全文获取类型
收费全文 | 25264篇 |
免费 | 3174篇 |
国内免费 | 1648篇 |
专业分类
电工技术 | 1458篇 |
技术理论 | 5篇 |
综合类 | 1668篇 |
化学工业 | 5691篇 |
金属工艺 | 1606篇 |
机械仪表 | 782篇 |
建筑科学 | 1453篇 |
矿业工程 | 1141篇 |
能源动力 | 2163篇 |
轻工业 | 888篇 |
水利工程 | 570篇 |
石油天然气 | 895篇 |
武器工业 | 125篇 |
无线电 | 1630篇 |
一般工业技术 | 2578篇 |
冶金工业 | 3169篇 |
原子能技术 | 202篇 |
自动化技术 | 4062篇 |
出版年
2024年 | 140篇 |
2023年 | 669篇 |
2022年 | 918篇 |
2021年 | 1015篇 |
2020年 | 1118篇 |
2019年 | 986篇 |
2018年 | 855篇 |
2017年 | 1039篇 |
2016年 | 1044篇 |
2015年 | 1024篇 |
2014年 | 1687篇 |
2013年 | 1696篇 |
2012年 | 1975篇 |
2011年 | 2219篇 |
2010年 | 1675篇 |
2009年 | 1627篇 |
2008年 | 1484篇 |
2007年 | 1551篇 |
2006年 | 1263篇 |
2005年 | 981篇 |
2004年 | 740篇 |
2003年 | 685篇 |
2002年 | 587篇 |
2001年 | 465篇 |
2000年 | 436篇 |
1999年 | 402篇 |
1998年 | 315篇 |
1997年 | 247篇 |
1996年 | 264篇 |
1995年 | 168篇 |
1994年 | 171篇 |
1993年 | 117篇 |
1992年 | 116篇 |
1991年 | 73篇 |
1990年 | 48篇 |
1989年 | 38篇 |
1988年 | 35篇 |
1987年 | 21篇 |
1986年 | 23篇 |
1985年 | 29篇 |
1984年 | 24篇 |
1983年 | 23篇 |
1982年 | 17篇 |
1981年 | 19篇 |
1980年 | 14篇 |
1979年 | 8篇 |
1978年 | 6篇 |
1977年 | 4篇 |
1973年 | 3篇 |
1951年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
VK Tzitzios V Georgakilas TN Angelidis 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(6):699-704
A study of nitrous oxide (N2O) reduction with methane (CH4) and propene (C3H6) in the presence of oxygen (5%) over Ag/Al2O3, Rh/Al2O3 and Ag–Rh/Al2O3 catalysts, with Ag and Rh loadings of 5 wt% and 0.05 wt% respectively, has been performed. From the results, it was observed that the Ag–Rh bimetallic catalyst was the most active for both nitrous oxide removal (more than 95%) and hydrocarbon oxidation. This high activity seems to be connected with a synergistic effect between Ag and Rh. The findings from X‐ray diffraction and X‐ray photoelectron spectroscopy studies showed also, that there were no strong interactions (eg alloying) between Ag and Rh. Copyright © 2005 Society of Chemical Industry 相似文献
62.
Yuanjing Zheng Anker Degn Jensen Jan Erik Johnsson 《Applied catalysis. B, Environmental》2005,60(3-4):253-264
The deactivation of a commercial type V2O5-WO3-TiO2 monolith catalyst under biomass combustion was studied at a full-scale grate-fired power plant burning straw/wood using a slip stream pilot scale reactor. The aerosols in the flue gas consisted of a mixture of potassium chloride and sulphate. Three catalyst elements were exposed at 350 °C, and one element was exposed at 250 °C for comparison. The catalyst activity was measured in the reactor at the exposure temperature by addition of NH3 and extra NO. The activity, in terms of a first-order rate constant, dropped by 52% after about 1140 h indicating a very fast deactivation compared to coal firing. It was also found that the reactor temperature was not of importance for the deactivation rate. SEM-EDX analysis showed that particle deposition and pore blocking contributed to the deactivation by decreasing the diffusion rate of NO and NH3 into the catalyst. However, potassium also penetrated into the catalyst wall and the resulting average K/V ratio in the catalyst structure was high enough (about 0.3–0.5) for a significant chemical deactivation. Chemisorption studies carried out in situ showed that the amount of chemisorbed NH3 on the catalyst decreased as a function of exposure time, which reveals that Brøndsted acid sites had reacted with potassium compounds and thereby rendered inactive. When washed by 0.5 M H2SO4 the regenerated catalyst regains a higher activity than that of the fresh catalyst at temperatures higher than 300 °C, but even though reactivation is possible, the deactivation rate appears too high for practical use of the SCR process in straw combustion. 相似文献
63.
恰当选择原材料、确保铆接工序质量、重视工作电解液的配比、严控各工序成品率是提高超小型铝电解电容器投入产出一次合格率的关键。以10V-47μF(4mm×7mm)产品为例,投入产出一次合格率达94%以上。 相似文献
64.
