FV520(B)钢时效组织和力学性能分析

通过透射电镜、电子拉伸、示波冲击试验,分析了马氏体沉淀硬化不锈钢FV520(B)850℃油淬后分别在560、600和630℃时效后的组织和力学性能。结果表明,淬火态FV520(B)钢560℃和600℃时效处理后,组织均为过时效马氏体+残余奥氏体,但细微组织有较大的差别,630℃时效处理后,组织为过时效马氏体+马氏体+ 残余奥氏体;560℃时效后强度最高;三种时效温度下,FV520(B)均具有较高的冲击韧度,600℃时效后冲击韧度最高;时效温度对FY520(B)冲击韧度的影响主要决定于其对塑性变形功(Apl)的影响。     

FV520(B)钢时效组织和力学性能分析

通过透射电镜、电子拉伸、示波冲击试验，分析了马氏体沉淀硬化不锈钢FV520（B）850℃油淬后分别在560、600和630℃时效后的组织和力学性能。结果表明，淬火态FV520（B）钢560℃和600℃时效处理后，组织均为过时效马氏体＋残余奥氏体，但细微组织有较大的差别，630℃时效处理后，组织为过时效马氏体＋马氏体＋残余奥氏体；560℃时效后强度最高；三种时效温度下，FV520（B）均具有较高的冲击韧度，600℃时效后冲击韧度最高；时效温度对FV520（B）冲击韧度的影响主要决定于其对塑性变形功（Ad）的影响。     

TEM studies of cross sections of oxidized Fe-25Cr-6Al-La alloy

The oxidation behavior of the alloy Fe–25%Cr–6%Al-RE (rich in lanthanum) was investigated by means of TEM analysis. The results show that after 2 hr oxidation of the alloy, in pure oxygen at 1200° C, La precipitated in the oxide scale at the top of -Al₂O₃ grains and at the grain-boundary regions in the form of tiny particles of hexagonal La₂O₃. These tiny particles prevented aluminum from diffusing toward the surface and suppressed lateral growth of the oxide scale. The rare-earth constituents accelerated the internal oxidation of the alloy during thermal cycling between 1200° C and room temperature. They appeared as particles of aluminum oxide and lanthanum oxide. Particles of cubic La₂O₃ precipitated in the alloy matrix near the oxide scale-metal interface in a direction parallel to grain boundaries.     

Oxidation behavior of 2.25Cr-1Mo steel with prior tempering at different temperatures

The oxidation behavior of a normalized 2.25Cr-1Mo steel tempered previously for 10 hr at different temperatures between 873 and 1023 K has been studied up to a maximum duration of 1000 hr in air at 773–973 K. The oxidation resistance of the steel was found to decrease significantly with the temperature of tempering. Tempering of this steel is reported to cause microstructural changes involving precipitation of Cr as carbides and a decrease in the effective (free) Cr contents, that could influence the oxidation resistance of the Cr-containing alloys. Relative compositions across the thickness of the oxide scales, as analyzed by SEM/EDX and SIMS, suggest that a less Cr-rich (and less protective) and thicker scale on the steel formed because previous tempering caused extensive depletion of free Cr.     

W-Cu合金深冷处理及其组织性能研究

对粉末冶金熔渗技术制备的不同成分W—Cu合金在-196℃，保温48h进行深冷处理。采用X射线衍射仪和透射电子显微镜分析长时间深冷处理的现象与机理。结果表明：深冷处理后铜颗粒以短棒状形态在钨基体上弥散析出。析出的细小弥散的铜颗粒阻碍晶粒粗化和位错移动，铜颗粒部分填充到材料微孔内，同时深冷处理过程中的体积收缩也使材料内的部分缺陷如空位和微孔得到弥合，从而使不同成分的W—Cu合金的硬度提高，密度增大，电导率降低。     

高Co稀土热作模具钢析出相沉淀析出的研究

采用X射线衍射和透射电镜对新研制的高Co稀土热作模具钢的析出相及析出动力学进行了分析和探讨。结果表明 ,经过固溶和时效处理后合金中同时析出大量金属间化合物和碳化物。金属间化合物主要为 μ相和Laves相 ,碳化物主要为MC、M2 3 C6和M6C。在 70 0℃时效不同时间后 ,析出相的总量随时效时间的延长而不断增大 ,但 μ相增加的速度比较缓慢 ;M2 3 C6、M6C、Laves相增加较快 ;而MC逐渐减少。M2 3 C6、M6C是通过基体中的M和C原子的直接反应的形式析出长大的。     

AGING BEHAVIOUR OF PARTICULATE REINFORCED ALUMINUM ALLOY MATRIX COMPOSITES

The process of aging precipitation in SiC_p/6061 and Al_2O_3/6061 composites were investigated. Hardness testing, differential scanning calorimetry(DSC) and transmission electron microscopy were employed. Results showed that the precipitation phase form directly along dislocation lines in the composites because the particles produce high densities of dislocations which makes vacancy densities in the composites decrease, and the main precipitation phase at peak hardness was β′ phase.     

常压混合脱硅工艺生产种分精液

本文介绍了碳分、种分工艺对精液硅量指数A/S的不同要求,认为种分精液单独生产是很有必要的.本文从理论上分析了目前所应用的脱硅工艺,提出了一种常压生产种分精液的方法-常压混合脱硅工艺,并对某厂采用此工艺进行种分精液生产的情况进行了简单的介绍.     

微量Y对Al—Li合金的析出相和力学性能的影响

研究了Y(0.1、0.5wt-％)对Al-Li-Cu—Mg—Zr合金析出相与拉伸性能的影响结果表明:Y可使铸态合金晶粒细化:促进β′(Al_3Zr)相析出:抑制δ′(Al_3Li)相的长大速度:使S′(Al_2CuMg)相的分布均匀化.添加0.1％Y能改善合金塑性而不降低强度:添加0.5％Y可使强度提高而塑性不降低     

Effects of secondary carbide precipitation and transformation on abrasion resistance of the 16Cr-1Mo-1Cu white iron

The relationship between secondary carbide precipitation and transformation of the 16Cr-1Mo-1Cu white iron and abrasion resistance were investigated. The results show that secondary carbide precipitation and transformation at holding stage play an important role in the hardness and abrasion resistance. After being held for a certain time at 853 K for subcritical treatment, the grainy secondary carbide, (Fe,Cr)₂₃C₆, precipitated first and then Fe₂MoC or MoC carbides precipitated in the alloy, both of which improve the bulk hardness and abrasion resistance of the alloy. The reasons for these improvements are the secondary carbide precipitates from the austenite and the retained austenite transforms into the martensite, both make the matrix strengthen. So the matrix has more effective support to the harder eutectic carbide against exterior abrasion. With expanding the holding time, the in situ transformation from the granular (Fe,Cr)₂₃C₆ carbide into laminar M₃C carbide causes the formation of the pearlitic matrix and an associated decrease of the alloy abrasion resistance.