全文获取类型
收费全文 | 40168篇 |
免费 | 4138篇 |
国内免费 | 2910篇 |
专业分类
电工技术 | 1788篇 |
综合类 | 3654篇 |
化学工业 | 6198篇 |
金属工艺 | 2134篇 |
机械仪表 | 1648篇 |
建筑科学 | 4753篇 |
矿业工程 | 1808篇 |
能源动力 | 1605篇 |
轻工业 | 3150篇 |
水利工程 | 1370篇 |
石油天然气 | 2237篇 |
武器工业 | 435篇 |
无线电 | 5129篇 |
一般工业技术 | 6308篇 |
冶金工业 | 2127篇 |
原子能技术 | 939篇 |
自动化技术 | 1933篇 |
出版年
2024年 | 193篇 |
2023年 | 687篇 |
2022年 | 1176篇 |
2021年 | 1399篇 |
2020年 | 1458篇 |
2019年 | 1349篇 |
2018年 | 1167篇 |
2017年 | 1521篇 |
2016年 | 1482篇 |
2015年 | 1546篇 |
2014年 | 2273篇 |
2013年 | 2427篇 |
2012年 | 2683篇 |
2011年 | 2921篇 |
2010年 | 2235篇 |
2009年 | 2328篇 |
2008年 | 2169篇 |
2007年 | 2610篇 |
2006年 | 2403篇 |
2005年 | 1981篇 |
2004年 | 1702篇 |
2003年 | 1504篇 |
2002年 | 1325篇 |
2001年 | 1038篇 |
2000年 | 973篇 |
1999年 | 762篇 |
1998年 | 611篇 |
1997年 | 575篇 |
1996年 | 482篇 |
1995年 | 412篇 |
1994年 | 358篇 |
1993年 | 299篇 |
1992年 | 232篇 |
1991年 | 197篇 |
1990年 | 167篇 |
1989年 | 137篇 |
1988年 | 100篇 |
1987年 | 65篇 |
1986年 | 44篇 |
1985年 | 32篇 |
1984年 | 35篇 |
1983年 | 22篇 |
1982年 | 19篇 |
1981年 | 12篇 |
1980年 | 18篇 |
1979年 | 22篇 |
1965年 | 5篇 |
1963年 | 5篇 |
1959年 | 9篇 |
1951年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
Tomasz Wasiewicz Paulina Szyszka Miroslawa Cichorek Zorica Janjetovic Robert C. Tuckey Andrzej T. Slominski Michal A. Zmijewski 《International journal of molecular sciences》2015,16(4):6645-6667
Deregulated melanogenesis is involved in melanomagenesis and melanoma progression and resistance to therapy. Vitamin D analogs have anti-melanoma activity. While the hypercalcaemic effect of the active form of Vitamin D (1,25(OH)2D3) limits its therapeutic use, novel Vitamin D analogs with a modified side chain demonstrate low calcaemic activity. We therefore examined the effect of secosteroidal analogs, both classic (1,25(OH)2D3 and 25(OH)D3), and novel relatively non-calcemic ones (20(OH)D3, calcipotriol, 21(OH)pD, pD and 20(OH)pL), on proliferation, colony formation in monolayer and soft-agar, and mRNA and protein expression by melanoma cells. Murine B16-F10 and hamster Bomirski Ab cell lines were shown to be effective models to study how melanogenesis affects anti-melanoma treatment. Novel Vitamin D analogs with a short side-chain and lumisterol-like 20(OH)pL efficiently inhibited rodent melanoma growth. Moderate pigmentation sensitized rodent melanoma cells towards Vitamin D analogs, and altered expression of key genes involved in Vitamin D signaling, which was opposite to the effect on heavily pigmented cells. Interestingly, melanogenesis inhibited ligand-induced Vitamin D receptor translocation and ligand-induced expression of VDR and CYP24A1 genes. These findings indicate that melanogenesis can affect the anti-melanoma activity of Vitamin D analogs in a complex manner. 相似文献
32.