W. Sjoerd Kijlstra Joop C.M.L. Daamen Jolinde M. van de Graaf Bart van der Linden Eduard K. Poels Alfred Bliek 《Applied catalysis. B, Environmental》1996,7(3-4):337-357
The effect of water on the selective catalytic reduction (SCR) of nitric oxide with ammonia over alumina supported with 2–15 wt.-% manganese oxide was investigated in the temperature range 385–600 K, with the emphasis on the low side of this temperature window. Studies on the effect of 1–5 vol.-% water vapour on the SCR reaction rate and selectivity were combined with TPD experiments to reveal the influence of water on the adsorption of the single SCR reactants. It turned out that the activity decrease due to water addition can be divided into a reversible inhibition and an irreversible deactivation. Inhibition is caused by molecular adsorption of water. TPD studies showed that water can adsorb competitively with both ammonia and nitric oxide. Additional kinetic experiments revealed that adsorbed ammonia is present in excess on the catalyst surface, even in the presence of water. Reduced nitric oxide adsorption is responsible for the observed reversible decrease in the reaction rate; the fractional reaction order changes from 0.79 in the absence of water to 1.07 in its presence. Deactivation is probably due to the dissociative adsorption of water, resulting in the formation of additional surface hydroxyls. As the amount of surface hydroxyls formed is limited to a saturation level, the deactivating effect on the catalyst is limited too. The additional hydroxyls condense and desorb in the temperature range 525–775 K, resulting in a lower degree of deactivation at higher temperature. A high temperature treatment at 775 K results in a complete regeneration. The amount of surface hydroxyls formed per unit surface area decreases at increasing MnOx-loading. The selectivity to the production of nitrogen is enhanced significantly by the presence of gas phase water. 相似文献
65.
本文提出了一种新的限制输出个数减少随机多变量自适应控制中辨识参数的方法,并给出了减少辨识参数的极点配置自适应算法。虽然采用n个输入1个输出的减少辨识参数的模型来设计控制器,但所提出的控制器能够保证被控系统的几个输出跟踪参考输入信号,仿真结果表明,所提出的方法是成功的。 相似文献
66.
The concept of moving surface boundary-layer control, as applied to a Joukowsky airfoil, is investigated through a planned
experimental programme complemented by numerical studies. The moving surface was provided by rotating cylinders located at
the leading edge and/or trailing edge as well as top surface of the airfoil. Results suggest that the concept is quite promising,
leading to a substantial increase in lift and a delay in stall. Depending on the performance desired, appropriate combinations
of cylinder geometry, location and speed can be selected to obtain favourable results over a wide range of angle of attack.
Next, effectiveness of the concept in reducing drag of bluff bodies such as a two-dimensional flat plate at large angles of
attack, rectangular prisms and three-dimensional models of trucks is assessed through an extensive wind tunnel test-programme.
Results show that injection of momentum through moving surfaces, achieved here by introduction of bearing-mounted, motordriven,
hollow cylinders, can significantly delay separation of the boundary-layer and reduce the pressure drag. The momentum injection
procedure also proved effective in arresting wind-induced vortex resonance and galloping type of instabilities. A flow visualization
study, conducted in a closed-circuit water tunnel using slit lighting and polyvinyl choride tracer particles, adds to the
wind-tunnel and numerical investigations. It shows, rather dramatically, the effectiveness of the moving surface boundary-layer
control (MSBC).
The Sabita Chaudhury Memorial Lecture
The models were fabricated in the Mechanical Engineering Workshop. The assistance of M/s E Abell, P Hurren and D Camp in the
design and construction of the models is gratefully acknowledged. The investigation was supported by the Natural Sciences
and Engineering Research Council of Canada, Grant No. A-2181. 相似文献
67.
68.
In this work, a possible way for partial CO2 emissions reduction from gas turbine exhausts by co-firing with biomass is investigated. The basic principle is the recirculation of a fraction of the exhausts (still rich in oxygen) to a gasifier, in order to produce syngas to mix with natural gas fuel. As biomass is a CO2 neutral fuel, the fraction of replaced natural gas is a measure of CO2 removal potential of the powerplant. 相似文献
69.
以镁法海绵钛生产工艺中大型无隔板镁电解槽的实际节能情况为例,探讨了在镁电解生产中的非生产耗电、生产耗电、漏电等因素造成的能量浪费,阐述了生产中粗镁直流电耗、电流效率、工作电压3者之间的关系,指出了影响电解槽工作电压的有关因素及降低电解槽工作电压的途径。 相似文献
70.
氟化铝是电解生产中十分重要的原料,它对控制电解槽电解质温度,保持电解槽技术条件发挥着重要的作用。但随着电解生产成本的逐渐降低,氟化铝的消耗成为电解生产成本中的一项重要内容。本文就某分厂电解槽氟化铝添加的生产工艺、设备、控制以及管理等方面,提出降低氟化铝单耗的简要方法。 相似文献