磁氧分析仪在焦化回收系统的应用

分析磁氧分析仪在实际生产中存在的问题,并提出改造措施,以提高电捕焦油器的安全性和稳定性。     

Fluorescence of poly(di-n-alkylsilane)s in room-temperature solution

A comprehensive study of the electronic absorption and emission spectra and the fluorescence quantum yield and lifetime of seven poly(di-n-alkylsilane)s and of three isotopically labelled poly(di-n-hexylsilane)s in hydrocarbon solution at room temperature is reported. Also reported are fluorescence polarization and carbon tetrachloride quenching of fluorescence of poly(di-n-hexylsilane). The observed fluorescence spectra, quantum yield, and polarization depend on the selected excitation energy in a very characteristic fashion, whereas the fluorescence lifetime does not; however, it depends on the selected emission energy. These characteristic dependencies are qualitatively accounted for by the previously proposed segment distribution model if one assumes that the photophysical behavior at higher excitation energies is strongly affected by the presence of a low-lying weakly allowed state in short-segment chromophores and the behavior at lower excitation energies is dictated by the selective excitation of emitting long-segment chromophores.     

An EXAFS study of the Mo/TiO2 hydrodesulphurization catalysis

In-situ EXAFS studies of sulphided Mo/TiO₂ catalysts have shown that at low Mo loadings (2–4 wt%), an active species with a short Mo-S distance of 2.25 Å is formed, while on Mo/TiO₂ with high Mo loadings as well as on Mo/-Al₂O₃, bulk MoS₂ (Mo-S, 2.42 Å) is formed. The species with the short Mo-S distance has Mo in an oxidation state close to 6 + and is likely to result from the sulphidation of the tetrahedral molybdate species present in the oxidic precursor at low Mo loadings. The calcination temperature of the oxidic precursor appears crucial, a high calcination temperature of 973 K favouring the formation of MoS₃ on sulphidation, and a low calcination temperature of 623 K favouring MoS₂.Contribution No. 790 from the Solid State and Structural Chemistry Unit.     

基于溶液图像时序特征的元素组分含量动态监测系统

针对稀土萃取过程中组分含量难以实时监测以及现有组分含量检测方法耗时、耗内存的现状,设计了一种基于溶液图像时序特征的元素组分含量动态监测系统。首先使用图像采集装置获取萃取槽体溶液的时序图像,考虑萃取液颜色特性和单一颜色空间的不全面性,采用主成分分析（PCA）方法在HSI和YUV融合的颜色空间提取图像的时序特征,并结合生产指标构造基于鲸鱼优化算法（WOA）的最小二乘支持向量机（LSSVM）分类器来对工况状态进行判断。然后当工况处于非最佳状态时,在HSV颜色空间对图像提取颜色直方图和颜色矩特征,并开发以溶液图像间的混合特征差值的线性加权值为相似度度量的图像检索系统,从而获取组分含量值。最后进行镨/钕萃取槽体混合溶液测试,结果表明该系统能够实现元素组分含量的动态监测。     

面向动用计划的车辆装备备件预测研究

针对动用计划下的车辆装备备件的消耗特点,研究了车辆装备维修备件消耗量和库存控制两个预测优化问题。考虑动用计划期内车辆装备的预防性维修和修复性维修,实现定时定程维修和自然随机故障维修下装备维修备件的消耗量的预测。在此基础上,根据备件库存检查方式的特点,建立基于定期检查策略的联合补货库存控制模型,根据模型的结构特点确定决策变量界限,并利用多类种群位置更新方式改进了果蝇优化算法。仿真结果表明,改进的果蝇优化算法具有良好的求解效率,本文所提出的优化方法可为车辆维修保障资源优化提供决策依据。     

旅游法实施背景下网友对“导游员”工作的感知——基于新浪微博文本分析

以2013年国庆期间新浪微博网友关于“旅游法”和“导游”的原创微博为样本,采用数量分析方法,分析网友对旅游法实施后导游工作关注程度的变化以及对旅游法的支持程度,研究表明,国庆期间网友对旅游法实施后导游工作的关注日益增加,认为旅游法的实施对导游工作有正面影响的网友占大多数.使用词频统计法和共现分析法进行内容分析,网友对导游工作的感知主要包括：导游工作需要旅行社和游客的支持和理解;支持旅游法对无证导游的惩罚,但是惩罚力度不足;旅游法对强制消费的约束已初见成效,但部分网友表现出对部分导游工作态度消极的不满;旅游法实施后导游收入下降明显.     

企业网站设计内容第一的原则

企业网站设计内容第一的原则,其根本在于企业网站能否吸引和留住客户或潜在客户,它包含三层意思：网站内容的面向对象要准确清晰;针对目标访客的网站内容要紧扣其兴趣中心,从为其带来价值的角度出发,令其感到有收获;促使目标访客对网站内容建立起充分的信任感、解答其疑问。从网站内容方面保证了企业网站对目标访客的吸引力和访问粘度,从而为企业网站实现其既定目标打下了良好的基础。     

Oxidation behavior of 2.25Cr-1Mo steel with prior tempering at different temperatures

The oxidation behavior of a normalized 2.25Cr-1Mo steel tempered previously for 10 hr at different temperatures between 873 and 1023 K has been studied up to a maximum duration of 1000 hr in air at 773–973 K. The oxidation resistance of the steel was found to decrease significantly with the temperature of tempering. Tempering of this steel is reported to cause microstructural changes involving precipitation of Cr as carbides and a decrease in the effective (free) Cr contents, that could influence the oxidation resistance of the Cr-containing alloys. Relative compositions across the thickness of the oxide scales, as analyzed by SEM/EDX and SIMS, suggest that a less Cr-rich (and less protective) and thicker scale on the steel formed because previous tempering caused extensive depletion of free Cr.     

碳含量对Ti(CN)基金属陶瓷力学性能的影响

研究了Ti(CN)基金属陶瓷的碳含量对其物理力学性能的影响。结果表明 ,在一定范围内 ,随着碳含量的减少 ,Ti(CN)基金属陶瓷的矫顽磁力、钴磁和硬度降低 ;而抗弯强度则明显增高。     

高钒高速钢碳化钒形态的数值化分析

针对碳化钒的不同形态,设计出定量分析软件,并利用形状因子K,实现了高钒高速钢不同碳化物形态数值化处理,当K介于0.785～1.000之间碳化钒形态为团球状;K≤0.223,碳化钒呈开花状.高钒高速钢当碳含量达到4.2%时,K为0.86和当量直径D为0.78μm,碳化物呈团球状均匀分布.