垃圾焚烧管式布风流化床的冷态实验

在床截面为300mm×300mm、床高为4. 4m的管式布风流化床实验台上,分别对宽筛分下不同颗粒粒度、不同床层高度、不同截面流速、布风的均匀性以及非平衡布风时颗粒流化特性进行实验研究,为未来垃圾衍生燃料的流化燃烧实验提供基础数据。管式布风流化床的开孔方向与夹角大小对床层压降变化影响明显,向下开孔角度越小,动能消耗越大,但床层稳定性能好。随着料层高度增加,各布风管间的布风更趋于平衡,流化的稳定与均匀性能也越好。管组压降失衡时,床层压降不平衡明显增加,波动幅度增大,不稳定性明显高于正常流化状态。     

聚合物合成及成型加工中协同学的应用

综述了协同学在聚合物领域的最新研究进展，介绍了加工制备一些聚合物合成及复合材料所显示出的协同效应，以及用协同学方法定量求解一类合成反应体系的动力学模型。提出通过改变振动力场等作用方式，在聚合物动态塑化成型加工时，协同学方法具有广阔的应用前景。     

Determination of the adhesion force between particles and a flat surface, using the centrifuge technique

By using a centrifuge technique, the influence of powdery material particle size on the adhesion force particle-surface was determined. In order to achieve this, the adhesion of phosphatic rock (ρ_p = 3.090 kg m^− 3) and of manioc starch particles (ρ_p = 1.480 kg m^− 3) on a steel surface were studied. A microcentrifuge that reached a maximum speed rotation of 14000 rpm and which contained specially designed centrifuge tubes was used. There tubes contained the flat surface where the test particles were deposited. The powder particles were dispersed on these disks and the particles detachment were performed using diverse centrifugal speeds. The graphics of particle percentages still adhering on the surface of the disks as a function of the applied detachment force showed that the profile of adhesion force followed a log-normal distribution. The adhesion force increased with particle size. The manioc starch particles presented adhesion forces greater than those for the phosphatic rock particles for all particle sizes studied. The results obtained were compared with the theory proposed by Derjaguin, Muller and Toporov whose theoretical adhesion presented values close to the experimental data for the phosphatic rock particles adhesion on the stainless steel surface. On the contrary, the theoretical values were lower than the experimental ones for the manioc starch particles maybe due to the small roughness of these particles, their physical properties (softer and deformable material) and/or specific chemical interactions since the organic composition of the manioc starch particles that can dominate the adhesion force. Finally, the separation distance among the surfaces in contact (Z₀) was estimated in approximately 1.0 × 10^− 9 m for the phosphatic rock and 5.0 × 10^− 10 m for the manioc starch. These results were weakly dependent on the particle size range.     

电动汽车机电复合制动力分配策略研究

为了实现再生制动力与机械制动力在驱动轮和从动轮之间的优化分配,在保证车辆制动安全的同时提高能量回收效率,将汽车理想制动力分配I曲线与模糊算法相结合,提出一种基于模糊控制的电动汽车机电复合制动力分配策略。设计了电动汽车再生制动力分配模糊控制器,根据车辆工况与理想制动力分配I曲线,计算前后轮上分别应加载的机电复合制动力大小。建立了电动汽车制动系统动力学仿真模型,在此基础上进行仿真分析。最后利用Advisor仿真软件对该分配策略进行回收能量效率测试。结果表明,该分配策略既能保证汽车前后轮的制动力分配按照理想制动力I曲线分布,确保汽车的制动安全;又能有效地实现再生制动能量回收,提高电动汽车的续驶里程。     

Effect of crystallization on morphology-conductivity relationship in polypyrrole/poly(?-caprolactone) blends

Electrically conducting blends, based on polypyrrole (PPy) as the conductive polymer and poly(?-caprolactone) (PCL) as an insulating polymeric matrix, were prepared by polymerizing pyrrole (Py) in its vapor state inside the PCL matrix. The roles of specific interactions between blend components as well as the crystallization of PCL matrix in the resulting morphology have been analyzed by Fourier-transform infrared spectroscopy (FTIR), thermo-optical analysis (TOA) and atomic force microscopy (AFM). The results indicate that PPy is located within both the intra and interspherulitic regions of the PCL matrix achieving a well-developed connected network. Compared with amorphous matrices, considerable conductivity (around 1 S/cm) was raised with the crystalline PCL matrix with only a relatively low level of the conductive polymer (∼5%) in the blend.     

