利用AFM对单晶硅表面加工化学反应理论分析

以原子力显微镜为工具,在空气条件下对单晶硅片表面加工得到下凹的三维微结构。给出了AFM金刚石针尖在对单晶硅的微加工中的化学反应和加工模型。对加工条件下发生的化学反应及其原理进行了理论分析。用化学热力学定律、化学动力学原理和相关的热力学数据自由能、生成热、化学键能、活化能等分析加工过程中发生的反应是空气中O2与单晶硅Si反应生成二氧化硅的过程;金刚石针尖磨损发生的反应主要是空气中O2与金刚石针尖C反应生成CO2的过程。     

摩擦式提升机安全性能的初步分析

介绍了多绳摩擦式提升机的工作原理,对摩擦式提升机的安全性能进行了分析,探讨了摩擦式提升机的防滑安全系数和具体的防滑安全措施,并对摩擦提升机的主要优缺点进行了比较．     

超空泡航行体纵向运动的鲁棒极点配置控制

由于空泡及滑行力的存在,使得超空泡航行体的建模及控制问题变得非常复杂,在其模型简化过程中会产生一定的建模误差,采用鲁棒极点配置算法进行超空泡航行体控制可以有效克服这一缺点.对超空泡航行体所受的流体动力、尤其是滑行力的动态特性进行了分析整理;建立了超空泡航行体纵平面内的动力学模型;最后利用鲁棒极点配置算法设计了控制器.仿真结果表明,该控制系统具有较强的鲁棒性及稳定性.对各控制变量的控制效果进行了对比分析,分析结果表明空化器比尾舵具有更好的控制效果.     

三星型压缩机振动问题研究

提出了引起星型活塞式压缩机振动这一宏观现象发生的根源.在一阶惯性力机器内完全平衡的情形下,对二阶惯性力因目前无法在机器内平衡,分析其形成的机理.在机器向大排量方向发展时,二阶惯性力引起机器振动不可忽略,容易引起机器在水平面内移动,所以需采取与基础紧固的措施.     

Fabrication of a gradient refractive index preform using laminar shear mixing

A gradient refractive index rod was successfully prepared by a new fabrication method using laminar shear mixing, and a graded index polymer optical fiber that satisfied IEEE1394b was obtained from the method. To fabricate the gradient refractive index rod, a liquid monomer mixture with a relatively low refractive index was placed in a prepared cylindrical glass reactor and a transparent polymer rod with a higher refractive index was introduced at the center of the reactor. The reactor and the polymer rod were then rotated concurrently with a small rotating speed difference to generate a Couette flow in the liquid phase. The centrifugal force generated by rotation and the polymer diffusion into the liquid monomer mixture developed a graded concentration profile in a radial direction. The Couette flow could reduce the concentration fluctuation in a tangential direction. In addition, the graded index profile could be controlled by the copolymer composition of the rod and its diameter. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1100–1104, 2005     

Highly moisture-proof polysilsesquioxane coating prepared via facile sol-gel process

A highly moisture-proof polysilsesquioxane coating was obtained from a new bis-silylated precursor, which was synthesized from 3-aminopropyltriethoxysilane (APTES) and m-xylylene diisocyanate (m-XDI) in tetrahydrofuran (THF) and verified by ¹H MAS NMR. For direct comparison purposes, an SiO₂ coating was also prepared by the Stöber method using tetraethoxysilane (TEOS) as the reactant. Interestingly, the coating obtained from the polysilsesquioxane sol exhibited a much higher moisture resistance capability than its counterpart, which was attributed to its more compact feature between nanoparticles as characterized by N₂ absorption experiment and transmission electron microscopy (TEM). Furthermore, its high transparency of about 92% showed potential for application in the protection of optical crystals.     