Hong Wei Li Li Ya‐Li Ma Ru‐Xue Liu Shuang‐Yan Meng Li‐Tong Niu Zhe Zhang Zhi‐Wang Yang 《火与材料》2019,43(7):868-879
Through the simple precipitation of palygorskite (PGS) by zinc borate (ZB) (to make PGS@ZB) and the decoration of PGS@ZB by dodecylamine (N), a novel organic‐inorganic@inorganic hybrid flame retardant of PGS@ZB‐N was prepared and was incorporated with ethylene vinyl acetate copolymer (EVA) to improve its flame retardance. The structure and morphology of PGS@ZB‐N were characterized by Fourier transform infrared (FTIR) spectroscopy, X‐ray diffraction (XRD), and scanning electron microscopy (SEM), and it was confirmed that the PGS@ZB‐N hybrid had been successfully prepared. The flame retardancy and burning behavior of EVA/PGS@ZB‐N/EG (EG = expandable graphite) composite were studied through thermogravimetric analysis (TGA), limiting oxygen index (LOI), UL‐94 (by the vertical burning test), and cone calorimeter test (CCT) characterizations. The prepared EVA/PGS@ZB‐N/EG composite obtained an LOI value of 41.2% with the addition of 30 wt% PGS@ZB‐N/EG. It was found that EVA/PGS@ZB‐N/EG was protected through a gas phase and condensed phase alternating synergistic effect mechanism. 相似文献
33.
《Journal of the European Ceramic Society》2020,40(2):203-211
ZrB2-SiC coatings with different ZrB2 contents were prepared by liquid phase sintering. The oxidation processes of coatings were explained according to TG results of ZrB2-SiC coatings and powders tested from 298 K to 1773 K. Results show that, increasing ZrB2 content made the weight of the samples changed from weight-loss of 10.04% to weight-gain of 0.14%, while the fastest weight-loss regions were narrowed, whose inflection points reduced from 1310℃ to 1050℃. Increasing ZrB2 content made the relative oxygen permeability of the ZrB2-SiC/SiC coatings reduced from 40%–60% to -10%-5%. Increasing ZrB2 content enhanced high-temperature stability of coatings, making final weight of samples changed from weight-loss of 0.16% to weight-gain of 0.11% after oxidation at 1773 K for 200 h. The peeling and dispersion of Zr-oxides formed Zr-B-Si-O compound glass layer, presenting enhanced stability, dispersion strengthening and pinning effect of Zr-oxides, which were responsible for the excellent anti-oxidation protective effect of coatings in a broad temperature region. 相似文献
34.
Comparative fatigue tests were carried out on Friction Stir Welded specimens of a 2195-T8 aluminum–lithium alloy that differed significantly in width. The width of the larger specimens was over thirteen times greater than that of the small specimens. Fatigue results showed a clear “size effect”, i.e. fatigue life of large specimens was about 40% of the corresponding value of small specimens. The Equivalent Initial Flaw Size methodology was adopted to correlate the two sets of results. Fatigue crack initiation life was disregarded with respect to crack propagation life, and fatigue life was evaluated only as propagation of a small pre-existing defect. Following this methodology, test results of small specimens were used to evaluate the initial equivalent flaw contained in each specimen. It was assumed that this data followed a normal distribution. The equivalent initial flaw in larger specimens was evaluated by simple geometrical considerations. A very good assessment of mean fatigue life and scatter in the fatigue results of large specimens was obtained by simulating the propagation of these defects. Calculations were carried out by taking also welding residual stresses into account, but the results demonstrated that this effect was not significant. 相似文献
35.