Graft polymerization of vinyl acetate onto silica

The free‐radical graft polymerization of vinyl acetate onto nonporous silica particles was studied experimentally. The grafting procedure consisted of surface activation with vinyltrimethoxysilane, followed by free‐radical graft polymerization of vinyl acetate in ethyl acetate with 2,2′‐azobis(2,4‐dimethylpentanenitrile) initiator. Initial monomer concentration was varied from 10 to 40% by volume and the reaction was spanned from 50 to 70°C. The resulting grafted polymer, which was stable over a wide range of pH levels, consisted of polymer chains that are terminally and covalently bonded to the silica substrate. The experimental polymerization rate order, with respect to monomer concentration, ranged from 1.61 to 2.00, consistent with the kinetic order for the high polymerization regime. The corresponding rate order for polymer grafting varied from 1.24 to 1.43. The polymer graft yield increased with both initial monomer concentration and reaction temperature, and the polymer‐grafted surface became more hydrophobic with increasing polymer graft yield. The present study suggests that a denser grafted polymer phase of shorter chains was created upon increasing temperature. On the other hand, both polymer chain length and polymer graft density increased with initial monomer concentration. Atomic force microscopy–determined topology of the polymer‐grafted surface revealed a distribution of surface clusters and surface elevations consistent with the expected broad molecular‐weight distribution for free‐radical polymerization. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 300–310, 2003     

容器设计中搅拌装置的轴向力分析

搅拌装置在化工厂中应用很广，在磷肥、钛白粉装置中（15kt/a)使用较多，仅钛白粉装置中就大约有40－50台，如增稠结晶器，中和槽等，搅拌操作所涉及的因素极为复杂，浆叶形式的选择，从力学的观点来说，迄今研究不够，本文就搅拌装置产生的轴向力问题进行了初步研究。     

用于测定钢液低氧含量的双层固体电解质研究

采用“毛坯浆料法”在ＺｒＯ２（９％摩尔含量ＭｇＯ）管状固体电解质基体表面制备了厚度为１－４μｍ的ＺｒＯ２（１０％摩尔含量Ｙ２Ｏ３）固体电解质涂层，并分别对此在本实验室和美国ＬｅｅｄｓａｎｄＮｏｒｔｈｒｕｐ公司进行了钢液低氧含量测试，结果表明：涂层没有破坏基体的抗热震性：氧浓差电池电动势的重现性偏差由原来的±２ｍＶ；电动势的绝对值提高１０ｍＶ左右；而比日本Ｔｏｒａｙ公司的同类产品提高３５ｍＶ，这说明     

宽厚板厚度控制模型的优化

宽厚板厚度控制的目的是轧制出板形良好、板凸度小、同板差和异板差尽可能小的产品.莱钢宽厚板生产线自投人生产以来,在板凸度、厚度的均匀性、同板差和异板差等宽厚板厚度控制的瓶颈问题上都难以达到要求.为了实现对轧制厚度的要求,我们在现有的厚度控制模型的基础上,深入理解其控制功能、补偿功能的作用,找到引起厚度难以控制的主要因素,采取轧辊刚度补偿、轧辊偏心补偿、支撑辊油膜厚度补偿、工作辊热膨胀补偿及冲击力补偿等措施来优化厚度控制模型.自优化相应厚度参数和增加相关补偿控制功能以来,宽厚板厚度控制的精度得到很大的提高,具有很高的推广价值.     

用于10-6N~10-5N微力测量的柔性铰链机构设计

在基于静电场原理的微纳力值测量系统中,力值的传递与转化机构起着至关重要的作用。选择平行四边形柔性铰链机构作为其弹性元件,以实现10-6N量级的力值测量。分析了柔性铰链的数学模型,研究了其静态与动态刚度;根据系统要求确定了柔性铰链的目标刚度,并采用有限元方法对其进行优化设计和模态分析;分析了加工精度对铰链刚度的影响。将该铰链用于微力测量系统中,通过实验给出了刚度测试结果和力值测量结果,实验表明,该平行四边形柔性铰链满足微力测量系统对10-6N量级的力值测量要求。