Retracted: Dual Effects of Nanostructuring and Oxygen Vacancy on Photoelectrochemical Water Oxidation Activity of Superstructured and Defective Hematite Nanorods

An Ar atmospheric treatment is rationally used to etch and activate hematite nanoflakes (NFs) as photoanodes toward enhanced photoelectrochemical water oxidation. The formation of a highly ordered hematite nanorods (NRs) array containing a high density of oxygen vacancy is successfully prepared through in situ reduction of NFs in Ar atmosphere. Furthermore, a hematite (104) plane and an iron suboxide layer at the absorber/back‐contact interface are formed. The material defects produced by a thermal oxidation method can be critical for the morphology transformation from 2D NFs to 1D NRs. The resulting hematite NR photoanodes show high efficiency toward solar water splitting with improved light harvesting capabilities, leading to an enhanced photoresponse due to the artificially formed oxygen vacancies.     

Imparting Designer Biorecognition Functionality to Metal–Organic Frameworks by a DNA‐Mediated Surface Engineering Strategy

Surface functionality is an essential component for processing and application of metal–organic frameworks (MOFs). A simple and cost‐effective strategy for DNA‐mediated surface engineering of zirconium‐based nanoscale MOFs (NMOFs) is presented, capable of endowing them with specific molecular recognition properties and thus expanding their potential for applications in nanotechnology and biotechnology. It is shown that efficient immobilization of functional DNA on NMOFs can be achieved via surface coordination chemistry. With this strategy, it is demonstrated that such porphyrin‐based NMOFs can be modified with a DNA aptamer for targeting specific cancer cells. Furthermore, the DNA–NMOFs can facilitate the delivery of therapeutic DNA (e.g., CpG) into cells for efficient recognition of endosomal Toll‐like receptor 9 and subsequent enhanced immunostimulatory activity in vitro and in vivo. No apparent toxicity is observed with systemic delivery of the DNA–NMOFs in vivo. Overall, these results suggest that the strategy allows for surface functionalization of MOFs with different functional DNAs, extending the use of these materials to diverse applications in biosensor, bioimaging, and nanomedicine.     

Simplified Perovskite Solar Cell with 4.1% Efficiency Employing Inorganic CsPbBr3 as Light Absorber

Perovskite solar cells with cost‐effectiveness, high power conversion efficiency, and improved stability are promising solutions to the energy crisis and environmental pollution. However, a wide‐bandgap inorganic–semiconductor electron‐transporting layer such as TiO₂ can harvest ultraviolet light to photodegrade perovskite halides, and the high cost of a state‐of‐the‐art hole‐transporting layer is an economic burden for commercialization. Here, the building of a simplified cesium lead bromide (CsPbBr₃) perovskite solar cell with fluorine‐doped tin oxide (FTO)/CsPbBr₃/carbon architecture by a multistep solution‐processed deposition technology is demonstrated, achieving an efficiency as high as 4.1% and improved stability upon interfacial modification by graphene quantum dots and CsPbBrI₂ quantum dots. This work provides new opportunities of building next‐generation solar cells with significantly simplified processes and reduced production costs.     

Nanoconfined Nickel@Carbon Core–Shell Cocatalyst Promoting Highly Efficient Visible‐Light Photocatalytic H2 Production

The realization of large‐scale solar hydrogen (H₂) production relies on the development of high‐performance and low‐cost photocatalysts driven by sunlight. Recently, cocatalysts have demonstrated immense potential in enhancing the activity and stability of photocatalysts. Hence, the rational design of highly active and inexpensive cocatalysts is of great significance. Here, a facile method is reported to synthesize Ni@C core–shell nanoparticles as a highly active cocatalyst. After merging Ni@C cocatalyst with CdS nanorod (NR), a tremendously enhanced visible‐light photocatalytic H₂‐production performance of 76.1 mmol g^?1 h^?1 is achieved, accompanied with an outstanding quantum efficiency of 31.2% at 420 nm. The state‐of‐art characterizations (e.g., synchrotron‐based X‐ray absorption near edge structure) and theoretical calculations strongly support the presence of pronounced nanoconfinement effect in Ni@C core–shell nanoparticles, which leads to controlled Ni core size, intimate interfacial contact and rapid charge transfer, optimized electronic structure, and protection against chemical corrosion. Hence, the combination of nanoconfined Ni@C with CdS nanorod leads to significantly improved photocatalytic activity and stability. This work not only for the first time demonstrates the great potential of using highly active and inexpensive Ni@C core–shell structure to replace expensive Pt in photocatalysis but also opens new avenues for synthesizing cocatalyst/photocatalyst hybridized systems with excellent performance by introducing nanoconfinement effect.     