Ziqian Wang Yalan Chen Yating He Weidong Jiang Yan Long Guangyin Fan 《International Journal of Hydrogen Energy》2021,46(21):11587-11596
Developing high-efficiency and low-cost catalysts for hydrogen evolution from hydrolysis of ammonia borane (AB) is significant and critical for the exploitation and utilization of hydrogen energy. Herein, the in-situ fabrication of well-dispersed and small bimetallic RuNi alloy nanoparticles (NPs) with tuned compositions and concomitant hydrolysis of AB are successfully achieved by using graphitic carbon nitride (g-C3N4) as a NP support without additional stabilizing ligands. The optimized Ru1Ni7.5/g-C3N4 catalyst exhibits an excellent catalytic activity with a high turnover frequency of 901 min?1 and an activation energy of 28.46 kJ mol?1 without any base additives, overtaking the activities of many previously reported catalysts for AB hydrolysis. The kinetic studies indicate that the AB hydrolysis over Ru1Ni7.5/g-C3N4 is first-order and zero-order reactions with respect to the catalyst and AB concentrations, respectively. Ru1Ni7.5/g-C3N4 has a good recyclability with 46% of the initial catalytic activity retained even after five runs. The high performance of Ru1Ni7.5/g-C3N4 should be assigned to the small-sized alloy NPs with abundant accessible active sites and the synergistic effect between the composition-tuned Ru–Ni bimetals. This work highlights a potentially powerful and simple strategy for preparing highly active bimetallic alloy catalysts for AB hydrolysis to generate hydrogen. 相似文献
36.
Ha-Nul Lee Joo-Hee Choi Ji-Yeon Park Jae-Hun Ahn Da Eun Jang Jae Gun Shim Jong-Hwan Park Young-Min Kim 《Food science and biotechnology》2021,30(4):583
Vegetable soup (VS), a plant-based functional food, has been used as a traditional folk medicine and is attracting attention for its ability to enhance the immune response. β-Glucan, a well-established and effective immunomodulator, has synergistic effects when used in combination with some bioactive compounds. In the present study, we aimed to evaluate the synergistic immunomodulatory effects of the combination of VS and β-glucan on macrophage-mediated immune responses. β-Glucan was demonstrated to synergistically enhance the VS-stimulated immune response, including the production of interleukin-6, tumor necrosis factor-α, and nitric oxide, mainly through the mitogen-activated protein kinase pathway in macrophages. In addition, this combination has the potential for further development in functional foods with immune-enhancing activity.Supplementary InformationThe online version contains supplementary material available at 10.1007/s10068-021-00888-x. 相似文献
37.
AlSb晶体内二维磁极化子的磁场与温度效应 总被引:1,自引:0,他引:1
在考虑声子之间相互作用的同时,本文应用线性组合算符和微扰法研究了电子自旋对弱耦合二维磁极化子特性的影响。对AlSb晶体所作的数值计算结果表明,随着磁场的加强,磁极化子平均数减少;随着温度的增加,磁极化子平均数也增加;随着温度的增加,电子自旋作用以及声子之间相互作用都加强;随着磁场的加强,电子自旋作用增加而声子之间相互作用基本不变。 相似文献
38.
A set of poly[N‐oligo(ethylene oxide)yl 4‐vinylpyridinium tosylate] (P4VOEOOTs) has been prepared by spontaneous polymerization of 4‐vinylpyridine. This method gives a grafted polyelectrolyte having a positive charge on every backbone pyridinic moiety. The P4VP15Ts, P4VP164Ts, P4VP350Ts and P4VP750Ts aqueous solution conductivities were determined in the concentration range from 6 × 10?4 to 10?2 M at 25 °C. The variation of the conductivity versus concentration of the investigated system exhibits typical polyelectrolyte behaviour. The polyelectrolyte mobility was found to be dependent on the oligo(ethylene oxide) (OEO) side‐chain length. Manning's rod‐like model fails to describe these results. A simple steric effect is proposed to explain the influence of the OEO length. Copyright © 2003 Society of Chemical Industry 相似文献
39.
40.
川东北飞仙关组碳酸盐岩气藏产能影响因素及压裂酸化新技术探讨 总被引:3,自引:2,他引:1
川东北地区飞仙关组碳酸盐岩气藏的储集层条件起好,不论直井还是水平井均可获高产工业气流,投产前的解堵酸化均可实现大幅度增产。在分析介绍该地区气藏地质特征的基础上,全面剖析了影响产能的主要因素,并对多功能深部酸化技术方案和稠化酸加砂压裂技术方案进行了具体探讨。 相似文献