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71.
《Advanced Powder Technology》2023,34(7):104049
Constructing heterojunctions is an excellent way to enhance the photocatalytic property of semiconductors. Herein, a range of S-scheme BiOCl/g-C3N4 heterojunctions with varying mass ratios were designed using a facile hydrothermal route, and their photocatalytic ability was assessed by degrading the ethyl xanthate (EX) under visible light (λ > 400 nm). The results showed that the degradation efficiency of BiOCl/g-C3N4-0.1 heterojunction for EX was up to 91.2 % within 180 min, and its apparent rate constants (Kapp) were 4.3 and 11 times greater than those of BiOCl and g-C3N4, respectively. The experimental and characterization results revealed that the excellent photocatalytic property was ascribed to the construction of S-scheme heterojunctions. Such structure not only enhanced the visible light response but also facilitated the efficient separation of photoinduced carriers with the S-scheme transfer route, retaining strong redox-capable holes and electrons to participate in surface reactions. Furthermore, the cycling experiments indicated that the fabricated photocatalysts have great recyclability and stability. Based on the results of active substance capture, the S-scheme charge transfer model was proposed and the photodegradation mechanism of EX was reasonably elucidated. Overall, this work offers some theoretical direction for the design and construction of S-scheme heterojunctions with superior visible-light-driven photocatalytic performance. 相似文献
72.
介绍了一种基于PC机的煤泥浮选自动识别系统。系统采用了数字图象处理技术、自动监控技术,在586机的Windows平台上,用VC++编程实现,所得结论准确,值得推广。 相似文献
73.
磷矿反浮选捕收剂大多数是由天然脂肪酸制成的,种类繁多,性能各异.从市场快速、准确地选择磷矿反浮选捕收剂,对浮选实践和浮选研究十分重要.浮选捕收剂的评价有助于掌握捕收剂的浮选性能,了解其在浮选过程中的作用.浮选法是浮选捕收剂的传统评价方法,程序复杂,耗时耗力.提出了一种新的浮选研究方法:燃烧-吸附量评价法,通过燃烧无机的矿石样品来测定其表面吸附的有机捕收剂量,评价磷矿反浮选捕收剂的性能.通过对油酸、硬脂酸和软脂酸这些结构明确且浮选工作者熟悉的脂肪酸的浮选性能和在白云石上的吸附量,建立了一个评价模型,验证燃烧-吸附量评价法的可行性. 相似文献
74.
湖北省某地具有较为丰富铁矿资源,矿石中铁含量较低,原矿中全铁(TFe)含量约15%,属于贫磁铁矿,铁矿物的嵌布粒度较细,通过单一弱磁选很难得到全铁品位超过60%的铁精矿,针对该矿弱磁选精矿进行反浮选提铁脱硅研究,一粗一精开路反浮选流程精矿品位可达60%以上,铁回收率60%,产率50%左右.通过小型闭路试验,反浮选最终获得较好指标:精矿产率为68.57%,品位为58.62%,回收率为82.83%. 相似文献
75.
76.
Flotation performances of polymorphic pyrrhotite 总被引:1,自引:0,他引:1
The floatability of different crystalline structures of pyrrhotite (monoclinic and hexagonal) was studied. It is shown that
the floatability of monoclinic and hexagonal has obvious difference, and that the flotation recovery of monoclinic pyrrhotite
is larger than that of hexagonal pyrrhotite using different collectors. When butyl dithiophosphate is used as the collector,
the recovery is larger than that by sodium butyl xanthate and sodium diethyl dithiocarbamate. At the pH values ranging from
6 to 9, monoclinic pyrrhotite can be floated well, and the flotation recovery is higher than 90%. Monoclinic and hexagonal
pyrrhotites are more easily activated by Cu2+ in acidic conditions than in alkaline conditions. But Cu2+ cannot activate hexagonal pyrrhotite using sodium diethyldithiocarbamate as the collector. By the measurement of contact
angle, it is indicated that monoclinic and hexagonal pyrrhotites float well and are easily activated by Cu2+ when dithiophosphate is used as the collector. Using sodium diethyl dithiocarbamate as a collector, the relationship between
potential and pH range for pyrrhotite flotation is established. At pH 5, the optimal potential range for flotation of monoclinic
pyrrhotite is about 125–580 mV (vs SHE), with the maximum flotation occurring at about 350 mV (vs SHE); the optimal potential
range for flotation of hexagonal pyrrhotite is 200–580 mV (vs SHE), with the maximum flotation occurring at about 300 mV (vs
SHE). 相似文献
77.
Surface roughness of quartz particles was determined by measuring the specific surface area of particles. The wettability
characteristics of particles were determined by measuring the flotation rate using a laboratory flotation cell. Experimental
results show that the rod mill product has higher roughness than the ball mill product. For the particles with larger surface
roughness, the flotation kinetics constant is also higher. Finally, empirical relationships between surface roughness (r) and the flotation kinetics constant (k) of quartz particles as k=A+Br+Cr
0.5lnr+D/lnr+E/r and k=A+Br are presented, in which A, B, C, D and E are constants related to experimental conditions and mineralogical properties of mineral. 相似文献
78.
Jiu-shuai Deng Shu-ming Wen Dan-dan Wu Jian Liu Xiao-lin Zhang Hai-ying Shen 《北京科技大学学报(英文版)》2013,(9):815-822
The existence and release of fluid inclusions in bornite and its associated minerals, namely, quartz and calcite were investigated and confirmed. The structures, forms, and phases of these large quantities of fluid inclusions were also studied. A mass of fluid inclusions with various sizes, distributions, shapes, and phases exist in bornite and its associated minerals. Their sizes vary from a few micrometers to tens of micrometers, and the forms appear as negative crystals, or elongated, elliptical, and irregular. At room temperature, fluid inclusions were mainly characterized as gas-liquid two- phase. However, small amounts of fluid inclusions with pure gas phase and pure liquid single-phase were also observed in quartz and calcite. These fluid inclusions initially broke during the ore crushing and grinding process and then released into the flotation pulp in the flotation process. The quantitative analysis of fluid inclusions in the solution and the comparisons of mineral dissolution show that the amount of copper and iron released by fluid inclusions in the bornite sample is higher than the amount dissolved by the mineral; fluid inclusions in the associated gangue minerals, quartz, and calcite also make contribution. 相似文献
79.
80.
Flotation column is widely used as the separation equipment for fine mineral due to its high selectivity. However, this device may be unsuitable for the coarse particle flotation and has high handling ability. A two-stage flotation column with dimensions of 2 000 mm× 1 000 mm×4 000 mm was designed to enhance the column flotation process. The energy input was modified by adjusting the flow rate and the head of circulating pump. The flotation column was designed with low energy input in the first stage (speed flotation stage) to recover easy-to-float materials quickly, and high energy input in the second stage (recovery stage) to recover difficult-to-float minerals compulsorily. Contrast experiments on the throughput and coarse coal recovery of high ash coal from the Kailuan Mine were conducted using conventional single-stage flotation column and the two-stage flotation column. The results show that the combustible matter recovery of the two-stage flotation column is 5.25% higher than that of the conventional single-stage flotation column. However, the ash contents of clean coal for both columns are similar. Less coarse coals with low ash are obtained using the two-stage flotation column than that using the single-stage column flotation with the same handling ability. The two-stage flotation column process can enhance coal flotation compared with the conventional single-stage column flotation. 相似文献