Extracting Light from Polymer Light‐Emitting Diodes Using Stamped Bragg Gratings

In this paper, we describe a method for increasing the external efficiency of polymer light‐emitting diodes (LEDs) by coupling out waveguided light with Bragg gratings. We numerically model the waveguide modes in a typical LED structure and demonstrate how optimizing layer thicknesses and reducing waveguide absorption can enhance the grating outcoupling. The gratings were created by a soft‐lithography technique that minimizes changes to the conventional LED structure. Using one‐dimensional and two‐dimensional gratings, we were able to increase the forward‐directed emission by 47 % and 70 %, respectively, and the external quantum efficiency by 15 % and 25 %.     

井下套管阀研究及室内试验

随着欠平衡钻井技术的深入研究和推广应用,全过程欠平衡钻井技术已成为研究热点。除了常规的欠平衡装备外,全过程欠平衡钻井还需配备井下套管阀,为此,研制了一种双液控井下套管阀。为检验该阀的使用可靠性,进行了全面的室内试验和测试,试验内容包括压力密封能力,高压、有流动情况下阀板关闭的动作准确性,模拟现场阀板下憋压时打开阀板的作业程序,检测在各种密封压力时阀的微泄漏量。试验结果表明,该阀达到设计要求,能够满足全过程欠平衡作业的工艺要求。     

磷酸酯类离子液体在燃油深度脱硫中的应用

研究了3种磷酸酯类离子液体,即1,3-二甲基咪唑磷酸二甲酯盐([MM im]DM P)、1-乙基-3-甲基咪唑磷酸二乙酯盐([EM im]DEP)和1-丁基-3-甲基咪唑磷酸二丁酯盐([BM im]DBP)的制备过程,考察了这3种磷酸酯类离子液体对模型油中3-甲基噻吩、苯并噻吩和二苯并噻吩的脱除效果及磷酸酯类离子液体的电化学再生方法。实验结果表明,这3种磷酸酯类离子液体的脱硫能力强弱顺序为:[EM im]DEP>[BM im]DBP[MM im]DM P;且对二苯并噻吩的脱除效果最好,对苯并噻吩的脱除效果次之,对3-甲基噻吩的脱除效果较差。以[EM im]DEP为萃取剂,油剂质量比为1∶1时,经5次萃取后,二苯并噻吩的脱除率可达到99.5%。利用电解法对[EM im]DEP进行了再生,在5~10V电压下电解10h,[EM im]DEP的脱硫率可以达到新鲜[EM im]DEP的90%以上。     

催化裂化汽油光化学氧化脱硫

以水为萃取剂、空气中的O2为氧化剂、500W高压汞灯为紫外光光源,研究了催化裂化(FCC)汽油光化学氧化反应的机理和氧化产物,考察了反应条件对FCC汽油脱硫率的影响。实验结果表明,FCC汽油中的极性含硫化合物首先部分溶于水相中,然后在水相中被氧化。在空气通入量为150mL/min、水与FCC汽油的体积比为1.0的条件下,反应5h后FCC汽油脱硫率达40.6%,加入0.45g4A分子筛作为O2的吸附剂后FCC汽油脱硫率提高到70.2%。FCC汽油的光化学氧化反应为一级动力学反应,加入4A分子筛时的反应速率常数为0.217 4h-1,半衰期为3.18h。FCC汽油光化学氧化反应的主要产物为亚砜和砜,并进一步生成CO2、草酸、SO24-等。     

新安江流域安徽省地区水环境状况分析

统计分析流域内点源污染、面源污染产生量与污染物入河量的调查监测数据,结果表明:安徽省辖新安江流域点源入河系数约为面源入河系数2~3倍,点源污染是流域内主要污染来源,但面源污染的作用不容忽视,尤其是总磷,有近2/3来自面源,相对省辖淮河、长江两流域来说,面源污染贡献率明显增大。指出流域污染防治必须综合考虑点、面源污染两个方面;在点源污染不太严重的情况下,对面源污染的治理必须引起足够的重视,才能取得实效。     

应用改进BP网络对潼关高程的预测

作者在分析了影响汛前和汛后潼关高程变化值的因素的基础上，利用改进BP网络模型对非特征汛期和汛期潼关高程的变化值进行了计算。计算中不采用潼关的绝对高程，而用高程的变化量作为网络的较出物正量，从而减少计算误差，同时又能客观地考虑各影响因子的作用。改进后的BP模型学习时间短，精度满足要求。用该模型计算的潼关高程变化趋势与实际水库调度运行中的高程基本吻合。     

辽河防洪应急工程中的加筋粉细砂筑坝技术

加筋粉细砂筑坝是一门新兴技术,通过在辽河防洪应急工程右岸李家堡段应用表明,该项技术在技术上是可行的、在经济上是合理的。本文介绍了该技术在辽河防洪应急工程右岸李家堡段的应用。     

Optimal Control of the Primary Drying Stage of Freeze Drying of Solutions in Vials Using Variational Calculus

The problem of operating freeze drying of pharmaceutical products in vials placed in trays of a freeze dryer to remove free water (in frozen state) at a minimum time was formulated as an optimal control problem. Two different types of freeze dryer designs were considered. In type I freeze dryer design, upper and lower plate temperatures were controlled together, while in type II freeze dryer design, upper and lower plate temperatures were controlled independently. The heat input to the material being dried and the drying chamber pressure were considered as control variables. Constraints were placed on the system state variables by the melting and scorch temperatures during primary drying stage. Necessary conditions of optimality for the primary drying stage of freeze drying process in vials are derived and presented. Furthermore, an approach for constructing the optimal control policies that would minimize the drying time for the primary drying stage was given. In order to analyze optimal control policy for the primary drying stage of the freeze-drying process in vials, a rigorous multi-dimensional unsteady state mathematical model was used. The theoretical approach presented in this work was applied in the freeze drying of skim milk. Significant reductions in the drying times of primary drying stage of freeze drying process in vials were obtained, as compared to the drying times obtained from conventional operational policies.     

Expanding the analytical potential of channel locational probability maps using cellular statistics

The planimetric shifts in channel location of large alluvial rivers are a critical component in the creation of diverse structures and functions in riverine habitats. Engineered management schemes must also compensate for this type of channel change to protect resources and maintain navigation channels. The stability of the Lower Mississippi River channel was assessed through an analysis of historical records of channel position produced and archived by the United States Army Corps of Engineers. Channel location was recorded for the years 1765, 1820, 1881, 1915, 1930, 1937, 1960 and 1970. Channel stability was measured by two introduced metrics on a cell‐by‐cell basis: (1) the standard deviation of Euclidean distance to a channel cell for the entire period of record, and (2) the rate of Euclidean distance change between years in the period of record. At a coarse spatial scale, channel instability increased in the downstream direction. The variability of channel stability also increased in the downstream direction. Analysis of this variability identified alternating areas of high and low stability occurring with greater frequency as distance downstream increased. These findings are validated by past studies of channel stability along the Lower Mississippi River. As a result, the proposed metrics provide a consistent, quantitative, efficient and cost‐effective means of identifying areas of channel instability at several spatial scales. Copyright © 2006 John Wiley & Sons, Ltd.     

基于子波域空间相关的多分辨图像滤波方法

从静态子波变换入手,提出了一种有效的图像滤波算法。通过计算相邻尺度下细节信号的空间相关性来区分噪声和信号,如果子波系数的空间相关性大,则认为此位置的系数含有特征及边缘信息予以保留。实现这种理论的完整方法包括两部分:空间滤波和子波收缩。仿真结果表明这个算法有很好的降噪性能。