的现状与不足,以及我国地震监测预报的迫切需求,探索新方法、新技术在地震监测预报中的应用势在必行。因此,可以开展"一个观测"、"两个研究"及"两个系统"方面的工作,即:"电磁扰动综合分析与观测"、"地磁内、外源场分离及其电流体系研究"、"地震电磁效应产生和传播的机理研究"、"天然源和人工源综合观测分析系统"、"天地一体化电磁立体观测分析系统"等工作。     

咪唑啉型缓蚀剂的合成及其缓蚀机理的研究

以棕榈酸、二乙烯三胺、马来酸酐为原料合成了一种咪唑啉型缓蚀剂YQ-01,与YQ-02复配后得到能有效抑制二氧化碳腐蚀的缓蚀体系YQ-03。应用静态挂片失重法、电化学极化曲线、X射线光电子能谱分析研究了YQ-03抑制二氧化碳腐蚀的电化学特征,分析了腐蚀前、后及加入缓蚀体系YQ-03后A3钢的表面产物,探讨了YQ-03的缓蚀机理。结果表明,由主剂YQ-01和助剂YQ-02组成的复配缓蚀体系有良好的协同作用,腐蚀产物膜有3层,能有效抑制饱和CO2的高矿化度盐水对A3钢的腐蚀。     

提高6063铝合金导热性能的途径探讨

采用试验的方法探讨了镁硅质量比、微量稀土及热处理制度对6063铝合金导热性能的影响。研究结果表明：6063铝合金采用1．73的Mg、Si质量比，加入0．3％稀土，经挤压后在250℃进行退火，然后随炉冷却，热导率比原来提高了9．5％。     

Thermodynamic properties and mixing thermodynamic parameters of Ba-Al, Mg-Al, Sr-Al and Cu-Al metallic melts

Application of equations of mixing thermodynamic parameters formulated on the basis of the coexistence theory of metallic melts in Ba-Al, Mg-Al, Sr-Al and Cu-Al melts leads to fruitful results that not only the evaluated mass action concentrations agree well with the measured activities, but also the calculated mixing thermodynamic parameters are quite coincident with the experimental values. Moreover, the calculated mass action concentrations strictly obey the mass action law. The evaluated mixing thermodynamic parameters have very fine regularity: the mixing free energy is composed of standard free formation energies of all compounds and chemical potentials of all structural units at equilibrium; the mixing enthalpy consists of standard formation enthalpies of all compounds; the mixing entropy is composed of standard entropies of all compounds and configuration entropies of all structural units at equilibrium. As the equations of mixing thermodynamic parameters formulated are widely applicable to metallic melts involving compound formation, they can be used as the second practical criterion to determine whether thermodynamic models of metallic melts are correctly formulated.     

对Al-Cu合金中α-Al及Al2Cu生长行为的探讨

研究了Al-Cu合金中α-Al和Al2Cu的生长行为,分析了初生α-Al及初生Al2Cu作为共晶核心形核的能力.结果发现,在过共晶组织中,初生相Al2Cu形貌大部分有明显的拐角,观察其平面有的呈矩形,呈现小面生长特性.而α-Al与Al2Cu共晶生长时,Al2Cu择优生长特征削弱,与α-Al耦合生长呈现非小面-非小面生长,表明Al2Cu在不同的生长阶段表现出的生长行为不同.在亚共晶组织中,初生相α-Al周围形成离异共晶的Al2Cu,而过共晶组织中初生相Al2Cu周围没有离异共晶的α-Al,表明初生相Al2Cu作为共晶层片核心的能力比初生相α-Al作为共晶层片核心的能力强.     

全自动双色注射模设计

介绍了全自动双色注射模具的技术要求和模具结构设计及动作流程 ,以实例分析了全自动双色注射模具的动作顺序