浅析炼油厂催化装置催化剂的损耗原因

本文根据对炼油厂催化装置的催化剂及油浆固含量的数据进行分析，从而对催化装置的催化剂损耗原因从几个方面进行了探讨。     

流动注射分析法对复合肥中五氧化二磷的分析

在复合肥的生产过程中，用流动注射分析测定磷矿，磷石膏，磷酸中的五氧化二磷，该方法制样简单，分析速度快，结果准确。     

Longitudinal and temporal water temperature patterns in the Yangtze River and its influence on spawning of the Chinese sturgeon (Acipenser sinensis Gray 1835)

In this study, water temperature longitudinal and temporal patterns were investigated in four locations of the Yangtze River to identify their influence on spawning of the Chinese sturgeon (Acipenser sinensis Gray 1835). The results showed that, historically (1960–1980), the four locations, Pingshan (PS, 2,687 river kilometres [rkm]), Yichang (YC, 1,640 rkm), Chenglingji (CLJ, 1,265 rkm), and Hukou (HK, 805 rkm), all had similar average annual water temperatures (around 18.0 °C) but very different amplitudes: The upper two locations, PS (11.4–23.2 °C) and YC (9.1–25.9 °C), were relatively stable and had smaller amplitude than the lower two ones, CLJ (6.0–30.0 °C) and HK (5.9–30.8 °C). On the basis of the physiological effects for Chinese sturgeon, we defined three water temperature ranges: stressing (>23 °C), holding (23–20 °C), and spawning (20–16 °C). We found that the upper two locations with successful spawning of the Chinese sturgeon (PS and YC) had short or no stressing period but long holding and spawning periods. Currently (2013–2016), the impoundment of the Three Gorges Reservoir increases the time for water temperature decreasing to 20 °C at the current spawning ground (YC) in autumn, which increases the stressing and holding periods, and has significant negative impact on the spawning of Chinese sturgeon. Nonetheless, considering the very high stressing temperature and the short duration of the holding and spawning periods at CLJ and HK, we propose that YC is still the most suitable spawning location for the Chinese sturgeon.     

Estimating discharge in gravel‐bed river using non‐contact ground‐penetrating and surface‐velocity radars

Discharge measurement is a critical task for gravel‐bed channels. Under high‐flow conditions, the elevation of the riverbed changes significantly by intensive torrential flow. The stage–discharge relations commonly used for stream discharge estimation may no longer be adequate. The contact‐type velocity measuring is also subject to measurement errors and/or instrument failures by the high‐flow velocities, driftwood, stumps, and debris. This study developed a new real‐time method to estimate river discharge in gravel‐bed channels. A systematic measuring technology combining ground‐penetrating radar and surface‐velocity radar was employed. The rating curves representing the relations of water surface velocity to the channel cross‐sectional mean velocity and flow area were established. Stream discharge was then deduced from the resulting mean velocity and flow area. The proposed method was examined in a steep gravel‐bed reach of the Cho‐Shui River in central Taiwan. The estimated stream discharge during three flood events were compared to the prediction by using the stage–discharge relation and the index‐velocity method. The proposed method of this study is capable of computing reasonable values of discharge for an entire flood hydrograph, whereas the other two methods tend to produce large extrapolation errors. Moreover, when the computed discharge is used in 2D flood flow simulation, the proposed method demonstrates better performance than the commonly used stage–discharge and index‐velocity methods.     

