CONVECTION PROMOTION AND GEL FORMATION IN AN ULTRAFILTRATION PROCESS

Convection promotion within a tubular ceramic membrane by using the kenics static mixer is studied. The experiments were carried out with aqueous solutions of pectin and sodium carboxymethylcellulose (CMC), for Reynolds number in the range of 60-5000. From the results of these experiments it can be concluded that the presence of convection promotor decreasing the concentration of the gel layer. The experimental data are correlated satisfactorily by the equation of the general form Sh=A Re^aSc^b.     

A BOUNDARY INTEGRAL EQUATION AND ITS NUMERICAL SOLUTION OF POTENTIAL FLOW AROUND SURFACE-IRREGULA-RITIES

In this paper,using complex functional theory,the authors turn the potentialflow around the surface irregularities in a pressure conduit and semi-infinite platforms intoDirichlet problem.Based on Schwarz formula and by the application of Plemelj's formula,theauthors change the problem into the integration of a Cauchy boundary integral equation in theflow plane through the substitution of variables.Using numerical integration,the authors obtainthe velocity distribution and pressure coefficient along surface irregularities and platforms.Thephysical concept of this method is clear,the convergent speed is rapid and the computative effi-ciency is high.The calculated values agree well with the measured results.It is an effective andsimple method in solving potential flow.     

Sodium silicate as a coke inhibitor during naphtha pyrolysis

Rates of coke formation during steam pyrolysis of naphtha have been investigated in a jet-stirred reactor both for sodium silicate coated and uncoated Inconel 600 surfaces in the temperature range of 1078–1108 K. Coke formation rates were significantly reduced on sodium silicate coated plates due to the passivation of the metal surface. However, the coking rates gradually increased with successive decokings of the coated surface.     

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本文简要介绍了国外在开发超酸性气体过程中遇到的材料选择、腐蚀监测、水化物堵塞、超酸性气的处理和加工等问题所采取的措施和办法。     

二钼酸铵(ADM)非团聚晶体的生成试验

探讨了二钼酸铵非团聚晶体生成的机理及制取新工艺。采取该工艺制取的ADM费氏粒度（Fsss)约30μm，激光粒度分布d0.5为370μm，松装比达1.37/cm^3。     

高含酸性气碳酸盐岩气藏流体敏感性实验研究

对川东北雷口坡组、嘉陵江组、飞仙关组、长兴组高含H，S及032的碳酸盐岩储层流体敏感性进行了实验研究，结果表明岩样速敏损害弱～强，水敏和盐敏损害中偏弱～极强，碱敏损害严重。岩石学分析揭示，川东北高含酸性气碳酸盐岩储层发育伊利石、微晶石英、白云石、方解石、硫化钙等潜在损害物质。钻井完井液侵入会破坏储层各物质间的原始动态平衡，诱发储层损害。主要损害机理为：①储层流体pH增加引起黏土矿物以及微晶石英失稳；②碱液与微晶石英、长石、白云石反应生成硅酸盐、高岭石、水镁石等新矿相；③流体矿化度改变可降低伊利石微粒间的连接力；④硫化钙水解产生OH^-，过量的OH-与Ca^2＋结合形成氢氧化钙沉淀；⑤储层含水饱和度和流体离子浓度改变，致使焦沥青脱附并在储层深部沉积；⑥硬石膏水化膨胀、分散运移。针对该气藏损害机理，可采用屏蔽暂堵技术以形成优质滤饼，有效降低储层流体敏感性损害。图5表2参10。     

Continuous formation of slurry ice by cooling water–oil emulsion in a tube

Water-silicone oil emulsion with an additive, (C₂H₅O)₃SiC₃H₆NH₂, was examined as a heat storage material. A spiral tube used as a heat exchanger was immersed in a low temperature bath and the emulsion was circulated in the tube to make ice continuously. Ice was separated from the ice–liquid suspension in an outlet tank. The amount of formed ice, the temperatures of the inlet and the outlet of the heat exchanger, and the temperatures in the tube wall were measured and the overall heat transfer coefficient and the heat flux through the tube were calculated. Experiments were carried out, varying the flow rate, the temperature of cooling brine, and the thickness of tube wall. The condition under which slurry ice was formed continuously without adhesion of ice to the cooling wall was clarified. Though decrease in the thermal resistance of the tube increased the rate of ice formation or raised the brine temperature, it narrowed the range of the flow rate and of the brine temperature in which slurry ice was formed continuously.     

In Situ Formation of a Novel Nanocomposite Structure Based on MCM-41 and Polyethylene

M41S materials are prepared by in situ assembly of inorganic precursors and organic template and can be viewed as nanocomposites of the siliceous phase and organic surfactant. Calcination of these precursors gives the M41S materials that have been used to prepare novel nanocomposite structures, in which the organic phase inside the nano-sized pores is isolated by the nano-sized inorganic pore walls. The nanocomposite structures can be formed by in situ polymerization of monomers inside the channels. Polymerization of ethylene takes place inside the nano-sized pores, producing the desired nanocomposite structure. The resulting polyethylene was found to be a mixture of crystalline and amorphous phases.     

环境因素对碳钢点蚀临界电势的影响

采用动电势扫描法测定了不同体系中碳钢发生点蚀的临界电势Eb。结果表明 :当Cl- 浓度 <0 .0 1mol/L时 ,随Cl- 浓度增加 ,临界电势负移并与Cl- 浓度成线性关系 ;pH值在 7～ 11之间 ,随pH值增加 ,临界电势正移并与pH值成线性关系 ;随温度增加 ,临界电势负移并与温度成线性关系。     

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解决注水泥作业的防气窜问题，是提高固井质量，保护油气层的关键技术。现有预测和防止水泥浆气管理的方法虽然较多，但应用于现场却有一定困难，主要表现在所考虑的因素比较单一，有些高温、高压下的水泥浆性能参数难以测定。文章在分析国内外预测和防止气窜方法的基础上，应用水泥浆浆体在环空的组成，GFP系数、水泥浆稠度阻力系数（A）及多凝水泥和环空加压等措施，拟定出一套提高水泥浆顶替效率，保证水泥浆动态和静态过程压力平衡关系的具体设计方法。