Mathematical model of shear rate of polymer melt dynamic extruding through capillary

With superimposing a sine vibration of displacement on the extruding direction of a polymer melt, the characterization formula of the shear rate of a polymer melt within a capillary was set up. By making use of the experimental equipment of a constant velocity type dynamic rheometer of capillary (CVDRC) designed by the authors, the calculating steps of the shear rate of the polymer melt at the wall of the capillary under a vibration force field were established. Through measuring and analyzing the instantaneous data of capillary entry pressure, capillary volume rate, and their phase‐difference under the superimposed vibration, the polymer melt's shear rate at the wall of the capillary can thus be calculated. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1056–1061, 2005     

深厚覆盖层上高心墙坝地震惯性力动态分布系数研究

对于强震区坐落在深厚覆盖层(深度超过50 m)上的高土石坝,通过拟静力稳定分析结果初步判定其抗震稳定性是抗震设计的主要内容,其中水平向地震惯性力沿坝基覆盖层至坝顶的动态分布系数是关键。然而,现行《水工建筑物抗震设计标准》(GB 51247—2018)中地震惯性力动态分布系数多基于坐落在基岩上的高土石坝的动力响应规律确定,现有动态分布系数忽略了深厚覆盖层和地震动强度对地震动传播规律的影响。因此,以坐落在深厚砂砾石覆盖层上150 m级高黏土心墙堆石坝为研究对象,结合现行土石坝设计规范和国内已建高土石坝实例,基于统计平均的方法确定了坝顶宽度、坝料分区、坝坡坡比、覆盖层材料的静、动力特性等关键参数,深入探讨了150 m级高黏土心墙堆石坝在小震(0.1 g)、中震(0.2 g)和大震(0.4 g)规范谱地震动作用下不同深度砂砾石料覆盖层的动力响应分布规律,进而总结归纳出不同深度覆盖层下150 m级高黏土心墙堆石坝的水平向地震惯性力的动态分布系数,将其引入到拟静力法稳定分析中,最后基于最危险滑动面和最小安全系数与现行规范所得结果进行对比分析。研究结果表明,小震(0.1 g)和中震(0.2 g)下采用文中推荐的考虑深厚覆盖层和地震动输入强度影响的水平向地震惯性力动态分布系数时将得到更符合工程实际的评价结果。研究成果可为深厚覆盖层上的高土石坝抗震设计提供参考依据。     

兰州某地铁车站深基坑开挖变形特性及环境影响分析

针对兰州城区工程地质水文条件复杂的问题,为了研究该地区地铁车站深基坑开挖过程中支护结构的变形受力特点和对周边环境的影响,以迎门滩站深基坑工程为典型案例进行分析。该车站基坑所在区段属黄河漫滩区,地铁穿过地层主要为卵石土,水位5～8 m。该基坑围护结构采用钻孔灌注桩+钢管内支撑体系。采用PLAXIS 3D有限元分析软件对该基坑建立三维有限元计算模型,土体本构模型采用土体硬化(HS)模型,依据工程实际开挖工况进行分部开挖计算,根据计算结果对桩撑式支护结构的变形和受力及基坑周边地表和地下管线的变形进行了分析。结果表明:围护桩的变形量、地表沉降量和管线位移量会随着基坑开挖深度的增加有逐渐累积的趋势,但在架设内支撑并施加预应力后,这些变形量的增速会减缓甚至变形量会减小。内支撑施加预应力之后自身轴力会有较大增加,之后基本保持不变,对其他内支撑轴力的影响较小。各变形量均在控制范围之内,满足设计和环境要求,表明该深基坑采用的钻孔灌注桩+钢管内支撑支护体系设计合理。研究成果可为后续黄土地区类似地铁车站深基坑工程建设提供一定的参考依据。     

波浪对圆柱外接圆弧型防波堤绕射的解析计算

在微幅波绕射理论的基础上,使用特征函数展开法,推导了圆柱外接圆弧型防波堤复合结构的水波绕射的解析解,并据此计算了该结构所受到的波浪载荷以及绕射波面分布。计算结果表明:与单一圆柱相比,外接圆弧型防波堤的存在可明显降低作用于圆柱的波浪载荷和圆柱表面的波浪爬高;采用外接堤表面密实或透空而内圆柱表面透空的结构形式可以取得圆柱防浪的较佳效果;结构透空系数、波浪入射角度、外接堤张角、外堤半径与水深比、水深与波长比等因素的变化对绕射波浪作用均存在一定影响。