Entanglement Loss in Fast-Flowing Entangled Polymer: Numerical Simulation of The Short-Chain Behavior and Interpretation of Phenomenology

Although some of the important consequences of flow-induced entanglement loss in entangled polymer rheology have recently been recognized, this specific molecular mechanism has rarely been investigated quantitatively based on experiments or molecular theories. For the first time, the amount of entanglement loss of a short entangled linear polymer (i.e., seven entanglements per chain at equilibrium) during fast-flow deformation is directly tracked in the stochastic simulation of an existing reptation model. The primary finding is that significant entanglement loss is observed in both fast elongation and fast shearing, and, contrary to some earlier conjectures, is particularly pronounced in elongational flow when polymer chain stretching formally commences. Furthermore, according to the current simulation in which three different CCR (Convective Constraint Release) schemes are considered, entanglement loss appears to have very prominent effects on the elongational rheology of an entangled linear polymer – an observation that had rarely been recognized or considered before. On the other hand, the currently explored features of flow-induced entanglement loss are tentatively linked to a wide variety of peculiar empirical properties of temporarily entangled polymer liquids. In particular, we are thus able to provide a consistent molecular explanation of the fairly well-known phenomenological effects of polydispersity and long-chain branching leading to a pronounced strain-hardening phenomenon, in view of two newly proposed effects of heterogeneous relaxations in preventing, directly or indirectly, fast entanglement loss during flows.     

阻垢缓蚀剂对不锈钢管缓蚀效果的评定方法

用点蚀电位法和失重法评价了七种阻垢缓蚀剂在不同冷却水样中对不锈钢的缓蚀效果。用腐蚀失重法评价阻垢缓蚀剂对不锈钢的缓蚀效果，既不合理也很难测准。点蚀电位法是评价阻垢缓蚀剂对不锈钢缓蚀效果的有效方法，但要选择合适的空白水样。     

混合材对水泥与减水剂适应性的影响研究

通过对掺高效减水剂水泥净浆流动性及流动性损失的测定试验，研究了3种混合材(粉煤灰、水淬高炉矿渣和沸石)在不同替代率情况下对减水剂作用效果的影响。结果表明：水淬高炉矿渣有利于改善减水剂与水泥的适应性，而掺粉煤灰和沸石(尤其是沸石)则会导致减水剂塑化作用的降低，而且浆体流动性损失也有增大趋势。     

基于OGC规范的多星多传感器卫星地面系统设计与实现

为解决传统卫星地面系统各业务功能单一、异构组织协作方面的不足, 提出了新型卫星地面系统的设计架构。以OGC(Open Geospatial Consortium)组织制定的空间信息服务标准为核心, 分别研究了卫星地面系统各业务系统的服务化, 给出了完整的新型卫星地面系统框架体系, 并进行了原型系统的开发和相关的应用实验。结果表明, 新型的卫星地面系统有助于实现多星多传感器的动态添加和跨组织协调合作。     

基于异步切换多胞系统的网络化飞行器故障检测

本文研究了存在时变短时延和随机丢包的大包线网络化飞行器故障检测问题.首先,采用切换多胞系统描述飞行动态,并提出了一种局部重叠多胞划分方式以较低设计保守性.然后,借助泰勒级数展开和伯努利分布将时延和丢包转化为多胞系统参数,并构建了切换参数依赖故障检测滤波器.同时,考虑滤波器切换指令及多胞加权参数更新滞后引起的异步切换问题,基于切换参数依赖Lyapunov函数和平均驻留时间方法分析了系统的稳定性和l2性能,并以LMI形式给出了滤波器存在的充分条件.最后,以HiMAT(highly maneuverable technology)飞行器为例验证了所提方法的有效性.     

具有数据包丢失的离散随机不确定系统的线性最优满阶估值器

研究了具有数据包丢失和随机不确定性离散随机线性系统的状态估计问题.其中数据包丢失是随机的,且满足Bernoulli分布,系统矩阵中的随机不确定性由一个白色乘性噪声来描述.首先,通过配方方法,提出了最小均方意义下的无偏最优线性递推满阶滤波器.所提出的滤波器用到了当前时刻和最近时刻接收到的观测来保证线性最优性.与多项式滤波和增广滤波器相比,本文的滤波器具有较小的计算负担.然后,基于所获得的线性滤波器推导了线性最优预报器和平滑器.进一步研究了线性最优估值器的渐近稳定性,给出了稳态特性存在的一个充分条件.最后,通过两个仿真例子验证了所提估计算法的优越性.