Electrochemical Behavior of Single CuO Nanoparticles: Implications for the Assessment of their Environmental Fate

The electrochemical behavior of copper oxide nanoparticles is investigated at both the single particle and at the ensemble level in neutral aqueous solutions through the electrode‐particle collision method and cyclic voltammetry, respectively. The influence of Cl^? and NO₃^? anions on the electrochemical processes occurring at the nanoparticles is further evaluated. The electroactivity of CuO nanoparticles is found to differ between the two types of experiments. At the single‐particle scale, the reduction of the CuO nanoparticles proceeds to a higher extent in the presence of chloride ion than of nitrate ion containing solutions. However, at the multiparticle scale the CuO reduction proceeds to the same extent regardless of the type of anions present in solution. The implications for assessing realistically the environmental fate and therefore the toxicity of metal‐based nanoparticles in general, and copper‐based nanoparticles in particular, are discussed.     

Mechanical and thermal properties of RE4Hf3O12 (RE=Ho,Er, Tm) ceramics with defect fluorite structure

The thermal and environmental barrier coatings (T/EBC) are technologically important for advanced propulsion engine system. In this study, RE₄Hf₃O₁₂ (RE=Ho, Er, Tm) with defect fluorite structure was investigated for potential use as top TBC layer. Dense pellets were fabricated via a hot pressing method and the mechanical and thermal properties were characterized. RE₄Hf₃O₁₂ (RE=Ho, Er, Tm) possessed a high Vickers hardness of 11 GPa. The material retained high elastic modulus at elevated temperatures up to 1773 K, which made it attractive for high temperature application. The coefficient of thermal expansion (CTE) of RE₄Hf₃O₁₂ (RE = Ho, Er, Tm) laid in the range between 7 × 10⁻⁶ K⁻¹ to 10 × 10⁻⁶ K⁻¹ from 473 K to 1673 K. In addition, the rare earth hafnates exhibited lower thermal conductivity which rendered it a good candidate material for thermal barrier applications.     

基于超声相控技术的船舶吃水测量方法

为了解决内河船舶因超吃水引起的通航阻塞以及船舶安全问题,提出一种基于超声相控技术的船舶吃水测量方法。以超声相控技术为理论基础,通过控制一维线型超声相控阵列换能器发射聚焦声波,实现对目标船舶的相控扫描,获取各扫描点的回波信号;利用匹配滤波算法对回波信号进行滤波,改善信噪比;利用阈值法提取回波信号的时延;利用渡越时间法,计算出扫描点到各发射振元中心的距离,利用双曲交汇法计算出扫描点的空间坐标;分析回波信号幅值和扫描点位置坐标即可得到船舶吃水深度。为验证方法的可靠性,搭建了小比尺船模吃水测量实验系统,分析了110~140 mm不同吃水深度下的实验结果,计算了实际吃水与测量吃水间的相对误差。实验结果表明,使用匹配滤波法处理后的回波信号信噪比从15.26 dB提高至36.39 dB,实验时,最大相对误差出现在船舶实际吃水130 mm时,绝对误差为2.3 mm,相对误差为1.7%。     

食品包装材质对消费者绿色购买意愿影响的眼动研究

目的 探讨食品包装材质对消费者注意加工流程和绿色购买意愿影响的内在机制。方法 采用包装材质2(环保/普通)×食品类型2(实用品/享乐品)双因素实验设计,在货架购物场景下采用Tobii Glasses 2眼镜式眼动仪,采集被试者浏览货架不同食品时的眼动数据(平均注视时间、注视次数、热点图),并结合行为数据综合分析。结果 在平均注视时间上,包装材质与食品类型的交互作用显著,注视次数交互作用不显著;环保材质包装的食品获得更多关注,被试者偏好于选择环保包装的享乐食品。结论 包装材质与食品类型共同影响消费者的视觉感知效果与加工过程,环保包装对青年消费者的绿色购买意愿有正向促进作用。     

基于ANSYS强度仿真与动力学测试的包装结构优化设计

目的 在保障机械结构强度的前提下,对消费量大的某泵用木包装结构进行优化设计,对机械强度进行CAE有限元仿真,并进行振动跌落冲击测试,以降低成本提高产品价值。方法 首先分析产品的使用功能,设计新型包装方案,将原有铁底板支撑结构优化改为用材更少的V型木质支撑结构,建立力学模型,进行底强度分析以及稳定性计算;然后运用SolidWorks建立3D模型,运用ANSYS Workbench进行仿真评估;最后生产出新型包装,并根据包装测试标准进行了测试。结果 新的包装结构用V型木质取代了铁底板支撑,节约了100%的铁质包装材料,并通过了冲击振动跌落测试。优化设计的新包装型式能满足运输过程中的冲击振动跌落等产品保护要求,满足运输稳定性的功能要求。结论 本文以价值工程理念为指导,优化设计的新包装结构,在满足产品功能的同时节约了成本,是价值工程在包装优化领域极好的运用,为机械工程领域包装工程师提供了设计参考和解决方案。