Electrochemical characteristics for redox systems at nano-honeycomb diamond

Electrochemical characteristics for several redox systems at diamond films with highly ordered nanometer-scale cylindrical pores (‘nano-honeycombs’) were examined with cyclic voltammetry (CV) and electrochemical impedance measurements. The cyclic voltammetric anodic-cathodic peak separations for these nano-honeycomb electrodes were in the same range as those for polished polycrystalline diamond films, indicating that the involvement of the oxygen-terminated surface of the nano-pore walls, which should give rise to large peak separations for certain redox couples was only slight. Moreover, the peak currents in the CV were not enhanced to the extent expected on the basis of the roughness factors of the nano-honeycomb films. Ac impedance plots results indicated the existence of a concentration gradient of the reactant in the nano-pores, which is in agreement with theoretical predictions for charge transfer reactions in porous electrodes. The average concentration of the reactant (Fe^2+/3+) inside the nano-pores was a factor of ca. 80 lower than that in the bulk electrolyte. The results of the impedance analysis also indicated an increase in the reaction resistances with decreasing pore diameters.     

薄板坯连铸浸入式水口结构数值模拟

使用有限元计算方法开展薄板坯连铸浸入式水口流场的研究 ,分别对水口不同浸入深度的流场分布、水口出口不同角度的流场分布进行计算。结果发现 :水口的浸入深度在 30 0mm时较为合理 ;水口的出口角度以R1 5、60°、45°为宜     

Upscaling hydraulic conductivity: theory and examples from geohydrological studies

This paper presents an overview of the theory of upscaling hydraulic conductivity and describes two case studies in which some of this theory has been applied. The representative hydraulic conductivity of a numerical model block (block conductivity for short) is defined in terms of smaller scale hydraulic conductivities. Also, using elementary examples, some general properties of block conductivities are given. Analytical solutions for the block conductivity are presented that were derived by various authors for uniform flow conditions both in a deterministic and in a stochastic setting. Some results of the hydraulic upscaling theory are illustrated by two case studies from the Netherlands. The first case study deals with deriving the representative hydraulic conductivity tensor of a clay layer. Upscaling results are compared with traditional harmonic averaging. In the second case study the upscaling is used to derive the three-dimensional distribution of block conductivities for a numerical groundwater model of a confining layer of complex deposits. Here stochastic upscaling is used together with a geostatistical simulation approach. The simulated block conductivities are used in a numerical groundwater model and results are compared with pumping tests. When the upscaling is ignored groundwater flow through the deposits is predicted wrongly.     

Has water-saving irrigation recovered groundwater in the Hebei Province plains of China?

This study performed a quantitative evaluation of the impact of water-saving irrigation on the groundwater regime in the Hebei Province plains area. In this work, the change in groundwater regime and the contributions of precipitation and water-saving irrigation development were investigated. The results indicate that the groundwater overdraft has been mitigated to some extent, mainly due to changes in precipitation and the implementation of water-saving irrigation, with contributions of 64.3% and 35.7%, respectively, when considering only these two factors. Water-saving irrigation is accepted as an important means for reducing groundwater depletion, but should be used in conjunction with other measures.     

2000—2014年辽宁省植被动态演变特征分析

基于MODIS － NDVI 数据,辅以线性回归法与分段线性回归法,并借助ArcGIS 软件,对辽宁 省2000—2014 年植被覆盖的动态演变过程进行分析。结果表明: ( 1) 时间上,辽宁省植被NDVI 在年 际尺度上呈现出明显的增大趋势,2005 年出现突变,多年平均NDVI 值为0. 496; 春季、夏季、秋季 以及植被生长季NDVI 突变年份分别为2006 年、2005 年、2009 年和2004 年,秋季波动变化的突变点 明显滞后; 植被生长最旺盛的季节为夏季,且集中于8 月。( 2) 空间上,辽宁省植被覆盖具有明显的 地域性差异,呈现出东部高、中西部低的分布特征; 辽宁省植被覆盖优良区与辽东山地的界限基本吻 合,植被覆盖贫乏区主要集中在朝阳市和阜新市的东北部地区。( 3) 辽宁省植被覆盖程度呈山地阴坡 高于阳坡的形态,并且植被覆盖程度最好的坡向为北偏西方向。( 4) 2000—2014 年辽宁省植被覆盖度 整体以维持现状和轻微改善为主,保持不变的区域集中于中东部地区,辽阳市与沈阳市一带有轻微退 化现象,辽西北地区改善情况较为明显。     

长大隧洞工程建设中地下水处理的实践及思考

以引汉济渭工程秦岭输水隧洞(越岭段81.779 km)为例,围绕该隧洞建设过程中的地下水问题,介绍其总体富水情况以及地下水预测方法。通过对秦岭各支洞抽排水措施的综合研究,给出了抽排水方案的设计步骤,结合不同涌水的处理提出了突涌水的处理思路,并介绍了目前国内先进的突涌水预测手段及应用效果。根据秦岭隧洞抽排设备的配置思路以及洞外环保处理情况,指出了目前地下水处理过程中存在的问题并提出相应的解决方法。通过引汉济渭工程建设过程中地下水处理情况的介绍、探讨和分析,对长大隧洞处理类似地下水问题提供一定的借鉴。     

糠醛生产与热电联合处理糠醛废渣模式探讨

糠醛废渣问题是制约我国糠醛行业发展的瓶颈。本文运用工业协作的基本原理,对糠醛生产和热电联合处理糠醛废渣模式进行了分析探讨,对于有效解决糠醛废渣问题及糠醛行业和其它行业实践生态工业具有积极的意义。     

生态型高吸水性树脂的研究

从高吸水性树脂的化学结构出发，论述了树脂的降解机理和降解方法，归纳和评述了近期我国在可降解天然聚合物、丙烯酸接枝共混和丙烯酸（盐）合成聚合物方向的研究，并对未来作出展望。     

免水型生态卫生设施用降解菌的分离筛选

本文对免水型生态卫生设施中的生物填料及施有机肥农田的土壤进行了人类粪便降解菌的分离。筛选得到的各菌种在实验条件下，降解粪便效果较好，除臭除味，COD下降率在30％左右。其中在土壤中分离出来的9号菌，COD下降率达41％，全部菌种复合培养处理的下降率高达59％。结果表明，实验采用的分离筛选方法是比较有效的，筛选得到了具有较好降解效果的菌种，为降解菌的进一步试验打下了基础。     

华北平原地下水资源承载力评价

华北平原地下水严重超采,并带来一系列资源环境问题,地下水资源承载力的可持续性面临严重挑战。本研究定义了地下水资源承载力的概念,提出了一种定量评价地下水承载力的新方法,并对华北平原地下水承载力进行了评价。结果表明,华北平原地区地下水资源支撑的GDP从2003年的15 608.18亿元迅速提高到2011年的37 584.9亿元,33.3%的地市位于未超采未超载区;华北平原整体及57.2%的地市均位于超采未超载区,已发生地下水超采,但通过提高用水效率,未来社会经济规模仍有发展空间;9.5%的地市位于超采超载区。最后探讨地下水资源的承载力的提高途径,主要包括增加地下水资源可利用量和提高用水效率两方面,其中提高用水效率效果更显著。