An IR study on ion-specific and solvent-specific swelling of poly(N-vinyl-2-pyrrolidone) gel

Swelling degrees of poly(N-vinyl-2-pyrrolidone) (PVP) gel were measured in aqueous salt solutions and in water/organic solvent mixtures to find marked ion- and solvent-specificities. In order to investigate any correlation of those specificities with hydration or solvation of PVP, IR spectra band of the CO group was monitored by means of ATR method both for PVP gel and the relevant solution systems. Dependence of the peak frequency on the swelling ratio suggested that hydration of PVP carbonyl group in deswollen gel systems is different from that in the corresponding solution systems. In the solution systems, PVP carbonyl band showed a high-wavenumber shift for deswollen systems, which can be well correlated with changes in water proton charge through ionic hydration and with Gutmann's acceptor number of organic solvents. In the deswollen gel systems, the CO band showed a low-wavenumber shift, suggesting a strong hydration or doubly hydrated state. This unexpected behavior was interpreted by assuming an intermolecular hydrogen bond of two carbonyl groups intermediated by water molecules.     

烷基化原料预加氢工艺应用分析

由于来自催化裂化装置的烷基化原料中所含有的丁二烯在烷基化反应中可生成重质油,使产品干点上升,辛烷值下降,并使酸耗增加.针对这种状况,齐鲁石化公司研究院和胜利炼油厂联合开发了QSH-01烷基化原料预加氢催化剂及其相应的工艺技术,来脱除原料中丁二烯.笔者对该工艺技术及其应用作了阐述,并对该技术的应用前景作出分析.     

太钢电弧炉上应用四星接法MOA的必要性

分析了太钢电弧炉变压器高压侧相间过电压的产生原因，比较了用于限制过电压的避雷器的两种接法．结论是用四垦接法ＭＯＡ限制过电压的效果较显著．     

YAG：Ce Phosphors for WLED via Nano-Pesudoboehmite Sol-Gel Route

The sub-micron sized YAG ： Ce phosphors were synthesized via a modified sol-gel method by peptizing nano-pesudoboehmite particulate. It is found that YAG phase from the dried gel powders appears at 1000 ℃ then the pure YAG phase exists at a relatively lower sintering temperature of 1400 ℃. The smaller sizes of phosphors in the ranges of 1 - 3 μm are obtained due to the contribution of seeding effects of nano-sized alumina particles to strengthen each step of the processes. Both the excitation and emission spectra of photoluminescence of the phosphor obtained at 1400 ℃ meet well with the spectroscopic requirements of the WLED phosphors.     

冷却排管的节能设计

从节能的观点出发，根据热力学原理和传递过程的理论，对冷却排管内湍流传热过程进行分析，研究损失随雷诺数的变化规律，探讨冷却排管的节能设计问题。     

微加速度计粘附问题的研究及应用

粘附是影响微机电系统(MEMS)可靠性的重要因素之一。针对MEMS的典型产品——微加速度计的粘附问题进行了研究,给出了2种典型的微加速度计的表征粘附特性的剥离数的表达式,并分析了将粘附条件应用于微加速度计的多学科设计优化之中,分析了其对系统结构设计产生的影响。     

Irradiation Defects in Silicon Crystal

The application of irradiation in silicon crystal is introduced.The defects caused by irradiation are reviewed and some major ways of studying defects in irradiated silicon are summarized.Furthermore the problems in the investigation of irradiated silicon are discussed as well as its properties.     

A general variance predictor for Cavalieri slices

A general variance predictor is presented for a Cavalieri design with slices of an arbitrary thickness t ≥ 0. So far, prediction formulae have been available either for measurement functions with smoothness constant q = 0, 1, … , and t ≥ 0, or for fractional q ∈ [0, 1] with t = 0. Because the possibility of using a fractional q adds flexibility to the variance prediction, we have extended the latter for any q ∈ [0, 1] and t ≥ 0. Empirical checks with previously published human brain data suggest an improved performance of the new prediction formula with respect to the hitherto available ones.     

不甩线圈的多星形移相变极

对于某些槽数和极数比的多星形移相变极电机,提出与前人不同的是在两种极数下均不甩去线圈的绕组方案,使绕组利用率高,且线圈及其联接都较简单.这种绕组方案在一种极数下并联支路略有不平衡,其所引起的电机定子铜耗的增加是极其有限的,不致影响电机的正常运行.     

电信号码编排的建议——使用电话名

介绍了电话名的概念 ,并主要针对电话名系统的实现、应用及前景做了相应的分析