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181.
The second virial coefficients of refrigerants HFC-32 (CH2F2), HFC-23 (CHF3), and HCFC-22 (CHC1F2) have been correlated on the bisis of site site model potential and have been compared with experimental results. The molecular interactions consisted of repulsion dispersion and electrostatic parts. From the site site potentials adjusted to the experimental second virial coefficients, spherically averaged potentials have been determined and a subsequent calculation of gaseous viscosity has been carried out. Agreement between measured and calculated values of second virial coellicients and gaseous viscosity is satisfactory. Calculated values of second virial coefficients and gaseous viscosity beyond available experimental data, therefore. can be assumed as a reliable extrapolation to lower and higher temperatures. 相似文献
182.
New measurements of the vapor-phase viscosity of phenol were performed from 437 up to 624 K and for densities between 0.006 and 0.023 mol · L–1 in an all-quartz oscillating-disk viscometer with small gaps. Thus, including our own measurements reported earlier, experimental data are available in the temperature range between 376 and 639 K and in the density range from 0.001 up to 0.023 mol · L–1. The data were evaluated with a density series for the viscosity in which only a linear density contribution is included. The values of the second viscosity virial coefficient obtained for phenol as well as for benzene, toluene, and p-xylene were compared with results of the Rainwater-Friend theory and of the modified Enskog theory on the basis of the Lennard-Jones 12-6 potential. The agreement is reasonable, when the potential parameter ratios determined by Bich and Vogel are used. The influence of bound dimers seems to be already taken into account in the three-monomer contribution according to Hoffman and Curtiss.Paper dedicated to Professor Joseph Kestin. 相似文献
183.
用试井方法确定注水后地层渗透率的变化 总被引:1,自引:0,他引:1
大港油田已进入开发中后期,高含水油田占73%,开发初期的一些参数已不适合现在开发的需要。研究出一套用试井方法确定注水以后地层渗透率变化的方法,对大港油田的增储上产具有重要意义。 相似文献
184.
185.
介绍了用于油田开采工艺的膜片式流量调节阀的结构及其特点,分析了调节阀出口压力、进口压力对其流量的影响。受力分析和现场使用表明:该阀流量恒定精度(即恒流偏差)取决于膜片有效面积S与阀心下端有效面积S′之比,此值为12,其恒流比偏差为0·03,说明该阀的流量恒定精度高;该阀不易被杂质卡死,稀油中直径1mm的砂粒能顺利通过,而不影响阀的功能;膜片式流量调节阀是没有高加工精度要求的部件,普通车床即可生产,因此造价较低。 相似文献
186.
以聚醚为基础油辅以抗磨剂、抗氧剂、防锈剂等多种添加剂研制而成的KGW聚醚合成工业齿轮油具有优异的黏温性能和低温性能,优异的极压抗磨性,极优的减摩性能,可满足高负荷、强冲击等苛刻条件下各类齿轮传动装置的润滑要求。该系列产品达到国外同类油品质量水平。 相似文献
187.
E. GLASER 《Journal of microscopy》2005,218(1):1-5
It is well known that the estimation of an object's volume by means of serial cross-sections, the so-called Cavalieri method, yields an unbiased estimate. But by itself it provides no means by which to estimate how precise this estimate is unless the shape of the volume is fully known beforehand. This knowledge can only be partially determined from the serial section information that is collected. Methods have been developed that claim to surmount this difficulty by using the serial section data to create a mathematical model of the volume's shape properties. The model then is used to estimate (predict) the precision of the volume estimate (its CE) from the single set of data available. Unfortunately, the theory underlying the model is flawed and so the model itself amounts to no more than an unsubstantiated guess about the shape of the volume. Therefore, the precision of the volume estimates that one obtains from the method is only as good as the model and this cannot be ascertained from the single set of acquired data. In this letter I explain the inadequacies of the modelling method. I suggest that it be used only with caution, if at all. Instead I suggest two alternative ways to predict the CE, one that is based upon a rule-of-thumb approach to the object's shape, and another that is based upon spectral analysis of the measurement function and that is easy to implement with available computer software. 相似文献
188.
189.
R. Tao 《Chemical engineering science》2006,61(7):2186-2190
Molecular dynamical simulation has been carried out to investigate the structure and dynamics of a dipolar fluid under strong shear. Dipolar fluid consists of polarizable particles, which have an induced dipole moment in the applied field direction. Shear stress is perpendicular to the field direction. When shear stress is small, the flow has a flowing-chain structure. If shear stress increases to pass a critical value, flowing-chain structure changes to flowing layer structure. Each layer is parallel to the flow direction and shear direction. Within one layer, particles form strings in the flow direction. 相似文献
190.