聚苯胺膜电极的电化学性能

CS-PAn(化学氧化聚合法合成聚苯胺)膜电极的CV曲线类似于ES-PAn(电化学聚合法合成的聚苯胺)膜电极,而且他们都具有优良的可逆性和循环稳定性。交流阻抗图谱表明两种方法制备的PAn具有相同的电化学反应机理。C S-PAn-Li和ES-PAn-Li扣式电池的最大放电比容量分别为75m Ah.g-1和86m Ah.g-1,容量衰减率分别为13.2%和6.8%,ES-PAn-Li扣式电池的大电流充放电性能优于CS-PAn-Li扣式电池。     

Sugar Beet Grown Using Nutrient Film Technique: Yield and Nutritional Quality

Sugar beet (Beta vulgaris L cv Great Western Sugar) was grown using the nutrient film technique with a half-strength modified Hoagland nutrient solution to determine its biomass yield and nutritional quality. After 6 months, storage root and foliage weights per plant were 493·1 g and 551·0 g, respectively. Sucrose content in the fresh storage root was 118·4 g kg⁻¹ but was less than 10 g kg⁻¹ in the fresh leaves and petioles. Some nutrients in the leaves and petioles were analysed to evaluate their potential as a leafy vegetable. Fresh leaf protein, total dietary fibre, mineral (Ca, Mg, Zn, Fe and K), vitamin (carotene, ascorbic acid and thiamine) and oxalic acid concentrations were similar to those of consumer-accepted green vegetables.     

过渡族金属掺杂ZnO薄膜的晶体结构和磁性能

采用电子束蒸发法制备了过渡族金属(Fe、Co、Cu)掺杂ZnO薄膜。分析和研究了衬底温度以及Cu掺杂量对薄膜相结构的影响,获得沿c轴高度择尤取向的高质量ZnO薄膜。采用原子力显微镜(AFM)观察薄膜的显微结构,利用所得的图象信息对薄膜进行分析,发现400℃的衬底温度对硅衬底薄膜是合适的,与XRD分析相吻合。通过对薄膜磁性能的分析和研究,得出一些有意义的结果:适量Fe、Co离子掺杂的ZnO薄膜,在室温下具有铁磁性,而在此基础上掺入少量的Cu离子能改善薄膜的磁性能。     

Condensation of organic binary mixtures flowing horizontally in a horizontal tube bundle

Both heat and mass transfer in the gas phase and heat transfer in the liquid phase are examined experimentally for film condensation of organic binary mixtures such as ethanol-water and methanol-water. Experimental results on the average heat flux, vapor-liquid interface temperature and liquid-phase Nusselt number are compared with analytical solutions based on stagnant film theory and heat-transfer relationships for film condensation from a pure vapor. Experimental heat transfer results agree well with the analytical solutions, except that the experimental liquid-phase Nusselt numbers under conditions of low mass fraction of water are considerably higher than predicted by the analytical solutions. This high value of the liquid-phase Nusselt number is considered to be caused by dropwise condensation in the liquid phase. However, its effect on the tube bundle is not so remarkable compared with that in gravity-controlled condensation on a vertical surface. This is considered to be caused by the condensate inundation effect. © 1997 Scripta Technica, Inc. Heat Trans Jpn Res, 25(6): 342–361, 1996     

化学镀Ni-P合金镀层内应力的研究

采用薄片弯曲法测量不同pH值和不同热处理对化学镀镍层内应力的影响,分析了产生变化的原因.结果表明,当镀液pH值为3.8～4.1和4.4～4.6时,镀层受到的内应力为压应力,而当镀液pH值为4.8～5.1时,镀层受到的内应力为拉应力.镀液pH值越高,镀层中磷含量越低,其内应力越高.经过200℃×1 h热处理,镀层的内应力减小;经过400℃×1 h或600℃×1 h热处理,镀层的内应力增大.     

锌/碳纳米管复合电沉积薄膜性能研究

通过复合电沉积技术制备了纳米叠层锌/碳纳米管和光亮锌/碳纳米管2种复合薄膜,薄膜的拉曼光谱验证了锌与碳纳米管的共沉积。薄膜表面的场发射扫描电子显微镜观测显示碳纳米管表面的金属包覆层连续且均匀,预示着良好的界面结合。在2种薄膜的断口和裂纹处分别发现了被拔出基体和桥联的碳纳米管,证实了碳管对基体具有有效的增强作用。     

功率高压稳流源的设计应用

介绍一种高压电流可调大功率稳流电路的设计方法,电路选用VMOS管作为功率器件。可实现工作电压800V以上或电流达数十安培的稳流电源,使用上限由VMOS管的最大额定值决定。电路简单可靠,可直接串联在直流供电回路中使用。该电路应用于溅射镀膜机上,可较精确地控制多层合金膜镀层。     

Free chlorine fixation and the protective film in boundary lubrication

Wax chloride is an older type of additive which releases free chlorine when it is hydrolysed or when it is in conditions of boundary lubrication. The chlorine forms a protective film of ferro-chloride but, on the other hand, it severely rusts the iron, the main reason for its discontinuance since the 1960s. In this paper, epoxy plant oil is recommended as a means to absorb effectively and fix the free chlorine, then transform it into chlorohydroxyl oil and polyether. Rust corrosion can be controlled, and the absorbent transformed into a ferro-chloride protective film on the frictional surfaces of the iron during rubbing. The free chlorine can thus be transformed directly into a protective film. With a dynamic test for the reaction of absorption HCl, a friction test, an anti-rust test, electron spectroscopy and infrared spectroscopy analysis, the underlying principles and effects of chlorine fixation have been confirmed. This method has been applied to cold squeezing, and tested with EP industrial gear oil. The price of wax chloride is much less than the standard additive containing sulphur and phosphorus, and its properties are almost the same. It is concluded that wax chloride could still be viable for use in lubricants.     

环境对各向异性导电胶膜性能参数的影响

各向异性导电胶膜(ACF)的玻璃转化温度T_g是它的一个重要性能参数,用差示扫描热示计(DSC)分别测定商用各向异性导电胶膜固化前和固化后的玻璃转化温度,并确定不同的固化时间对它的玻璃转化温度的影响,以及高温高湿(85℃,85%RH)环境对它的玻璃转化温度影响,得到各向异性导电胶玻璃转化温度下降是其粘接强度下降的原因之一。     

高温超导薄膜微波表面电阻测试方法的改进

介绍了一种12 GHz附近的高温超导薄膜微波表面电阻Rs测试系统。该系统采用低损耗高介电常数的蓝宝石,构成工作在TE011+δ谐振模式的介质谐振器,在77 K时,利用测量介质谐振器的Q值得到单片高温超导薄膜的微波表面电阻Rs。分析了其耦合装置对校准物理模型的影响,通过改进耦合装置可提高系统测试的准确度。该系统与前三代测试系统进行比较,其测试准确度有明显地提高。